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Research Article

Highly dispersed Pt clusters encapsulated in MIL-125-NH2 via in situ auto-reduction method for photocatalytic H2 production under visible light

Xiubing Huang§( ), Xiangjun Li§, Qingjie Luan§, Kaiyue Zhang, Zhenyu Wu, Baozhen Li, Zuoshuai Xi, Wenjun Dong, Ge Wang( )
Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory of Function Materials for Molecule & Structure Construction School of Materials Science and Engineering University of Science and Technology Beijing Beijing 10083 China

§Xiubing Huang, Xiangjun Li, and Qingjie Luan contributed equally to this work

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Abstract

Efficient hydrogen production via photocatalysis with high utilization efficiency of Pt cocatalyst is of great importance for sustainable development. In this work, we report an in situ auto-reduction strategy to encapsulate highly dispersed Pt clusters inside the cages of MIL-125-NH2. The amino groups in MIL-125-NH2 first react with formaldehyde to form reducing groups (i.e., –NH-CH2OH), which can in situ auto-reduce the confined Pt2+ ions to ultrasmall Pt clusters within the cavities. With optimized Pt content, photocatalytic H2 production over the obtained Pt(1.5)/MIL-125-NH-CH2OH catalyst with 1.43 wt.% Pt loading achieved as high as 4, 496.4 µmol·g−1·h−1 under visible light (λ > 420 nm) due to the facilitated transfer and separation of the photo-induced charger carriers arising from the synergetic effects between highly dispersed Pt clusters and MIL-125-NH-CH2OH framework. This in situ auto-reduction strategy may be extended to encapsulate various kinds of metal or alloy clusters/nanoparticles within amino-functioned metal-organic frameworks (MOFs) with superior properties and excellent performance.

Keywords

Pt clustersMIL-125-NH2in situ auto-reduction methodphotocatalytic H2 productionvisible light

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Nano Research
Volume 14 Issue 11,
November 2021
Pages 4250-4257
DOI: 10.1007/s12274-021-3597-3
Cite this article:
Huang X, Li X, Luan Q, et al. Highly dispersed Pt clusters encapsulated in MIL-125-NH2 via in situ auto-reduction method for photocatalytic H2 production under visible light. Nano Research, 2021, 14(11): 4250-4257. https://doi.org/10.1007/s12274-021-3597-3
Topics:
Photocatalysts

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Received: 01 April 2021
Revised: 10 May 2021
Accepted: 16 May 2021
Published: 14 July 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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