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Research Article

Strong and conductive reduced graphene oxide-MXene porous films for efficient electromagnetic interference shielding

Yu Zhang1,2, Ming-Ke Xu2, Zhenguo Wang1, Tianyu Zhao1, Liu-Xin Liu1,2, Hao-Bin Zhang1( ), Zhong-Zhen Yu2
State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Beijing Key Laboratory of Advanced Functional Polymer Composites, Beijing University of Chemical Technology, Beijing 100029, China
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Graphical Abstract

A reduced graphene oxide (rGO)-Ti3C2Tx MXene (rG-M) porous film with the optimizedinterconnected structure, prepared by a controlled foaming process, exhibits a large tensile strength andis efficient for electromagnetic interference shielding with balanced apparent density andelectrical conductivity.

Abstract

Lightweight, flexible, and electrically conductive porous films are promising for efficient electromagnetic interference (EMI) shielding. However, the mechanical and electrical properties of porous films are far from optimum. Herein, we fabricate mechanically flexible and electrically conductive reduced graphene oxide (rGO)-Ti3C2Tx MXene (rG-M) porous films with optimized continuous cellular morphology by a controlled hydrazine foaming process. The presence of MXene prevents excessive expansion of the rG-M film, improves the electron conduction paths, and enhances the mechanical properties. The resultant rG-M porous film has superior mechanical and electric performances compared to its rGO counterpart, giving one of the highest tensile strengths (24.5 MPa) among the porous films, a high electrical conductivity of 74.4 S·cm−1, and an excellent broadband EMI shielding from 8 to 26.5 GHz. A high EMI shielding effectiveness of 52.6 dB is achieved for the porous film by adjusting its thickness and treatment procedure, providing a feasible fabrication route for lightweight and high-performance EMI shielding materials.

Keywords

grapheneMXeneelectromagnetic interference shieldingporous filmselectrical conductivity

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References

1

Yun, T.; Kim, H.; Iqbal, A.; Cho, Y. S.; Lee, G. S.; Kim, M. K.; Kim, S. J.; Kim, D.; Gogotsi, Y.; Kim, S. O. et al. Electromagnetic shielding of monolayer MXene assemblies. Adv. Mater. 2020, 32, 1906769.
Crossref Google Scholar
2

Liu, L. Y.; Deng, H.; Tang, X. P.; Lu, Y. X.; Zhou, J. Y.; Wang, X. F.; Zhao, Y. Y.; Huang, B.; Shi, Y. G. Specific electromagnetic radiation in the wireless signal range increases wakefulness in mice. Proc. Natl. Acad. Sci. USA 2021, 118, e2105838118.
Crossref Google Scholar
3
Ma, Z. L.; Xiang, X. L.; Shao, L.; Zhang, Y. L.; Gu, J. W. Multifunctional wearable silver nanowire decorated leather nanocomposites for joule heating, electromagnetic interference shielding and piezoresistive sensing. Angew. Chem., Int. Ed., in press, https://doi.org/10.1002/anie.202200705.
Crossref
4

Zeng, Z. H.; Jiang, F. Z.; Yue, Y.; Han, D. X.; Lin, L. C.; Zhao, S. Y.; Zhao, Y. B.; Pan, Z. Y.; Li, C. J.; Nyström, G. et al. Flexible and ultrathin waterproof cellular membranes based on high-conjunction metal-wrapped polymer nanofibers for electromagnetic interference shielding. Adv. Mater. 2020, 32, 1908496.
Crossref Google Scholar
5

Chen, Y.; Li, J. Z.; Li, T.; Zhang, L. K.; Meng, F. B. Recent advances in graphene-based films for electromagnetic interference shielding: Review and future prospects. Carbon 2021, 180, 163–184.
Crossref Google Scholar
6

Balci, O.; Polat, E. O.; Kakenov, N.; Kocabas, C. Graphene-enabled electrically switchable radar-absorbing surfaces. Nat. Commun. 2015, 6, 6628.
Crossref Google Scholar
7

Li, T.; Zhi, D. D.; Guo, Z. H.; Li, J. Z.; Chen, Y.; Meng, F. B. 3D porous biomass-derived carbon materials: Biomass sources, controllable transformation and microwave absorption application. Green Chem. 2022, 24, 647–674.
Crossref Google Scholar
8

Wang, L.; Ma, Z. L.; Zhang, Y. L.; Chen, L. X.; Cao, D. P.; Gu, J. W. Polymer-based EMI shielding composites with 3D conductive networks: A mini-review. SusMat 2021, 1, 413–431.
Crossref Google Scholar
9

Zhang, H. B.; Yan, Q.; Zheng, W. G.; He, Z. X.; Yu, Z. Z. Tough graphene-polymer microcellular foams for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 2011, 3, 918–924.
Crossref Google Scholar
10

Liu, J.; Zhang, H. B.; Sun, R. H.; Liu, Y. F.; Liu, Z. S.; Zhou, A. G.; Yu, Z. Z. Hydrophobic, flexible, and lightweight MXene foams for high-performance electromagnetic-interference shielding. Adv. Mater. 2017, 29, 1702367.
Crossref Google Scholar
11

Park, S.; Ruoff, R. S. Chemical methods for the production of graphenes. Nat. Nanotechnol. 2009, 4, 217–224.
Crossref Google Scholar
12

Chang, C.; Chen, W.; Chen, Y.; Chen, Y. H.; Chen, Y.; Ding, F.; Fan, C. H.; Fan, H. J.; Fan, Z. X.; Gong, C. et al. Recent progress on two-dimensional materials. Acta Phys. Chim. Sin. 2021, 37, 2108017.
Crossref Google Scholar
13

Naguib, M.; Mochalin, V. N.; Barsoum, M. W.; Gogotsi, Y. 25th anniversary article: MXenes: A new family of two-dimensional materials. Adv. Mater. 2014, 26, 992–1005.
Crossref Google Scholar
14

Zhang, M.; Cao, M. S.; Shu, J. C.; Cao, W. Q.; Li, L.; Yuan, J. Electromagnetic absorber converting radiation for multifunction. Mater. Sci. Eng. R: Rep. 2021, 145, 100627.
Crossref Google Scholar
15

Cao, M. S.; Shu, J. C.; Wen, B.; Wang, X. X.; Cao, W. Q. Genetic dielectric genes inside 2D carbon-based materials with tunable electromagnetic function at elevated temperature. Small Struct. 2021, 2, 2100104.
Crossref Google Scholar
16

Zhang, P.; Zhu, Q. Z.; Soomro, R. A.; He, S. Y.; Sun, N.; Qiao, N.; Xu, B. In situ ice template approach to fabricate 3D flexible MXene film-based electrode for high performance supercapacitors. Adv. Funct. Mater. 2020, 30, 2000922.
Crossref Google Scholar
17

Lv, W.; Li, Z. J.; Zhou, G. M.; Shao, J. J.; Kong, D. B.; Zheng, X. Y.; Li, B. H.; Li, F.; Kang, F. Y.; Yang, Q. H. Tailoring microstructure of graphene-based membrane by controlled removal of trapped water inspired by the phase diagram. Adv. Funct. Mater. 2014, 24, 3456–3463.
Crossref Google Scholar
18

Song, P.; Ma, Z. L.; Qiu, H.; Ru, Y. F.; Gu, J. W. High-efficiency electromagnetic interference shielding of rGO@FeNi/epoxy composites with regular honeycomb structures. Nano-Micro Lett. 2022, 14, 51.
Crossref Google Scholar
19

Zhao, M. Q.; Xie, X. Q.; Ren, C. E.; Makaryan, T.; Anasori, B.; Wang, G. X.; Gogotsi, Y. Hollow MXene spheres and 3D macroporous MXene frameworks for Na-ion storage. Adv. Mater. 2017, 29, 1702410.
Crossref Google Scholar
20

Niu, Z. Q.; Chen, J.; Hng, H. H.; Ma, J.; Chen, X. D. A leavening strategy to prepare reduced graphene oxide foams. Adv. Mater. 2012, 24, 4144–4150.
Crossref Google Scholar
21

Lai, D. G.; Chen, X. X.; Wang, Y. Controllable fabrication of elastomeric and porous graphene films with superior foldable behavior and excellent electromagnetic interference shielding performance. Carbon 2020, 158, 728–737.
Crossref Google Scholar
22

Song, Z. Q.; Li, W. Y.; Bao, Y.; Kong, H. J.; Gan, S. Y.; Wang, W.; Liu, Z. B.; Ma, Y. M.; Han, D. X.; Niu, L. Space-confined graphene films for pressure-sensing applications. ACS Appl. Nano Mater. 2020, 3, 1731–1740.
Crossref Google Scholar
23

Lai, D. G.; Chen, X. X.; Wang, G.; Xu, X. H.; Wang, Y. Highly conductive porous graphene film with excellent folding resilience for exceptional electromagnetic interference shielding. J. Mater. Chem. C 2020, 8, 8904–8916.
Crossref Google Scholar
24

Natu, V.; Sokol, M.; Verger, L.; Barsoum, M. W. Effect of edge charges on stability and aggregation of Ti3C2Tz MXene colloidal suspensions. J. Phys. Chem. C 2018, 122, 27745–27753.
Crossref Google Scholar
25

Qu, D.; Zheng, M.; Zhang, L. G.; Zhao, H. F.; Xie, Z. G.; Jing, X. B.; Haddad, R. E.; Fan, H. Y.; Sun, Z. C. Formation mechanism and optimization of highly luminescent N-doped graphene quantum dots. Sci. Rep. 2014, 4, 5294.
Crossref Google Scholar
26

Sambyal, P.; Iqbal, A.; Hong, J.; Kim, H.; Kim, M. K.; Hong, S. M.; Han, M. K.; Gogotsi, Y.; Koo, C. M. Ultralight and mechanically robust Ti3C2Tx hybrid aerogel reinforced by carbon nanotubes for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 2019, 11, 38046–38054.
Crossref Google Scholar
27

Choi, H. K.; Lee, A.; Park, M.; Lee, D. S.; Bae, S.; Lee, S. K.; Lee, S. H.; Lee, T.; Kim, T. W. Hierarchical porous film with layer-by-layer assembly of 2D copper nanosheets for ultimate electromagnetic interference shielding. ACS Nano 2021, 15, 829–839.
Crossref Google Scholar
28

Fu, H. L.; Yang, Z. P.; Zhang, Y. Y.; Zhu, M.; Jia, Y. H.; Chao, Z.; Hu, D. M.; Li, Q. W. SWCNT-modulated folding-resistant sandwich-structured graphene film for high-performance electromagnetic interference shielding. Carbon 2020, 162, 490–496.
Crossref Google Scholar
29

Zhong, J.; Sun, W.; Wei, Q. W.; Qian, X. T.; Cheng, H. M.; Ren, W. C. Efficient and scalable synthesis of highly aligned and compact two-dimensional nanosheet films with record performances. Nat. Commun. 2018, 9, 3484.
Crossref Google Scholar
30

Fu, Q. L.; Chen, Y.; Sorieul, M. Wood-based flexible electronics. ACS Nano 2020, 14, 3528–3538.
Crossref Google Scholar
31

Kuo, P. Y.; Wang, S. Y.; Chen, J. H.; Hsueh, H. C.; Tsai, M. J. Effects of material compositions on the mechanical properties of wood-plastic composites manufactured by injection molding. Mater. Des. 2009, 30, 3489–3496.
Crossref Google Scholar
32

Smorygo, O.; Gokhale, A. A.; Vazhnova, A.; Stefan, A. Ultra-low density epoxy/polystyrene foam composite with high specific strength and pseudo-plastic behavior. Compos. Commun. 2019, 15, 64–67.
Crossref Google Scholar
33

Easton, M.; Song, W. Q.; Abbott, T. A comparison of the deformation of magnesium alloys with aluminium and steel in tension, bending and buckling. Mater. Des. 2006, 27, 935–946.
Crossref Google Scholar
34

Simon, R. M. EMI shielding through conductive plastics. Polym. Plast. Technol. Eng. 1981, 17, 1–10.
Crossref Google Scholar
35

Zhang, M. K.; Zhang, P. J.; Zhang, C. L.; Wang, Y. S.; Chang, H.; Rao, W. Porous and anisotropic liquid metal composites with tunable reflection ratio for low-temperature electromagnetic interference shielding. Appl. Mater. Today 2020, 19, 100612.
Crossref Google Scholar
36

Li, X. P.; Zeng, S. P.; E, S. J.; Liang, L. Y.; Bai, Z. Y.; Zhou, Y. Y.; Zhao, B.; Zhang, R. Quick heat dissipation in absorption-dominated microwave shielding properties of flexible poly(vinylidene fluoride)/carbon nanotube/Co composite films with anisotropy-shaped Co (flowers or chains). ACS Appl. Mater. Interfaces 2018, 10, 40789–40799.
Crossref Google Scholar
37

Song, Q.; Ye, F.; Yin, X. W.; Li, W.; Li, H. J.; Liu, Y. S.; Li, K. Z.; Xie, K. Y.; Li, X. H.; Fu, Q. G. et al. Carbon nanotube-multilayered graphene edge plane core–shell hybrid foams for ultrahigh-performance electromagnetic-interference shielding. Adv. Mater. 2017, 29, 1701583.
Crossref Google Scholar
38

Lalan, V.; Subodh, G. The smallest anions, induced porosity and graphene interfaces in C12A7:e− electrides: A paradigm shift in electromagnetic absorbers and shielding materials. J. Mater. Chem. C 2022, 10, 969–982.
Crossref Google Scholar
39

Wang, X. X.; Zhang, M.; Shu, J. C.; Wen, B.; Cao, W. Q.; Cao, M. S. Thermally-tailoring dielectric “genes” in graphene-based hetero-structure to manipulate electromagnetic response. Carbon 2021, 184, 136–145.
Crossref Google Scholar
40

Cao, M. S.; Wang, X. X.; Cao, W. Q.; Fang, X. Y.; Wen, B.; Yuan, J. Thermally driven transport and relaxation switching self-powered electromagnetic energy conversion. Small 2018, 14, 1800987.
Crossref Google Scholar
41

Hart, J. L.; Hantanasirisakul, K.; Lang, A. C.; Anasori, B.; Pinto, D.; Pivak, Y.; van Omme, J. T.; May, S. J.; Gogotsi, Y.; Taheri, M. L. Control of MXenes’ electronic properties through termination and intercalation. Nat. Commun. 2019, 10, 522.
Crossref Google Scholar
42

Iqbal, A.; Shahzad, F.; Hantanasirisakul, K.; Kim, M. K.; Kwon, J.; Hong, J.; Kim, H.; Kim, D.; Gogotsi, Y.; Koo, C. M. Anomalous absorption of electromagnetic waves by 2D transition metal carbonitride Ti3CNTx (MXene). Science 2020, 369, 446–450.
Crossref Google Scholar
43

Shui, X. P.; Chung, D. D. L. Nickel filament polymer-matrix composites with low surface impedance and high electromagnetic interference shielding effectiveness. J. Electron. Mater. 1997, 26, 928–934.
Crossref Google Scholar
44

Shahzad, F.; Alhabeb, M.; Hatter, C. B.; Anasori, B.; Hong, S. M.; Koo, C. M.; Gogotsi, Y. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 2016, 353, 1137–1140.
Crossref Google Scholar
45

Zhou, B.; Zhang, Z.; Li, Y. L.; Han, G. J.; Feng, Y. Z.; Wang, B.; Zhang, D. B.; Ma, J. M.; Liu, C. T. Flexible, robust, and multifunctional electromagnetic interference shielding film with alternating cellulose nanofiber and MXene layers. ACS Appl. Mater. Interfaces 2020, 12, 4895–4905.
Crossref Google Scholar
46

Yang, R. L.; Gui, X. C.; Yao, L.; Hu, Q. M.; Yang, L. L.; Zhang, H.; Yao, Y. T.; Mei, H.; Tang, Z. K. Ultrathin, lightweight, and flexible CNT buckypaper enhanced using MXenes for electromagnetic interference shielding. Nanomicro Lett. 2021, 13, 66.
Crossref Google Scholar
47

Liu, R. T.; Miao, M.; Li, Y. H.; Zhang, J. F.; Cao, S. M.; Feng, X. Ultrathin biomimetic polymeric Ti3C2Tx MXene composite films for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 2018, 10, 44787–44795.
Crossref Google Scholar
48

Zhang, L.; Alvarez, N. T.; Zhang, M. X.; Haase, M.; Malik, R.; Mast, D.; Shanov, V. Preparation and characterization of graphene paper for electromagnetic interference shielding. Carbon 2015, 82, 353–359.
Crossref Google Scholar
49

Moglie, F.; Micheli, D.; Laurenzi, S.; Marchetti, M.; Primiani, V. M. Electromagnetic shielding performance of carbon foams. Carbon 2012, 50, 1972–1980.
Crossref Google Scholar
50

Crespo, M.; González, M.; Elías, A. L.; Rajukumar, L. P.; Baselga, J.; Terrones, M.; Pozuelo, J. Ultra-light carbon nanotube sponge as an efficient electromagnetic shielding material in the GHz range. Phys. Status Solidi Rapid Res. Lett. 2014, 8, 698–704.
Crossref Google Scholar
51

Zeng, Z. H.; Jin, H.; Chen, M. J.; Li, W. W.; Zhou, L. C.; Zhang, Z. Lightweight and anisotropic porous MWCNT/WPU composites for ultrahigh performance electromagnetic interference shielding. Adv. Funct. Mater. 2016, 26, 303–310.
Crossref Google Scholar
52

Chen, Z. P.; Xu, C.; Ma, C. Q.; Ren, W. C.; Cheng, H. M. Lightweight and flexible graphene foam composites for high-performance electromagnetic interference shielding. Adv. Mater. 2013, 25, 1296–1300.
Crossref Google Scholar
53

Shen, B.; Li, Y.; Yi, D.; Zhai, W. T.; Wei, X. C.; Zheng, W. G. Microcellular graphene foam for improved broadband electromagnetic interference shielding. Carbon 2016, 102, 154–160.
Crossref Google Scholar
Nano Research
Volume 15 Issue 6,
June 2022
Pages 4916-4924
DOI: 10.1007/s12274-022-4311-9
Cite this article:
Zhang Y, Xu M-K, Wang Z, et al. Strong and conductive reduced graphene oxide-MXene porous films for efficient electromagnetic interference shielding. Nano Research, 2022, 15(6): 4916-4924. https://doi.org/10.1007/s12274-022-4311-9
Topics:
Carbon
Part of a topical collection:
EM Wave Functional Materials

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Received: 10 February 2022
Revised: 10 March 2022
Accepted: 11 March 2022
Published: 31 March 2022
© Tsinghua University Press 2022
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