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Research Article

High-definition colorful perovskite narrowband photodetector array enabled by laser-direct-writing

Xiaobao XuYuhang DongYuanzhou ZhangZeyao HanJiaxin LiuDejian YuYi WeiYousheng Zou( )Bo HuangJun ChenHaibo Zeng( )
Key Laboratory of Advanced Display Materials and Devices, Ministry of Industry and Information Technology, Institute of Optoelectronics & Nanomaterials, College of Material Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
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Graphical Abstract

Under laser irradiation, the photolysis of halocarbon solvent provides the halideions, which react with CsPbBr3 and giving into the manipulated bandgap, forexample, CsPb(Cl/Br)3 and CsPb(Br/I)3. By optimizing the laser printing process,the programmable full-color patterning perovskite film is achieved. The colorfulnarrowband photodetectors array responding to blue and green photons isfabricated with the high-definition of ~ 53 ppi.

Abstract

Narrowband photodetectors as specific spectral sensing pixels have drawn intense attention in multispectral detection due to their distinct characteristic of filter-free spectrum discrimination, in which the emerging halide lead perovskites witness a booming development in their performance and wavelength-selectivity from blue to near-infrared light. However, the challenge in integrating perovskite narrowband photodetectors on one chip imposes an impediment on practical application. In this work, the combination of laser-direct-writing and ion exchange is proposed as an efficient way to fabricate high-definition colorful sensing array with perovskite narrowband photodetector unit as pixel. Under laser irradiation, the photolysis of halocarbon solvent (CHCl3, CH3CH2I, etc) releases the halide ions, which brings the ion exchange and gives rise to slow-varying bandgap in single perovskite photoactive film. This ion exchange can be controlled via laser irradiation time and focus point, thus enabling precisely engineerable bandgap. By optimizing the process, it is successfully applied to develop patterned perovskite narrow blue and green photodetectors array with a high-definition of ~ 53 ppi. We believe this result will make a great step forward to integrate multifunctional perovskite devices on one chip, which will pave the way for perovskite optoelectronic device to the commercial application.

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Nano Research
Pages 5476-5482
Cite this article:
Xu X, Dong Y, Zhang Y, et al. High-definition colorful perovskite narrowband photodetector array enabled by laser-direct-writing. Nano Research, 2022, 15(6): 5476-5482. https://doi.org/10.1007/s12274-022-4163-3
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Received: 21 October 2021
Revised: 13 January 2022
Accepted: 13 January 2022
Published: 10 March 2022
© Tsinghua University Press 2022
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