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Research Article

Atomic Co/Ni dual sites with N/P-coordination as bifunctional oxygen electrocatalyst for rechargeable zinc–air batteries

Botao Hu1,§, Aijian Huang1,2,§, Xuejiang Zhang3, Zheng Chen4, Renyong Tu1, Wei Zhu3, Zhongbin Zhuang3, Chen Chen1( ), Qing Peng1( ), Yadong Li1( )
Department of Chemistry,Tsinghua University,Beijing,100084,China;
School of Electronics Science and Engineering,University of Electronic Science and Technology of China,Chengdu,610054,China;
College of Chemical Engineering,Beijing University of Chemical Technology,Beijing,100029,China;
College of Chemistry and Materials Science,Anhui Normal University,Wuhu,241000,China;

§ Botao Hu and Aijian Huang contributed equally to this work.

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Graphical Abstract

Abstract

Metal-nitrogen-carbon (M-N-C) single-atom catalysts exhibit desirable electrochemical catalytic properties. However, the replacement of N atoms by heteroatoms (B, P, S, etc.) has been regarded as a useful method for regulating the coordination environment. The structure engineered M-N-C sites via doping heteroatoms play an important role to the adsorption and activation of the oxygen intermediate. Herein, we develop an efficient strategy to construct dual atomic site catalysts via the formation of a Co1-PN and Ni1-PN planar configuration. The developed Co1-PNC/Ni1-PNC catalyst exhibits excellent bifunctional electrocatalytic performance in alkaline solution. Both experimental and theoretical results demonstrated that the N/P coordinated Co/Ni sites moderately reduced the binding interaction of oxygen intermediates. The Co1-PNC/Ni1-PNC endows a rechargeable Zn-air battery with excellent power density and cycling stability as an air-cathode, which is superior to that of the benchmark Pt/C+IrO2. This work paves an avenue for design of dual single-atomic sites and regulation of the atomic configuration on carbon-based materials to achieve high-performance electrocatalysts.

Keywords

single-atom catalystsdual atomic sitesbifunctional electrocatalystmetal-organic frameworkZn-air battery

Electronic Supplementary Material

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Nano Research
Volume 14 Issue 10,
October 2021
Pages 3482-3488
DOI: 10.1007/s12274-021-3535-4
Cite this article:
Hu B, Huang A, Zhang X, et al. Atomic Co/Ni dual sites with N/P-coordination as bifunctional oxygen electrocatalyst for rechargeable zinc–air batteries. Nano Research, 2021, 14(10): 3482-3488. https://doi.org/10.1007/s12274-021-3535-4
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Received: 23 February 2021
Revised: 22 April 2021
Accepted: 22 April 2021
Published: 23 May 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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