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Research Article

Facet-induced coordination competition for highly ordered CsPbBr3 nanoplatelets with strong polarized emission

Dandan Yang1, Xiaoming Li1( ), Yuelei Li1, Bo Cai1, Lin Su2, Shengli Zhang1, Zhili Juan1, Cuifang Meng1, Dongling Geng1, Jiaxin Chen1, Feng Xu2, Haibo Zeng1( )
MIIT Key Laboratory of Advanced Display Materials and Devices Institute of Optoelectronics & Nanomaterials College of Materials Science and Engineering Nanjing University of Science and Technology Nanjing 210094 China
SEU-FEI Nano-Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University Nanjing 210096 China
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Abstract

Controllable anisotropic growth of perovskite nanocrystals (NCs) is challenging since it is difficult to separate the nucleation and growth processes. Here, a two-step nucleation strategy is proposed to control the binding interaction between surface ligands and NCs, resulting in facet-induced coordination competition. Oleic acid as surface activated ligand leads to the formation of defective lead bromine octahedron, and the binding interaction between 4-dodecylbenzenesulfonic acid and lead atoms promotes the formation of two kinds of binding interactions. Based on this strategy, the anisotropic growth of CsPbBr3 nanoplatelet (NPLs) with adjusted length from 11.4 to 24 nm, and the evolution of NPLs from stacked to tongue-shaped have been realized. Elemental line scan reveals the sulfur atoms mainly distribute at the edge of NPLs. Furthermore, binding energy calculation and experimental results illustrate the coordination competition of different binding interaction on specific facets induces the anisotropic growth of NPLs. Importantly, strong emission anisotropy of highly ordered NPLs with polarization ratio up to 0.58 is illustrated. This work not only deepens our understanding of the controllable synthesis of perovskite NCs, but also provides a reference for the regulation of light emitting diode and soler cells.

Keywords

CsPbBr3 nanoplatelet (NPLs)anisotropic growthbenzenesulfonic acid groupfacet-induced coordination competitionpolarized emission

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References

1

Protesescu, L.; Yakunin, S.; Bodnarchuk, M. I.; Krieg, F.; Caputo, R.; Hendon, C. H.; Yang, R. X.; Walsh, A.; Kovalenko, M. V. Nanocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br, I): Novel optoelectronic materials showing bright emission with wide color gamut. Nano Lett. 2015, 15, 3692–3696.
Crossref Google Scholar
2

Li, X. M.; Wu, Y.; Zhang, S. L.; Cai, B.; Gu, Y.; Song, J. Z.; Zeng, H. B. CsPbX3 quantum dots for lighting and displays: Room-temperature synthesis, photoluminescence superiorities, underlying origins and white light-emitting diodes. Adv. Funct. Mater. 2016, 26, 2435–2445.
Crossref Google Scholar
3

Akkerman, Q. A.; Motti, S. G.; Srimath Kandada, A. R.; Mosconi, E.; D'Innocenzo, V.; Bertoni, G.; Marras, S.; Kamino, B. A.; Miranda, L.; De Angelis, F. et al. Solution synthesis approach to colloidal cesium lead halide perovskite nanoplatelets with monolayer-level thickness control. J. Am. Chem. Soc. 2016, 138, 1010–1016.
Crossref Google Scholar
4

Dong, Y. T.; Wang, Y. K.; Yuan, F. L.; Johnston, A.; Liu, Y.; Ma, D. X.; Choi, M. J.; Chen, B.; Chekini, M.; Baek, S. W. et al. Bipolar-shell resurfacing for blue LEDs based on strongly confined perovskite quantum dots. Nat. Nanotech. 2020, 15, 668–674.
Crossref Google Scholar
5

Kim, Y. H.; Kim, S.; Kakekhani, A.; Park, J.; Park, J.; Lee, Y. H.; Xu, H. X.; Nagane, S.; Wexler, R. B.; Kim, D. H. et al. Comprehensive defect suppression in perovskite nanocrystals for high-efficiency light-emitting diodes. Nat. Photonics 2021, 15, 148–155.
Crossref Google Scholar
6

De Roo, J.; Ibáñez, M.; Geiregat, P.; Nedelcu, G.; Walravens, W.; Maes, J.; Martins, J. C.; Van Driessche, I.; Kovalenko, M. V.; Hens, Z. Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals. ACS Nano 2016, 10, 2071–2081.
Crossref Google Scholar
7

Chen, M.; Hu, H. C.; Tan, Y. S.; Yao, N.; Zhong, Q. X.; Sun, B. Q.; Cao, M. H.; Zhang, Q.; Yin, Y. D. Controlled growth of dodecapod- branched CsPbBr3 nanocrystals and their application in white light emitting diodes. Nano Energy 2018, 53, 559–566.
Crossref Google Scholar
8

Liu, J. L.; Shi, W. X.; Ni, B.; Yang, Y.; Li, S. Z.; Zhuang, J.; Wang, X. Incorporation of clusters within inorganic materials through their addition during nucleation steps. Nat. Chem. 2019, 11, 839–845.
Crossref Google Scholar
9

Pradhan, N. Journey of making cesium lead halide perovskite nanocrystals: What's next. J. Phys. Chem. Lett. 2019, 10, 5847–5855.
Crossref Google Scholar
10

Zhu, C. Q.; Chen, D. D.; Cao, W. C.; Lai, R. C.; Pu, C. D.; Li, J. Z.; Kong, X. Q.; Peng, X. G. Facet-dependent on-surface reactions in the growth of CdSe nanoplatelets. Angew. Chem. , Int. Ed. 2019, 58, 17764–17770.
Crossref Google Scholar
11

Wang, Y. H.; Pu, C. D.; Lei, H. R.; Qin, H. Y.; Peng, X. G. CdSe@CdS dot@platelet nanocrystals: Controlled epitaxy, monoexponential decay of two-dimensional exciton, nonblinking photoluminescence of single nanocrystal. J. Am. Chem. Soc. 2019, 141, 17617–17628.
Crossref Google Scholar
12

Zhang, B. W.; Goldoni, L.; Zito, J.; Dang, Z. Y.; Almeida, G.; Zaccaria, F.; de Wit, J.; Infante, I.; De Trizio, L.; Manna, L. Alkyl phosphonic acids deliver CsPbBr3 nanocrystals with high photoluminescence quantum yield and truncated octahedron shape. Chem. Mater. 2019, 31, 9140–9147.
Crossref Google Scholar
13

Peng, L. C.; Dutta, S. K.; Mondal, D.; Hudait, B.; Shyamal, S.; Xie, R. G.; Mahadevan, P.; Pradhan, N. Arm growth and facet modulation in perovskite nanocrystals. J. Am. Chem. Soc. 2019, 141, 16160–16168.
Crossref Google Scholar
14

Tong, Y.; Fu, M.; Bladt, E.; Huang, H.; Richter, A. F.; Wang, K.; Muller-Buschbaum, P.; Bals, S.; Tamarat, P.; Lounis, B. et al. Chemical cutting of perovskite nanowires into single-photon emissive low- aspect-ratio CsPbX3 (X = Cl, Br, I) nanorods. Angew. Chem. , Int. Ed. 2018, 57, 16094–16098.
Crossref Google Scholar
15

Yang, D.; Li, P. L.; Zou, Y. T.; Cao, M. H.; Hu, H. C.; Zhong, Q. X.; Hu, J. X.; Sun, B. Q.; Duhm, S.; Xu, Y. et al. Interfacial synthesis of monodisperse CsPbBr3 nanorods with tunable aspect ratio and clean surface for efficient light-emitting diode applications. Chem. Mater. 2019, 31, 1575–1583.
Crossref Google Scholar
16

Jing, Q.; Su, Y. C.; Xing, X.; Lu, Z. D. Highly luminescent CsPbBr3 nanorods synthesized by a ligand-regulated reaction at the water-oil interface. J. Mater. Chem. C. 2019, 7, 1854–1858.
Crossref Google Scholar
17

Li, Y. X.; Huang, H.; Xiong, Y.; Richter, A. F.; Kershaw, S. V.; Feldmann, J.; Rogach, A. L. Using polar alcohols for the direct synthesis of cesium lead halide perovskite nanorods with anisotropic emission. ACS Nano 2019, 13, 8237–8245.
Crossref Google Scholar
18

Wang, S.; Yu, J. H; Zhang, M. Y.; Chen, D. C.; Li, C. S.; Chen, R.; Jia, G. H.; Rogach, A. L.; Yang, X. Y. Stable, strongly emitting cesium lead bromide perovskite nanorods with high optical gain enabled by an intermediate monomer reservoir synthetic strategy. Nano Lett. 2019, 19, 6315–6322.
Crossref Google Scholar
19

Hudait, B.; Dutta, S. K.; Pradhan, N. Isotropic CsPbBr3 perovskite nanocrystals beyond nanocubes: Growth and optical properties. ACS Energy Lett. 2020, 5, 650–656.
Crossref Google Scholar
20

Yang, D. D.; Li, X. M.; Wu, Y.; Wei, C. T.; Qin, Z. Y.; Zhang, C. F.; Sun, Z. G.; Li, Y. L.; Wang, Y.; Zeng, H. B. Surface halogen compensation for robust performance enhancements of CsPbX3 perovskite quantum dots. Adv. Opt. Mater. 2019, 7, 1900276.
Crossref Google Scholar
21

Almeida, G.; Goldoni, L.; Akkerman, Q.; Dang, Z. Y.; Khan, A. H.; Marras, S.; Moreels, I.; Manna, L. Role of acid-base equilibria in the size, shape, and phase control of cesium lead bromide nanocrystals. ACS Nano 2018, 12, 1704–1711.
Crossref Google Scholar
22

Pradhan, N.; Reifsnyder, D.; Xie, R. G.; Aldana, J.; Peng, X. G. Surface ligand dynamics in growth of nanocrystals. J. Am. Chem. Soc. 2007, 129, 9500–9509.
Crossref Google Scholar
23
Persson, K. Materials Data on CsPbBr3 (SG: 140) by Materials Project. United States, 2016, DOI: 10.17188/1330982.
24

Bekenstein, Y.; Koscher, B. A.; Eaton, S. W.; Yang, P. D.; Alivisatos, A. P. Highly luminescent colloidal nanoplates of perovskite cesium lead halide and their oriented assemblies. J. Am. Chem. Soc. 2015, 137, 16008–16011.
Crossref Google Scholar
25

Wu, Y.; Li, X. M.; Zeng, H. B. Highly luminescent and stable halide perovskite nanocrystals. ACS Energy Lett. 2019, 4, 673–681.
Crossref Google Scholar
26

Pan, J.; Shang, Y. Q.; Yin, J.; De Bastiani, M.; Peng, W.; Dursun, I.; Sinatra, L.; El-Zohry, A. M.; Hedhili, M. N.; Emwas, A. H. et al. Bidentate ligand-passivated CsPbI3 perovskite nanocrystals for stable near-unity photoluminescence quantum yield and efficient red light-emitting diodes. J. Am. Chem. Soc. 2018, 140, 562–565.
Crossref Google Scholar
27

Hintermayr, V. A.; Polavarapu, L.; Urban, A. S.; Feldmann, J. Accelerated carrier relaxation through reduced coulomb screening in two-dimensional halide perovskite nanoplatelets. ACS Nano 2018, 12, 10151–10158.
Crossref Google Scholar
28

Peng, X. Mechanisms for the shape-control and shape-evolution of colloidal semiconductor nanocrystals. Adv. Mater. 2003, 15, 459–463.
Crossref Google Scholar
29

Yang, D. D.; Li, X. M.; Zhou, W. H.; Zhang, S. L.; Meng, C. F.; Wu, Y.; Wang, Y.; Zeng, H. B. CsPbBr3 quantum dots 2.0: Benzenesulfonic acid equivalent ligand awakens complete purification. Adv. Mater. 2019, 31, 1900767.
Crossref Google Scholar
30

Kresse, G.; Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 1996, 6, 15–50.
Crossref Google Scholar
31

Kresse, G.; Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B. 1996, 54, 11169–11186.
Crossref Google Scholar
32

Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868.
Crossref Google Scholar
33

Deacon, G. B.; Phillips, R. J. Relationships between the carbon- oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coordin. Chem. Rev. 1980, 33, 227–250.
Crossref Google Scholar
34

Zhang, J.; Zhang, H. B.; Cao, W. C.; Pang, Z. F.; Li, J. Z.; Shu, Y. F.; Zhu, C. Q.; Kong, X. Q.; Wang, L. J.; Peng, X. G. Identification of facet-dependent coordination structures of carboxylate ligands on CdSe nanocrystals. J. Am. Chem. Soc. 2019, 141, 15675–15683.
Crossref Google Scholar
35

Im, J. H.; Lee, C. R.; Lee, J. W.; Park, S. W.; Park, N. G. 6.5% efficient perovskite quantum-dot-sensitized solar cell. Nanoscale 2011, 3, 4088–4093.
Crossref Google Scholar
36

Świderski, G.; Kalinowska, M.; Świsłocka, R.; Wojtulewski, S.; Lewandowski, W. Spectroscopic (FT-IR, FT-Raman and 1H and 13C NMR) and theoretical in MP2/6–311++G(d, p) and B3LYP/ 6–311++G(d, p) levels study of benzenesulfonic acid and alkali metal benzenesulfonates. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2013, 100, 41–50.
Crossref Google Scholar
37

Zhu, Z.; Hadjiev, V. G.; Rong, Y. G.; Guo, R.; Cao, B.; Tang, Z. J.; Qin, F.; Li, Y.; Wang, Y. N.; Hao, F. et al. Interaction of organic cation with water molecule in perovskite MAPbI3: From dynamic orientational disorder to hydrogen bonding. Chem. Mater. 2016, 28, 7385–7393.
Crossref Google Scholar
38

Glaser, T.; Müller, C.; Sendner, M.; Krekeler, C.; Semonin, O. E.; Hull, T. D.; Yaffe, O.; Owen, J. S.; Kowalsky, W.; Pucci, A. et al. Infrared spectroscopic study of vibrational modes in methylammonium lead halide perovskites. J. Phys. Chem. Lett. 2015, 6, 2913–2918.
Crossref Google Scholar
39

Woo, J. Y.; Kim, Y.; Bae, J.; Kim, T. G.; Kim, J. W.; Lee, D. C.; Jeong, S. Highly stable cesium lead halide perovskite nanocrystals through in situ lead halide inorganic passivation. Chem. Mater. 2017, 29, 7088–7092.
Crossref Google Scholar
40

Liu, L. G.; Huang, S.; Pan, L. F.; Shi, L. J.; Zou, B. S.; Deng, L. G.; Zhong, H. Z. Colloidal synthesis of CH3NH3PbBr3 nanoplatelets with polarized emission through self-organization. Angew. Chem. , Int. Ed. 2017, 56, 1780–1783.
Crossref Google Scholar
41

Liu, Y.; Wu, Z. Y.; Liu, X. T.; Han, S. G.; Li, Y. B.; Yang, T.; Ma, Y.; Hong, M. C.; Luo, J. H.; Sun, Z. H. Intrinsic strong linear dichroism of multilayered 2D hybrid perovskite crystals toward highly polarized-sensitive photodetection. Adv. Opt. Mater. 2019, 7, 1901049.
Crossref Google Scholar
42

Gao, Y.; Zhao, L. Y.; Shang, Q. Y.; Zhong, Y. G.; Liu, Z.; Chen, J.; Zhang, Z. P.; Shi, J.; Du, W. N.; Zhang, Y. F. et al. Ultrathin CsPbX3 nanowire arrays with strong emission anisotropy. Adv. Mater. 2018, 30, 1801805.
Crossref Google Scholar
43

Shi, Y.; Duan, P.; Huo, S.; Li, Y.; Liu, M. Endowing perovskite nanocrystals with circularly polarized luminescence. Adv. Mater. 2018, 30, 1705011.
Crossref Google Scholar
44

Srivastava, A. K.; Zhang, W. L.; Schneider, J.; Rogach, A. L.; Chigrinov, V. G.; Kwok, H. S. Photoaligned nanorod enhancement films with polarized emission for liquid-crystal-display applications. Adv. Mater. 2017, 29, 1701091.
Crossref Google Scholar
45

Wang, D.; Wu, D.; Dong, D.; Chen, W.; Hao, J. J.; Qin, J.; Xu, B.; Wang, K.; Sun, X. W. Polarized emission from CsPbX3 perovskite quantum dots. Nanoscale 2016, 8, 11565–11570.
Crossref Google Scholar
46

He, J.; Towers, A.; Wang, Y. N.; Yuan, P. S.; Jiang, Z.; Chen, J. S.; Gesquiere, A. J.; Wu, S. T.; Dong, Y. J. In situ synthesis and macroscale alignment of CsPbBr3 perovskite nanorods in a polymer matrix. Nanoscale 2018, 10, 15436–15441.
Crossref Google Scholar
47

Shi, Z. F.; Li, Y.; Li, S.; Ji, H. F.; Lei, L. Z.; Wu, D.; Xu, T. T.; Xu, J. M.; Tian, Y. T.; Li, X. J. Polarized emission effect realized in CH3NH3PbI3 perovskite nanocrystals. J. Mater. Chem. C. 2017, 5, 8699–8706.
Crossref Google Scholar
48

Dou, Y. J.; Cao, F.; Dudka, T.; Li, Y. G.; Wang, S.; Zhang, C. X.; Gao, Y.; Yang, X. Y.; Rogach, A. L. Lattice distortion in mixed-anion lead halide perovskite nanorods leads to their high fluorescence anisotropy. ACS Mater. Lett. 2020, 2, 814–820.
Crossref Google Scholar
49

Meng, L. H.; Yang, C. G.; Meng, J. J.; Wang, Y. Z.; Ge, Y.; Shao, Z. Q.; Zhang, G. F.; Rogach, A. L.; Zhong, H. Z. In-situ fabricated anisotropic halide perovskite nanocrystals in polyvinylalcohol nanofibers: Shape tuning and polarized emission. Nano Res. 2019, 12, 1411–1416.
Crossref Google Scholar
50

Raja, S. N.; Bekenstein, Y.; Koc, M. A.; Fischer, S.; Zhang, D. D.; Lin, L. W.; Ritchie, R. O.; Yang, P. D.; Alivisatos, A. P. Encapsulation of perovskite nanocrystals into macroscale polymer matrices: Enhanced stability and polarization. ACS Appl. Mater. Interfaces 2016, 8, 35523–35533.
Crossref Google Scholar
Nano Research
Volume 15 Issue 1,
January 2022
Pages 502-509
DOI: 10.1007/s12274-021-3509-6
Cite this article:
Yang D, Li X, Li Y, et al. Facet-induced coordination competition for highly ordered CsPbBr3 nanoplatelets with strong polarized emission. Nano Research, 2022, 15(1): 502-509. https://doi.org/10.1007/s12274-021-3509-6
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Received: 01 February 2021
Revised: 08 April 2021
Accepted: 08 April 2021
Published: 09 July 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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