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Research Article

Compact Sn/C composite realizes long-life sodium-ion batteries

Mingdong Tan, Shuanghui Han, Zhenbang Li, Hao Cui, Danni Lei( ), Chengxin Wang( )
State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China
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Graphical Abstract

The commercial applications of sodium-ion batteries are limited by the harsh preparation conditions and unsatisfactory electrochemical performances of most anode materials. Herein, a compact and stable Sn/C composite anode is developed based on a simple alloying/dealloying method for a long-life and high-energy sodium-ion battery.

Abstract

Sodium-ion batteries are considered as a promising low-cost alternative to commercial lithium-ion batteries. However, the harsh preparation conditions and unsatisfactory electrochemical performance of most sodium-ion batteries anode materials limit their commercial applications. Herein, we develop a new alloying/dealloying method for producing nano-scale tin from freezing point to room temperature. Due to the unique surface properties of tin particles, a tin/carbon composite with a compact structure is obtained. When coupled with a diglyme-based electrolyte, tin/carbon composite (contains 60 wt.% tin) exhibits a reversible capacity of 334.8 mAh·g−1 after 1,000 cycles at 500 mA·g−1. An as-prepared tin/carbon anode||high-load vanadium phosphate sodium full cell (N/P ratio: 1.07) shows a stable cycle life of 300 cycles at 1 A·g−1. The achievement of such an excellent performance can be ascribed to the carbon conductive network and robust solid electrolyte interphase film, which facilitates the fast transportation of electrons and Na ions. This work provides a new idea to prepare other alloyed anode materials for high-performance sodium-ion batteries.

Keywords

sodium-ion batteriesalloying/dealloying methodcompact tin/carbon composite

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Nano Research
Volume 16 Issue 3,
March 2023
Pages 3804-3813
DOI: 10.1007/s12274-022-4255-0
Cite this article:
Tan M, Han S, Li Z, et al. Compact Sn/C composite realizes long-life sodium-ion batteries. Nano Research, 2023, 16(3): 3804-3813. https://doi.org/10.1007/s12274-022-4255-0
Topics:
Ion batteries
Part of a topical collection:
Women’s Special Issue: Nanomaterials: Preparation, Applications, and Challenges

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Received: 15 December 2021
Revised: 16 February 2022
Accepted: 19 February 2022
Published: 19 March 2022
© Tsinghua University Press 2022
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