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Research Article

Improved anticorrosion performance of mixed valence Mn-modified ZnO dilute magnetic solid solution with multilevel self-assembled network structure

Yi-Xiang Chen1, Dan Zhou1, Xiao-Jiao Guo1,2, Xiu Yang1,2, Si-Rui Zhao1, Yi Lu1,2, Jin-Ku Liu1( )
Key Laboratory for Advanced Materials, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
Material Corrosion and Protection, Key Laboratory of Sichuan Province, Zigong 643000, China
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Graphical Abstract

ZnO-based dilute magnetic solid solution (DMSs) with hydrophobic micronano network structure was synthesized for steel corrosion protection, which was further imparted with dilute magnetic properties through the doping of mixed-valence Mn elements. The corrosion protection mechanism could be summarized into three parts: (a) magnetically induced electron transfer effect, (b) tertiary shielding effect of multilevel self-assembled network nanostructure, and (c) anode replacement and photocathode protection.

Abstract

The design and performance prediction of efficient anticorrosion materials is a work full of value, novelty, and challenges. In this work, from the perspective of nanostructure and composition, ZnO-based dilute magnetic solid solution (DMSs) with hydrophobic micronano network structure was synthesized through the self-induced effect of raw materials, the impact-resistant network structure, complex micro-channels, and densely nested layers resisted electrolyte intrusion. Further, the doping of mixed valence Mn element endowed the solid solution with dilute magnetic properties, so the Lorentz force from micromagnetic field changed the movement path of electrons produced by the anode reaction to improve the corrosion inhibition ability of the protective layer. Under the synergy of morphology and magnetism, the corrosion resistance of the DMSs materials was 555.4% and 173.8% higher than that of epoxy resin and ZnO shielding layer, respectively. Besides, a valuable phenomenon was found that the photocatalytic property of DMSs materials was positively correlated with their corrosive defense. In conclusion, this research provided a novel design idea for new high-efficiency anticorrosion materials.

Keywords

Mn-modified ZnO dilute magnetic solid solutionnetwork nanostructureanticorrosionfunctional nanomaterials

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Nano Research
Volume 15 Issue 7,
July 2022
Pages 6590-6600
DOI: 10.1007/s12274-022-4278-6
Cite this article:
Chen Y-X, Zhou D, Guo X-J, et al. Improved anticorrosion performance of mixed valence Mn-modified ZnO dilute magnetic solid solution with multilevel self-assembled network structure. Nano Research, 2022, 15(7): 6590-6600. https://doi.org/10.1007/s12274-022-4278-6
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Received: 19 February 2022
Revised: 24 February 2022
Accepted: 24 February 2022
Published: 02 May 2022
© Tsinghua University Press 2022
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