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Research Article

Dislocation-strained MoS2 nanosheets for high-efficiency hydrogen evolution reaction

Shihao Wang1,§, Longlu Wang1,§( ), Lingbin Xie2, Weiwei Zhao2, Xia Liu3( ), Zechao Zhuang4, YanLing Zhuang1, Jing Chen1, Shujuan Liu2, Qiang Zhao1,2 ( )
College of Electronic and Optical Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China
Key Laboratory for Organic Electronics and Information Displays and Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM) and Institute of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing 210023, China
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China
Department of Chemistry, Tsinghua University, Beijing 100084, China

§ Shihao Wang and Longlu Wang contributed equally to this work.

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Graphical Abstract

Defect engineering is an effective means to improve the catalytic performance of MoS2 for hydrogenevolution reaction (HER). Here, we synthesized flexible dislocation-strained MoS2 nanosheets toachieve efficiency HER under visible light.

Abstract

Defect engineering is one of the effective strategies to optimize the physical and chemical properties of molybdenum disulfide (MoS2) to improve catalytic hydrogen evolution reaction (HER) performance. Dislocations, as a typical defect structure, are worthy of further investigation due to the versatility and sophistication of structures and the influence of local strain effects on the catalytic performance. Herein, this study adopted a low-temperature hydrothermal synthesis strategy to introduce numerous dislocation-strained structures into the in-plane and out-of-plane of MoS2 nanosheets. Superior HER catalytic activity of 5.85 mmol·g−1·h−1 under visible light was achieved based on the high-density dislocations and the corresponding strain field. This work paves a new pathway for improving the catalytic activity of MoS2 via a dislocation-strained synergistic modulation strategy.

Keywords

molybdenum disulfidedislocationstrainhydrogen evolution reaction

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Nano Research
Volume 15 Issue 6,
June 2022
Pages 4996-5003
DOI: 10.1007/s12274-022-4158-0
Cite this article:
Wang S, Wang L, Xie L, et al. Dislocation-strained MoS2 nanosheets for high-efficiency hydrogen evolution reaction. Nano Research, 2022, 15(6): 4996-5003. https://doi.org/10.1007/s12274-022-4158-0
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Received: 19 December 2021
Revised: 12 January 2022
Accepted: 13 January 2022
Published: 10 March 2022
© Tsinghua University Press 2022
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