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Research Article

Zephyranthes-like Co2NiSe4 arrays grown on 3D porous carbon frame-work as electrodes for advanced supercapacitors and sodium-ion batteries

Yanchun Xue1, Xingmei Guo1, Mengrong Wu1, Jiale Chen1, Mengting Duan1, Jing Shi1, Junhao Zhang1( ), Fu Cao1, Yuanjun Liu1, Qinghong Kong2
School of Environmental and Chemical Engineering,Jiangsu University of Science and Technology,Zhenjiang,212003,China;
School of the Environment and Safety Engineering,Jiangsu University,Zhenjiang,212013,China;
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Graphical Abstract

Abstract

Developing suitable electrode materials for electrochemical energy storage devices by biomorph assisted design has become a fascinating topic due to the fantastic properties derived from bio-architectures. Herein, zephyranthes-like Co2NiSe4 arrays grown on butterfly wings derived three-dimensional (3D) carbon framework (Z-Co2NiSe4/BWC) is fabricated via hydrothermal assembly and further conversion method. Benefiting from its unique structure and multi-components, the obtained Z-Co2NiSe4/BWC electrode for supercapacitor delivers an excellent specific capacitance of 2, 280 F·g−1 at 1 A·g−1. Impressively, the constructed asymmetric supercapacitor using Co2NiSe4/BWC as positive electrode and activated butterfly wings carbon as negative electrode acquires a high energy density of 42.9 Wh·kg−1 at a power density of 800 W·kg−1 with robust stability of 94.6% capacitance retention at 10 A·g−1 after 5, 000 cycles. Moreover, the Z-Co2NiSe4/BWC as anode for sodium-ion batteries exhibits a high specific capacity of 568 mAh·g−1 at 0.1 A·g−1 and high cycling stability (maintaining 80.1% of the second cycle after 100 cycles). The outstanding electrochemical performances are ascribed to that the synergistic effect of bimetallic selenides and N-doped carbon improves electrochemical activities and conductivity. One-dimensional (1D) nanoneedles grown on 3D porous framework increase the exposure of redox-active sites, endow adequate transmission channels of electrons/ions, and guarantee stability of the electrode during charge/discharge processes. This study will shed light on the avenue towards extending such nanohybrids to excellent energy storage applications.

Keywords

Co2NiSe4three-dimensional (3D) carbon frameworksynergistic effectsupercapacitorssodium-ion batteries

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Nano Research
Volume 14 Issue 10,
October 2021
Pages 3598-3607
DOI: 10.1007/s12274-021-3640-4
Cite this article:
Xue Y, Guo X, Wu M, et al. Zephyranthes-like Co2NiSe4 arrays grown on 3D porous carbon frame-work as electrodes for advanced supercapacitors and sodium-ion batteries. Nano Research, 2021, 14(10): 3598-3607. https://doi.org/10.1007/s12274-021-3640-4
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Received: 07 March 2021
Revised: 25 May 2021
Accepted: 02 June 2021
Published: 28 June 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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