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Research Article

High-rate sodium metal batteries enabled by trifluormethylfullerene additive

Pengju Li1, Xiaobo Huang1, Zhipeng Jiang1,2, Han Zhang1,2, Pengwei Yu1, Xing Lu1( ), Jia Xie2( )
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
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Graphical Abstract

Trifluormethylfullerene as an electrolyte additive enables the high-rate performance of sodium metal batteries by inhibiting the decomposition of electrolytes and forming robust electrode/electrolyte interface layers, which suppress side reactions and promote the uniform Na deposition.

Abstract

Sodium metal is a promising anode for sodium batteries due to its high theoretical capacity and low cost. However, the serious Na dendrite growth and low Coulombic efficiency, especially at high current densities/cycling capacities, severely limit the application of sodium metal anodes. Herein, trifluoromethylfullerene, C60(CF3)6, is designed as an electrolyte additive to enable the high-rate cycling of sodium metal anodes with high Coulombic efficiency. The CF3 groups contribute to the formation of stable NaF-rich solid electrolyte interface layer, while C60 cages induce the uniform distribution of sodium ions and promote the formation of smooth and compact morphology. Thus, Na||Cu cell with C60(CF3)6 can be cycled at 2 mA·cm−2 and 10 mAh·cm−2 over 180 cycles with an average Coulombic efficiency of 99.9%, and Na||Na cell can be cycled at 10 mA·cm−2 over 600 cycles. Furthermore, Na||NaV2(PO4)3@C full cell exhibits high capacity retention of 84% over 2,000 cycles at 20 C (~ 3 mA·cm−2).

Keywords

sodium metal anodefullerenetrifluormethylfullerenehigh rateelectrolyte additive

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Nano Research
Volume 15 Issue 8,
August 2022
Pages 7172-7179
DOI: 10.1007/s12274-022-4349-8
Cite this article:
Li P, Huang X, Jiang Z, et al. High-rate sodium metal batteries enabled by trifluormethylfullerene additive. Nano Research, 2022, 15(8): 7172-7179. https://doi.org/10.1007/s12274-022-4349-8
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Received: 10 January 2022
Revised: 01 March 2022
Accepted: 22 March 2022
Published: 04 May 2022
© Tsinghua University Press 2022
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