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Research Article

Construction and electrochemical mechanism investigation of hierarchical core-shell like composite as high performance anode for potassium ion batteries

Nadeem Hussain1,3, Suyuan Zeng2, Zhenyu Feng1, Yanjun Zhai2, Chunsheng Wang1, Mingwen Zhao4( ), Yitai Qian1, Liqiang Xu1,2( )
Key Laboratory of Colloid & Interface Chemistry,Ministry of Education and School of Chemistry and Chemical Engineering, Shandong University,Jinan,250100,China;
Shandong Provincial Key Laboratory/Collaborative Innovation Center of Chemical Energy Storage & Novel Cell Technology,Liaocheng University,Liaocheng,252059,China;
International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology (Ministry of Education),Institute of Microscale Optoelectronics, Shenzhen University,Shenzhen,518060,China;
School of Physics,Shandong University,Jinan,250100,China;
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Abstract

Potassium-ion batteries (PIBs) are promising candidates for next-generation energy storage devices due to the earth abundance of potassium, low cost, and stable redox potentials. However, the lack of promising high-performance electrode materials for the intercalation/deintercalation of large potassium ions is a major challenge up to date. Herein, we report a novel uniform nickel selenide nanoparticles encapsulated in nitrogen-doped carbon (defined as pNiSe@NCq) as an anode for PIBs, which exhibits superior rate performance and cyclic stability. Benefiting from the unique hierarchical core-shell like nanostructure, the intrinsic properties of metal-selenium bonds, synergetic effect of different components, and a remarkable pseudocapacitance effect, the anode exhibits a very high reversible capacity of 438 mAdhdg-1 at 50 mAdg-1, an excellent rate capability, and remarkable cycling performance over 2, 000 cycles. The electrochemical mechanism were investigated by the in-situ X-ray diffraction, ex-situ high-resolution transmission electron microscopy, selected area electron diffraction, and first principle calculations. In addition, NiSe@NC anode also shows high reversible capacity of 512 mAdhdg-1 at 100 mAdg-1 with 84% initial Coulombic efficiency, remarkable rate performance, and excellent cycling life for sodium ion batteries. We believe the proposed simple approach will pave a new way to synthesize suitable anode materials for secondary ion batteries.

Keywords

core-shellpseudocapacitancein-situ X-ray diffraction (XRD)first principle calculationspotassium-ion batteries

Electronic Supplementary Material

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Nano Research
Volume 14 Issue 10,
October 2021
Pages 3552-3561
DOI: 10.1007/s12274-021-3657-8
Cite this article:
Hussain N, Zeng S, Feng Z, et al. Construction and electrochemical mechanism investigation of hierarchical core-shell like composite as high performance anode for potassium ion batteries. Nano Research, 2021, 14(10): 3552-3561. https://doi.org/10.1007/s12274-021-3657-8
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Received: 15 March 2021
Revised: 04 June 2021
Accepted: 06 June 2021
Published: 08 July 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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