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Review Article

Progress toward understanding the fullerene-related chemical interactions in perovskite solar cells

Kaikai Liu, Chengbo Tian ( ), Yuming Liang, Yujie Luo, Liqiang Xie, Zhanhua Wei( )
Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China
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Graphical Abstract

This review provides a broader summary and in-depth insights about the function of fullerene materials in perovskite solar cells and highlights the crucial role of the fullerene-related chemical interaction, including fullerene-perovskite, fullerene-inorganic electron transport layer (IETL), and fullerene-fullerene.

Abstract

Fullerene materials have been widely used to fabricate efficient and stable perovskite solar cells (PSCs) due to their excellent electron transport ability, defect passivation effect, and beyond. Recent studies have shown that fullerene-related chemical interaction has played a crucial role in determining device performance. However, the corresponding fullerene-related chemical interactions are yet well understood. Herein, a comprehensive review of fullerene materials in regulating carrier transport, passivating the surface and grain boundary defects, and enhancing device stability is provided. Specifically, the influence of the fullerene-related chemical interactions, including fullerene-perovskite, fullerene-inorganic electron transport layer (IETL), and fullerene-fullerene, on the device performance is well discussed. Finally, we outline some perspectives for further design and application of fullerene materials to enhance the performance and commercial application of PSCs.

Keywords

perovskite solar cellsfunctional fullereneschemical interactionsdevice performance

References

1

Dresselhaus, M. S.; Crabtree, G. W.; Buchanan, M. V. Addressing grand energy challenges through advanced materials. MRS Bull. 2005, 30, 518–524.
Crossref Google Scholar
2

Liu, M. Z.; Johnston, M. B.; Snaith, H. J. Efficient planar heterojunction perovskite solar cells by vapour deposition. Nature 2013, 501, 395–398.
Crossref Google Scholar
3

Kim, H. S.; Lee, C. R.; Im, J. H.; Lee, K. B.; Moehl, T.; Marchioro, A.; Moon, S. J.; Humphry-Baker, R.; Yum, J. H.; Moser, J. E. et al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci. Rep. 2012, 2, 591.
Crossref Google Scholar
4

Yang, W. S.; Noh, J. H.; Jeon, N. J.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange. Science 2015, 348, 1234–1237.
Crossref Google Scholar
5

Bai, S.; Wu, Z. W.; Wu, X. J.; Jin, Y. Z.; Zhao, N.; Chen, Z. H.; Mei, Q. Q.; Wang, X.; Ye, Z. Z.; Song, T. et al. High-performance planar heterojunction perovskite solar cells: Preserving long charge carrier diffusion lengths and interfacial engineering. Nano Res. 2014, 7, 1749–1758.
Crossref Google Scholar
6

Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 2009, 131, 6050–6051.
Crossref Google Scholar
7

Jeon, N. J.; Noh, J. H.; Kim, Y. C.; Yang, W. S.; Ryu, S.; Seok, S. I. Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells. Nat. Mater. 2014, 13, 897–903.
Crossref Google Scholar
8

Bi, D. Q.; Yi, C. Y.; Luo, J. S.; Décoppet, J. D.; Zhang, F.; Zakeeruddin, S. M.; Li, X.; Hagfeldt, A.; Grätzel, M. Polymer-templated nucleation and crystal growth of perovskite films for solar cells with efficiency greater than 21%. Nat. Energy 2016, 1, 16142.
Crossref Google Scholar
9

Tan, H. R.; Jain, A.; Voznyy, O.; Lan, X. Z.; GarcÍa de Arquer, F. P.; Fan, J. Z.; Quintero-Bermudez, R.; Yuan, M. J.; Zhang, B.; Zhao, Y. C. et al. Efficient and stable solution-processed planar perovskite solar cells via contact passivation. Science 2017, 355, 722–726.
Crossref Google Scholar
10

Jeon, N. J.; Na, H.; Jung, E. H.; Yang, T. Y.; Lee, Y. G.; Kim, G.; Shin, H. W.; Seok, S. I.; Lee, J.; Seo, J. A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells. Nat. Energy 2018, 3, 682–689.
Crossref Google Scholar
11

Jeong, M.; Choi, I. W.; Go, E. M.; Cho, Y.; Kim, M.; Lee, B.; Jeong, S.; Jo, Y.; Choi, H. W.; Lee, J. et al. Stable perovskite solar cells with efficiency exceeding 24.8% and 0.3-V voltage loss. Science 2020, 369, 1615–1620.
Crossref Google Scholar
12

Yoo, J. J.; Seo, G.; Chua, M. R.; Park, T. G.; Lu, Y. L.; Rotermund, F.; Kim, Y. K.; Moon, C. S.; Jeon, N. J.; Correa-Baena, J. P. et al. Efficient perovskite solar cells via improved carrier management. Nature 2021, 590, 587–593.
Crossref Google Scholar
13

Tu, Y. G.; Xu, G. N.; Yang, X. Y.; Zhang, Y. F.; Li, Z. J.; Su, R.; Luo, D. Y.; Yang, W. Q.; Miao, Y.; Cai, R. et al. Mixed-cation perovskite solar cells in space. Sci. China Phys. Mech. Astron. 2019, 62, 974221.
Crossref Google Scholar
14

Yang, J. M.; Bao, Q. Y.; Shen, L.; Ding, L. M. Potential applications for perovskite solar cells in space. Nano Energy 2020, 76, 105019.
Crossref Google Scholar
15

Li, X.; Du, J. Y.; Duan, H.; Wang, H. Y.; Fan, L.; Sun, Y. F.; Sui, Y. R.; Yang, J. H.; Wang, F. Y.; Yang, L. L. Moisture-preventing MAPbI3 solar cells with high photovoltaic performance via multiple ligand engineering. Nano Res. 2022, 15, 1375–1382.
Crossref Google Scholar
16

Tu, Y. G.; Wu, J.; Xu, G. N.; Yang, X. Y.; Cai, R.; Gong, Q. H.; Zhu, R.; Huang, W. Perovskite solar cells for space applications: Progress and challenges. Adv. Mater. 2021, 33, 2006545.
Crossref Google Scholar
17
Zhao, X. ; Fang, W. H. ; Long, R. ; Prezhdo, O. V. Chemical passivation of methylammonium fragments eliminates traps, extends charge lifetimes, and restores structural stability of CH3NH3PbI3 perovskite. Nano Res., in press, https://doi.org/10.1007/s12274-021-4054-z.
18

Wang, F. Y.; Yang, M. F.; Zhang, Y. H.; Du, J. Y.; Yang, S.; Yang, L. L.; Fan, L.; Sui, Y. R.; Sun, Y. F.; Yang, J. H. Full-scale chemical and field-effect passivation: 21.52% efficiency of stable MAPbI3 solar cells via benzenamine modification. Nano Res. 2021, 14, 2783–2789.
Crossref Google Scholar
19

Sha, W. E. I.; Ren, X. G.; Chen, L. Z.; Choy, W. C. H. The efficiency limit of CH3NH3PbI3 perovskite solar cells. Appl. Phys. Lett. 2015, 106, 221104.
Crossref Google Scholar
20

Zhou, H. P.; Chen, Q.; Li, G.; Luo, S.; Song, T. B.; Duan, H. S.; Hong, Z. R.; You, J. B.; Liu, Y. S.; Yang, Y. Interface engineering of highly efficient perovskite solar cells. Science 2014, 345, 542–546.
Crossref Google Scholar
21

Jeon, N. J.; Noh, J. H.; Yang, W. S.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. Compositional engineering of perovskite materials for high-performance solar cells. Nature 2015, 517, 476–480.
Crossref Google Scholar
22

Da, P. M.; Zheng, G. F. Tailoring interface of lead-halide perovskite solar cells. Nano Res. 2017, 10, 1471–1497.
Crossref Google Scholar
23

Cho, A. N.; Park, N. G. Impact of interfacial layers in perovskite solar cells. ChemSusChem 2017, 10, 3687–3704.
Crossref Google Scholar
24

Hou, Y.; Du, X. Y.; Scheiner, S.; McMeekin, D. P.; Wang, Z. P.; Li, N.; Killian, M. S.; Chen, H. W.; Richter, M.; Levchuk, I. et al. A generic interface to reduce the efficiency-stability-cost gap of perovskite solar cells. Science 2017, 358, 1192–1197.
Crossref Google Scholar
25

Yang, W. S.; Park, B. W.; Jung, E. H.; Jeon, N. J.; Kim, Y. C.; Lee, D. U.; Shin, S. S.; Seo, J.; Kim, E. K.; Noh, J. H. et al. Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells. Science 2017, 356, 1376–1379.
Crossref Google Scholar
26

Zhang, F.; Zhu, K. Additive engineering for efficient and stable perovskite solar cells. Adv. Energy Mater. 2020, 10, 1902579.
Crossref Google Scholar
27

Liu, K. K.; Xie, L. Q.; Song, P. Q.; Lin, K. B.; Shen, L. N.; Liang, Y. M.; Lu, J. X.; Feng, W. J.; Guan, X.; Yan, C. Z. et al. Stable perovskite solar cells enabled by simultaneous surface and bulk defects passivation. Sol. RRL 2020, 4, 2000224.
Crossref Google Scholar
28

Mei, A. Y.; Sheng, Y. S.; Ming, Y.; Hu, Y.; Rong, Y. G.; Zhang, W. H.; Luo, S. L.; Na, G.; Tian, C. B.; Hou, X. M. et al. Stabilizing perovskite solar cells to IEC61215: 2016 standards with over 9, 000-h operational tracking. Joule 2020, 4, 2646–2660.
Crossref Google Scholar
29

Kim, M.; Jeong, J.; Lu, H.; Lee Tae, K.; Eickemeyer Felix, T.; Liu, Y.; Choi In, W.; Choi Seung, J.; Jo, Y.; Kim, H.-B. et al. Conformal quantum dot-SnO2 layers as electron transporters for efficient perovskite solar cells. Science 2022, 375, 302–306.
Crossref Google Scholar
30

Yu, W. J.; Sun, X. R.; Xiao, M.; Hou, T.; Liu, X.; Zheng, B. L.; Yu, H.; Zhang, M.; Huang, Y. L.; Hao, X. J. Recent advances on interface engineering of perovskite solar cells. Nano Res. 2022, 15, 85–103.
Crossref Google Scholar
31

Fang, Y. J.; Bi, C.; Wang, D.; Huang, J. S. The functions of fullerenes in hybrid perovskite solar cells. ACS Energy Lett. 2017, 2, 782–794.
Crossref Google Scholar
32

Zhang, M.; Lyu, M.; Yun, J. H.; Noori, M.; Zhou, X. J.; Cooling, N. A.; Wang, Q.; Yu, H.; Dastoor, P. C.; Wang, L. Z. Low-temperature processed solar cells with formamidinium tin halide perovskite/fullerene heterojunctions. Nano Res. 2016, 9, 1570–1577.
Crossref Google Scholar
33

Zheng, X. P.; Hou, Y.; Bao, C. X.; Yin, J.; Yuan, F. L.; Huang, Z. R.; Song, K. P.; Liu, J. K.; Troughton, J.; Gasparini, N. et al. Managing grains and interfaces via ligand anchoring enables 22.3%-efficiency inverted perovskite solar cells. Nat. Energy 2020, 5, 131–140.
Crossref Google Scholar
34

Jia, L. B.; Zhang, L. X.; Ding, L. M.; Yang, S. F. Using fluorinated and crosslinkable fullerene derivatives to improve the stability of perovskite solar cells. J. Semicond. 2021, 42, 120201.
Crossref Google Scholar
35

Ke, W. J.; Zhao, D. W.; Grice, C. R.; Cimaroli, A. J.; Ge, J.; Tao, H.; Lei, H. W.; Fang, G. J.; Yan, Y. F. Efficient planar perovskite solar cells using room-temperature vacuum-processed C60 electron selective layers. J. Mater. Chem. A 2015, 3, 17971–17976.
Crossref Google Scholar
36

Collavini, S.; Kosta, I.; Völker, S. F.; Cabanero, G.; Grande, H. J.; Tena-Zaera, R.; Delgado, J. L. Efficient regular perovskite solar cells based on pristine [70]fullerene as electron-selective contact. ChemSusChem 2016, 9, 1263–1270.
Crossref Google Scholar
37

Wang, Y. C.; Li, X. D.; Zhu, L. P.; Liu, X. H.; Zhang, W. J.; Fang, J. F. Efficient and hysteresis-free perovskite solar cells based on a solution processable polar fullerene electron transport layer. Adv. Energy Mater. 2017, 7, 1701144.
Crossref Google Scholar
38

Xie, J. S.; Yu, X. G.; Huang, J. B.; Sun, X.; Zhang, Y. H.; Yang, Z. R.; Lei, M.; Xu, L. B.; Tang, Z. G.; Cui, C. et al. Self-organized fullerene interfacial layer for efficient and low-temperature processed planar perovskite solar cells with high UV-light stability. Adv. Sci. 2017, 4, 1700018.
Crossref Google Scholar
39

Cao, T. T.; Chen, K.; Chen, Q. Y.; Zhou, Y.; Chen, N.; Li, Y. F. Fullerene derivative-modified SnO2 electron transport layer for highly efficient perovskite solar cells with efficiency over 21%. ACS Appl. Mater. Interfaces 2019, 11, 33825–33834.
Crossref Google Scholar
40

Castro, E.; Murillo, J.; Fernandez-Delgado, O.; Echegoyen, L. Progress in fullerene-based hybrid perovskite solar cells. J. Mater. Chem. C 2018, 6, 2635–2651.
Crossref Google Scholar
41

Collavini, S.; Saliba, M.; Tress, W. R.; Holzhey, P. J.; Völker, S. F.; Domanski, K.; Turren-Cruz, S. H.; Ummadisingu, A.; Zakeeruddin, S. M.; Hagfeldt, A. et al. Poly(ethylene glycol)-[60]fullerene-based materials for perovskite solar cells with improved moisture resistance and reduced hysteresis. ChemSusChem 2018, 11, 1032–1039.
Crossref Google Scholar
42

Wang, S. H.; Chen, H. Y.; Zhang, J. D.; Xu, G. Y.; Chen, W. J.; Xue, R. M.; Zhang, M. Y.; Li, Y. W.; Li, Y. F. Targeted therapy for interfacial engineering toward stable and efficient perovskite solar cells. Adv. Mater. 2019, 31, 1903691.
Crossref Google Scholar
43

Shao, Y. C.; Yuan, Y. B.; Huang, J. S. Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells. Nat. Energy 2016, 1, 15001.
Crossref Google Scholar
44

Liang, P. W.; Chueh, C. C.; Williams, S. T.; Jen, A. K. Y. Roles of fullerene-based interlayers in enhancing the performance of organometal perovskite thin-film solar cells. Adv. Energy Mater. 2015, 5, 1402321.
Crossref Google Scholar
45
Liang, Y. M.; Song, P. Q.; Tian, H. R.; Tian, C. B.; Tian, W. J.; Nan, Z. A.; Cai, Y. T.; Yang, P. P.; Sun, C.; Chen, J. F. et al. Lead leakage preventable fullerene-porphyrin dyad for efficient and stable perovskite solar cells. Adv. Funct. Mater., in press, https://doi.org/10.1002/adfm.202110139.
46

Li, X. D.; Zhang, W. X.; Guo, X. M.; Lu, C. Y.; Wei, J. Y.; Fang, J. F. Constructing heterojunctions by surface sulfidation for efficient inverted perovskite solar cells. Science 2022, 375, 434–437.
Crossref Google Scholar
47

Kan, C. X.; Tang, Z. F.; Yao, Y. X.; Hang, P. J.; Li, B.; Wang, Y.; Sun, X.; Lei, M.; Yang, D. R.; Yu, X. G. Mitigating ion migration by polyethylene glycol-modified fullerene for perovskite solar cells with enhanced stability. ACS Energy Lett. 2021, 6, 3864–3872.
Crossref Google Scholar
48

Li, C. Z.; Chueh, C. C.; Yip, H. L.; Ding, F. Z.; Li, X. S.; Jen, A. K. Y. Solution-processible highly conducting fullerenes. Adv. Mater. 2013, 25, 2457–2461.
Crossref Google Scholar
49

Jeng, J. Y.; Chiang, Y. F.; Lee, M. H.; Peng, S. R.; Guo, T. F.; Chen, P.; Wen, T. C. CH3NH3PbI3 perovskite/fullerene planar-heterojunction hybrid solar cells. Adv. Mater. 2013, 25, 3727–3732.
Crossref Google Scholar
50

Heo, J. H.; Han, H. J.; Kim, D.; Ahn, T. K.; Im, S. H. Hysteresis-less inverted CH3NH3PbI3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency. Energy Environ. Sci. 2015, 8, 1602–1608.
Crossref Google Scholar
51

Wolff, C. M.; Zu, F. S.; Paulke, A.; Toro, L. P.; Koch, N.; Neher, D. Reduced interface-mediated recombination for high open-circuit voltages in CH3NH3PbI3 solar cells. Adv. Mater. 2017, 29, 1700159.
Crossref Google Scholar
52

Shao, Y. C.; Xiao, Z. G.; Bi, C.; Yuan, Y. B.; Huang, J. S. Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells. Nat. Commun. 2014, 5, 5784.
Crossref Google Scholar
53

Bai, Y.; Dong, Q. F.; Shao, Y. C.; Deng, Y. H.; Wang, Q.; Shen, L.; Wang, D.; Wei, W.; Huang, J. S. Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene. Nat. Commun. 2016, 7, 12806.
Crossref Google Scholar
54

Meng, L.; You, J. B.; Guo, T. F.; Yang, Y. Recent advances in the inverted planar structure of perovskite solar cells. Acc. Chem. Res. 2016, 49, 155–165.
Crossref Google Scholar
55

Deng, L. L.; Xie, S. Y.; Gao, F. Fullerene-based materials for photovoltaic applications: Toward efficient, hysteresis-free, and stable perovskite solar cells. Adv. Electron. Mater. 2018, 4, 1700435.
Crossref Google Scholar
56

Pascual, J.; Delgado, J. L.; Tena-Zaera, R. Physicochemical phenomena and application in solar cells of perovskite: Fullerene films. J. Phys. Chem. Lett. 2018, 9, 2893–2902.
Crossref Google Scholar
57

Docampo, P.; Ball, J. M.; Darwich, M.; Eperon, G. E.; Snaith, H. J. Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates. Nat. Commun. 2013, 4, 2761.
Crossref Google Scholar
58

Cao, T. T.; Huang, P.; Zhang, K. C.; Sun, Z. Q.; Zhu, K.; Yuan, L. G.; Chen, K.; Chen, N.; Li, Y. F. Interfacial engineering via inserting functionalized water-soluble fullerene derivative interlayers for enhancing the performance of perovskite solar cells. J. Mater. Chem. A 2018, 6, 3435–3443.
Crossref Google Scholar
59

Xing, Y.; Sun, C.; Yip, H. L.; Bazan, G. C.; Huang, F.; Cao, Y. New fullerene design enables efficient passivation of surface traps in high performance p–i–n heterojunction perovskite solar cells. Nano Energy 2016, 26, 7–15.
Crossref Google Scholar
60

Dai, S. M.; Zhang, X.; Chen, W. Y.; Li, X.; Tan, Z. A.; Li, C.; Deng, L. L.; Zhan, X. X.; Lin, M. S.; Xing, Z. et al. Formulation engineering for optimizing ternary electron acceptors exemplified by isomeric PC71BM in planar perovskite solar cells. J. Mater. Chem. A 2016, 4, 18776–18782.
Crossref Google Scholar
61

Xu, J. X.; Buin, A.; Ip, A. H.; Li, W.; Voznyy, O.; Comin, R.; Yuan, M. J.; Jeon, S.; Ning, Z. J.; McDowell, J. J. et al. Perovskite-fullerene hybrid materials suppress hysteresis in planar diodes. Nat. Commun. 2015, 6, 7081.
Crossref Google Scholar
62

Tian, C. B.; Castro, E.; Betancourt-Solis, G.; Nan, Z. A.; Fernandez-Delgado, O.; Jankuru, S.; Echegoyen, L. Fullerene derivative with a branched alkyl chain exhibits enhanced charge extraction and stability in inverted planar perovskite solar cells. New J. Chem. 2018, 42, 2896–2902.
Crossref Google Scholar
63

Chiang, C. H.; Wu, C. G. Bulk heterojunction perovskite-PCBM solar cells with high fill factor. Nat. Photonics 2016, 10, 196–200.
Crossref Google Scholar
64

Wu, Y. Z.; Yang, X. D.; Chen, W.; Yue, Y. F.; Cai, M. L.; Xie, F. X.; Bi, E. B.; Islam, A.; Han, L. Perovskite solar cells with 18.21% efficiency and area over 1 cm2 fabricated by heterojunction engineering. Nat. Energy 2016, 1, 16148.
Crossref Google Scholar
65

Zhang, F.; Shi, W. D.; Luo, J. S.; Pellet, N.; Yi, C. Y.; Li, X.; Zhao, X. M.; Dennis, T. J. S.; Li, X. G.; Wang, S. R. et al. Isomer-pure bis-PCBM-assisted crystal engineering of perovskite solar cells showing excellent efficiency and stability. Adv. Mater. 2017, 29, 1606806.
Crossref Google Scholar
66

Li, Y. W.; Zhao, Y.; Chen, Q.; Yang, Y.; Liu, Y. S.; Hong, Z. R.; Liu, Z. H.; Hsieh, Y. T.; Meng, L.; Li, Y. F. et al. Multifunctional fullerene derivative for interface engineering in perovskite solar cells. J. Am. Chem. Soc. 2015, 137, 15540–15547.
Crossref Google Scholar
67

Dong, Q.; Ho, C. H. Y.; Yu, H.; Salehi, A.; So, F. Defect passivation by fullerene derivative in perovskite solar cells with aluminum-doped zinc oxide as electron transporting layer. Chem. Mater. 2019, 31, 6833–6840.
Crossref Google Scholar
68

Luo, Z. H.; Wu, F.; Zhang, T.; Zeng, X.; Xiao, Y. Q.; Liu, T.; Zhong, C.; Lu, X. H.; Zhu, L. N.; Yang, S. H. et al. Designing a perylene diimide/fullerene hybrid as effective electron transporting material in inverted perovskite solar cells with enhanced efficiency and stability. Angew. Chem., Int. Ed. 2019, 58, 8520–8525.
Crossref Google Scholar
69

Bertoluzzi, L.; Belisle, R. A.; Bush, K. A.; Cheacharoen, R.; McGehee, M. D.; O’Regan, B. C. In situ measurement of electric-field screening in hysteresis-free PTAA/FA0.83Cs0.17Pb(I0.83Br0.17)3/C60 perovskite solar cells gives an ion mobility of ~ 3 × 10−7 cm2/(V·s), 2 orders of magnitude faster than reported for metal-oxide-contacted perovskite cells with hysteresis. J. Am. Chem. Soc. 2018, 140, 12775–12784.
Crossref Google Scholar
70

Huang, H. H.; Tsai, H.; Raja, R.; Lin, S. L.; Ghosh, D.; Hou, C. H.; Shyue, J. J.; Tretiak, S.; Chen, W.; Lin, K. F. et al. Robust unencapsulated perovskite solar cells protected by a fluorinated fullerene electron transporting layer. ACS Energy Lett. 2021, 6, 3376–3385.
Crossref Google Scholar
71

Zhou, Y. Q.; Wu, B. S.; Lin, G. H.; Xing, Z.; Li, S. H.; Deng, L. L.; Chen, D. C.; Yun, D. Q.; Xie, S. Y. Interfacing pristine C60 onto TiO2 for viable flexibility in perovskite solar cells by a low-temperature all-solution process. Adv. Energy Mater. 2018, 8, 1800399.
Crossref Google Scholar
72

Xu, G. Y.; Wang, S. H.; Bi, P. Q.; Chen, H. Y.; Zhang, M. Y.; Xue, R. M.; Hao, X. T.; Wang, Z. K.; Li, Y. W.; Li, Y. F. Hydrophilic fullerene derivative doping in active layer and electron transport layer for enhancing oxygen stability of perovskite solar cells. Sol. RRL 2020, 4, 1900249.
Crossref Google Scholar
73

Aristidou, N.; Eames, C.; Sanchez-Molina, I.; Bu, X. N.; Kosco, J.; Islam, M. S.; Haque, S. A. Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells. Nat. Commun. 2017, 8, 15218.
Crossref Google Scholar
74

Gatti, T.; Menna, E.; Meneghetti, M.; Maggini, M.; Petrozza, A.; Lamberti, F. The renaissance of fullerenes with perovskite solar cells. Nano Energy 2017, 41, 84–100.
Crossref Google Scholar
75

Elnaggar, M.; Elshobaki, M.; Mumyatov, A.; Luchkin, S. Y.; Dremova, N. N.; Stevenson, K. J.; Troshin, P. A. Molecular engineering of the fullerene-based electron transport layer materials for improving ambient stability of perovskite solar cells. Sol. RRL 2019, 3, 1900223.
Crossref Google Scholar
76

Jia, L. B.; Chen, M. Q.; Yang, S. F. Functionalization of fullerene materials toward applications in perovskite solar cells. Mater. Chem. Front. 2020, 4, 2256–2282.
Crossref Google Scholar
77

Fernandez-Delgado, O.; Castro, E.; Ganivet, C. R.; Fosnacht, K.; Liu, F.; Mates, T.; Liu, Y.; Wu, X. J.; Echegoyen, L. Variation of interfacial interactions in PC61BM-like electron-transporting compounds for perovskite solar cells. ACS Appl. Mater. Interfaces 2019, 11, 34408–34415.
Crossref Google Scholar
78

Taufique, M. F. N.; Mortuza, S. M.; Banerjee, S. Mechanistic insight into the attachment of fullerene derivatives on crystal faces of methylammonium lead iodide based perovskites. J. Phys. Chem. C 2016, 120, 22426–22432.
Crossref Google Scholar
79

Xing, Z.; Li, S. H.; Hui, Y.; Wu, B. S.; Chen, Z. C.; Yun, D. Q.; Deng, L. L.; Zhang, M. L.; Mao, B. W.; Xie, S. Y. et al. Star-like hexakis[di(ethoxycarbonyl)methano]-C60 with higher electron mobility: An unexpected electron extractor interfaced in photovoltaic perovskites. Nano Energy 2020, 74, 104859.
Crossref Google Scholar
80

Tian, C. B.; Castro, E.; Wang, T.; Betancourt-Solis, G.; Rodriguez, G.; Echegoyen, L. Improved performance and stability of inverted planar perovskite solar cells using fulleropyrrolidine layers. ACS Appl. Mater. Interfaces 2016, 8, 31426–31432.
Crossref Google Scholar
81

Tian, C. B.; Zhang, S. J.; Mei, A. Y.; Rong, Y. G.; Hu, Y.; Du, K.; Duan, M.; Sheng, Y. S.; Jiang, P.; Xu, G. Z. et al. A multifunctional bis-adduct fullerene for efficient printable mesoscopic perovskite solar cells. ACS Appl. Mater. Interfaces 2018, 10, 10835–10841.
Crossref Google Scholar
82

Tian, C. B.; Kochiss, K.; Castro, E.; Betancourt-Solis, G.; Han, H. W.; Echegoyen, L. A dimeric fullerene derivative for efficient inverted planar perovskite solar cells with improved stability. J. Mater. Chem. A 2017, 5, 7326–7332.
Crossref Google Scholar
83

Tian, C. B.; Lin, K.; Lu, J.; Feng, W.; Song, P.; Xie, L.; Wei, Z. Interfacial bridge using a cis-fulleropyrrolidine for efficient planar perovskite solar cells with enhanced stability. Small Methods 2019, 4, 1900476.
Crossref Google Scholar
84

Noel, N. K.; Abate, A.; Stranks, S. D.; Parrott, E. S.; Burlakov, V. M.; Goriely, A.; Snaith, H. J. Enhanced photoluminescence and solar cell performance via lewis base passivation of organic–inorganic lead halide perovskites. ACS Nano 2014, 8, 9815–9821.
Crossref Google Scholar
85

Liu, H. R.; Li, S. H.; Deng, L. L.; Wang, Z. Y.; Xing, Z.; Rong, X.; Tian, H. R.; Li, X.; Xie, S. Y.; Huang, R. B. et al. Pyridine-functionalized fullerene electron transport layer for efficient planar perovskite solar cells. ACS Appl. Mater. Interfaces 2019, 11, 23982–23989.
Crossref Google Scholar
86

Li, B. R.; Zhen, J. M.; Wan, Y. Y.; Lei, X. Y.; Liu, Q.; Liu, Y. J.; Jia, L. B.; Wu, X. J.; Zeng, H. L.; Zhang, W. F. et al. Anchoring fullerene onto perovskite film via grafting pyridine toward enhanced electron transport in high-efficiency solar cells. ACS Appl. Mater. Interfaces 2018, 10, 32471–32482.
Crossref Google Scholar
87

Li, B. R.; Zhen, J. M.; Wan, Y. Y.; Lei, X. Y.; Jia, L. B.; Wu, X. J.; Zeng, H. L.; Chen, M. Q.; Wang, G. W.; Yang, S. F. Steering the electron transport properties of pyridine-functionalized fullerene derivatives in inverted perovskite solar cells: The nitrogen site matters. J. Mater. Chem. A 2020, 8, 3872–3881.
Crossref Google Scholar
88

Liu, X.; Lin, F.; Chueh, C. C.; Chen, Q.; Zhao, T.; Liang, P. W.; Zhu, Z. L.; Sun, Y.; Jen, A. K. Y. Fluoroalkyl-substituted fullerene/perovskite heterojunction for efficient and ambient stable perovskite solar cells. Nano Energy 2016, 30, 417–425.
Crossref Google Scholar
89

Unger, E. L.; Hoke, E. T.; Bailie, C. D.; Nguyen, W. H.; Bowring, A. R.; Heumüller, T.; Christoforo, M. G.; McGehee, M. D. Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells. Energy Environ. Sci. 2014, 7, 3690–3698.
Crossref Google Scholar
90

Wang, H.; Li, F. B.; Wang, P.; Sun, R.; Ma, W.; Chen, M. T.; Miao, W. Q.; Liu, D.; Wang, T. Chlorinated fullerene dimers for interfacial engineering toward stable planar perovskite solar cells with 22.3% efficiency. Adv. Energy Mater. 2020, 10, 2000615.
Crossref Google Scholar
91

Zhang, M. Y.; Chen, Q.; Xue, R. M.; Zhan, Y.; Wang, C.; Lai, J. Q.; Yang, J.; Lin, H. Z.; Yao, J. L.; Li, Y. W. et al. Reconfiguration of interfacial energy band structure for high-performance inverted structure perovskite solar cells. Nat. Commun. 2019, 10, 4593.
Crossref Google Scholar
92

Sandoval-Torrientes, R.; Pascual, J.; García-Benito, I.; Collavini, S.; Kosta, I.; Tena-Zaera, R.; Martín, N.; Delgado, J. L. Modified fullerenes for efficient electron transport layer-free perovskite/fullerene blend-based solar cells. ChemSusChem 2017, 10, 2023–2029.
Crossref Google Scholar
93

Pascual, J.; Collavini, S.; Völker, S. F.; Phung, N.; Palacios-Lidon, E.; Irusta, L.; Grande, H. J.; Abate, A.; Tena-Zaera, R.; Delgado, J. L. Unravelling fullerene-perovskite interactions introduces advanced blend films for performance-improved solar cells. Sustainable Energy Fuels 2019, 3, 2779–2787.
Crossref Google Scholar
94

Wang, X.; Rakstys, K.; Jack, K.; Jin, H.; Lai, J.; Li, H.; Ranasinghe, C. S. K.; Saghaei, J.; Zhang, G. R.; Burn, P. L. et al. Engineering fluorinated-cation containing inverted perovskite solar cells with an efficiency of > 21% and improved stability towards humidity. Nat. Commun. 2021, 12, 52.
Crossref Google Scholar
95

Rajagopal, A.; Liang, P. W.; Chueh, C. C.; Yang, Z. B.; Jen, A. K. Y. Defect passivation via a graded fullerene heterojunction in low-bandgap Pb-Sn binary perovskite photovoltaics. ACS Energy Lett. 2017, 2, 2531–2539.
Crossref Google Scholar
96

Chang, C. Y.; Wang, C. P.; Raja, R.; Wang, L.; Tsao, C. S.; Su, W. F. High-efficiency bulk heterojunction perovskite solar cell fabricated by one-step solution process using single solvent: Synthesis and characterization of material and film formation mechanism. J. Mater. Chem. A 2018, 6, 4179–4188.
Crossref Google Scholar
97

Abrusci, A.; Stranks, S. D.; Docampo, P.; Yip, H. L.; Jen, A. K. Y.; Snaith, H. J. High-performance perovskite-polymer hybrid solar cells via electronic coupling with fullerene monolayers. Nano Lett. 2013, 13, 3124–3128.
Crossref Google Scholar
98

Dong, Y.; Li, W. H.; Zhang, X. J.; Xu, Q.; Liu, Q.; Li, C. H.; Bo, Z. S. Highly efficient planar perovskite solar cells via interfacial modification with fullerene derivatives. Small 2016, 12, 1098–1104.
Crossref Google Scholar
99

Wang, H.; Cai, F. L.; Zhang, M.; Wang, P.; Yao, J. X.; Gurney, R. S.; Li, F. B.; Liu, D.; Wang, T. Halogen-substituted fullerene derivatives for interface engineering of perovskite solar cells. J. Mater. Chem. A 2018, 6, 21368–21378.
Crossref Google Scholar
100

Zhong, M. Y.; Liang, Y. Q.; Zhang, J. Q.; Wei, Z. X.; Li, Q.; Xu, D. S. Highly efficient flexible MAPbI3 solar cells with a fullerene derivative-modified SnO2 layer as the electron transport layer. J. Mater. Chem. A 2019, 7, 6659–6664.
Crossref Google Scholar
101

Yang, Z. J.; Zhong, M. Y.; Liang, Y. Q.; Yang, L. W.; Liu, X. Y.; Li, Q.; Zhang, J.; Xu, D. S. SnO2-C60 pyrrolidine tris-acid (CPTA) as the electron transport layer for highly efficient and stable planar Sn-based perovskite solar cells. Adv. Funct. Mater. 2019, 29, 1903621.
Crossref Google Scholar
102

Wang, J. K.; Datta, K.; Weijtens, C. H. L.; Wienk, M. M.; Janssen, R. A. J. Insights into fullerene passivation of SnO2 electron transport layers in perovskite solar cells. Adv. Funct. Mater. 2019, 29, 1905883.
Crossref Google Scholar
103

Liu, K.; Chen, S.; Wu, J. H.; Zhang, H. Y.; Qin, M. C.; Lu, X. H.; Tu, Y. F.; Meng, Q. B.; Zhan, X. W. Fullerene derivative anchored SnO2 for high-performance perovskite solar cells. Energy Environ. Sci. 2018, 11, 3463–3471.
Crossref Google Scholar
104

Xu, G. Y.; Xue, R. M.; Chen, W. J.; Zhang, J. W.; Zhang, M. Y.; Chen, H. Y.; Cui, C. H.; Li, H. K.; Li, Y. W.; Li, Y. F. New strategy for two-step sequential deposition: Incorporation of hydrophilic fullerene in second precursor for high-performance p–i–n planar perovskite solar cells. Adv. Energy Mater. 2018, 8, 1703054.
Crossref Google Scholar
105

Yao, K.; Leng, S. F.; Liu, Z. L.; Fei, L. F.; Chen, Y. J.; Li, S. B.; Zhou, N. G.; Zhang, J.; Xu, Y. X.; Zhou, L. et al. Fullerene-anchored core–shell ZnO nanoparticles for efficient and stable dual-sensitized perovskite solar cells. Joule 2019, 3, 417–431.
Crossref Google Scholar
106
Jie, Z.; Leyu, B.; Yuanhang, C.; Baomin, X.; Alex K.-Y, J. Self-assembled monolayer enabling improved buried interfaces in blade-coated perovskite solar cells for high efficiency and stability. Nano Research Energy, in press, https://doi.org/10.26599/NRE.2022.9120004.
Crossref
107

Kim, J.; Kim, G.; Kim, T. K.; Kwon, S.; Back, H.; Lee, J.; Lee, S. H.; Kang, H.; Lee, K. Efficient planar-heterojunction perovskite solar cells achieved via interfacial modification of a sol-gel ZnO electron collection layer. J. Mater. Chem. A 2014, 2, 17291–17296.
Crossref Google Scholar
108

Li, S. H.; Xing, Z.; Wu, B. S.; Chen, Z. C.; Yao, Y. R.; Tian, H. R.; Li, M. F.; Yun, D. Q.; Deng, L. L.; Xie, S. Y. et al. Hybrid fullerene-based electron transport layers improving the thermal stability of perovskite solar cells. ACS Appl. Mater. Interfaces 2020, 12, 20733–20740.
Crossref Google Scholar
109

Xing, Z.; Li, S. H.; Xie, F. F.; Xu, P. Y.; Deng, L. L.; Zhong, X. X.; Xie, S. Y. Mixed fullerene electron transport layers with fluorocarbon chains assembling on the surface: A moisture-resistant coverage for perovskite solar cells. ACS Appl. Mater. Interfaces 2020, 12, 35081–35087.
Crossref Google Scholar
110

Tian, C. B.; Betancourt-Solis, G.; Nan, Z.; Liu, K. K.; Lin, K. B.; Lu, J. X.; Xie, L. Q.; Echegoyen, L.; Wei, Z. H. Efficient and stable inverted perovskite solar cells enabled by inhibition of self-aggregation of fullerene electron-transporting compounds. Sci. Bull. 2021, 66, 339–346.
Crossref Google Scholar
111

Wojciechowski, K.; Ramirez, I.; Gorisse, T.; Dautel, O.; Dasari, R.; Sakai, N.; Hardigree, J. M.; Song, S.; Marder, S.; Riede, M. et al. Cross-linkable fullerene derivatives for solution-processed n–i–p perovskite solar cells. ACS Energy Lett. 2016, 1, 648–653.
Crossref Google Scholar
112

Tao, C.; Van Der Velden, J.; Cabau, L.; Montcada, N. F.; Neutzner, S.; Srimath Kandada, A. R.; Marras, S.; Brambilla, L.; Tommasini, M.; Xu, W. D. et al. Fully solution-processed n–i–p-like perovskite solar cells with planar junction: How the charge extracting layer determines the open-circuit voltage. Adv. Mater. 2017, 29, 1604493.
Crossref Google Scholar
113

Kang, T.; Tsai, C. M.; Jiang, Y. H.; Gollavelli, G.; Mohanta, N.; Diau, E. W. G.; Hsu, C. S. Interfacial engineering with cross-linkable fullerene derivatives for high-performance perovskite solar cells. ACS Appl. Mater. Interfaces 2017, 9, 38530–38536.
Crossref Google Scholar
114

Watson, B. L.; Rolston, N.; Bush, K. A.; Leijtens, T.; McGehee, M. D.; Dauskardt, R. H. Cross-linkable, solvent-resistant fullerene contacts for robust and efficient perovskite solar cells with increased JSC and VOC. ACS Appl. Mater. Interfaces 2016, 8, 25896–25904.
Crossref Google Scholar
115

Song, S.; Hill, R.; Choi, K.; Wojciechowski, K.; Barlow, S.; Leisen, J.; Snaith, H. J.; Marder, S. R.; Park, T. Surface modified fullerene electron transport layers for stable and reproducible flexible perovskite solar cells. Nano Energy 2018, 49, 324–332.
Crossref Google Scholar
116

Li, M.; Yang, Y. G.; Wang, Z. K.; Kang, T.; Wang, Q.; Turren-Cruz, S. H.; Gao, X. Y.; Hsu, C. S.; Liao, L. S.; Abate, A. Perovskite grains embraced in a soft fullerene network make highly efficient flexible solar cells with superior mechanical stability. Adv. Mater. 2019, 31, 1901519.
Crossref Google Scholar
Nano Research
Volume 15 Issue 8,
August 2022
Pages 7139-7153
DOI: 10.1007/s12274-022-4322-6
Cite this article:
Liu K, Tian C, Liang Y, et al. Progress toward understanding the fullerene-related chemical interactions in perovskite solar cells. Nano Research, 2022, 15(8): 7139-7153. https://doi.org/10.1007/s12274-022-4322-6
Topics:
Perovskite solar cells

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Received: 27 January 2022
Revised: 11 March 2022
Accepted: 13 March 2022
Published: 28 May 2022
© Tsinghua University Press 2022
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