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Research Article

Vortex tuning magnetization configurations in porous Fe3O4 nanotube with wide microwave absorption frequency

Ruixuan Zhang1, Lei Wang1,4, Chunyang Xu1, Chongyun Liang3( ), Xianhu Liu5, Xuefeng Zhang6, Renchao Che1,2( )
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Materials Science, Fudan University, Shanghai 200438, China
Joint-Research Center for Computational Materials, Zhejiang Laboratory, Hangzhou 311100, China
Department of Chemistry, Fudan University, Shanghai 200433, China
School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, China
Key Laboratory of Materials Processing and Mold, Ministry of Education, Zhengzhou University, Zhengzhou 450002, China
Institute of Advanced Magnetic Materials, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310012, China
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Graphical Abstract

A porous Fe3O4 nanotube has been produced by electrospinning and calcination. The pores on the surface of the nanotube induce vortices into the nanotube, thus the spin-wave resonance has been modulated and the microwave absorption performance is improved.

Abstract

The design and optimization of one-dimension (1D) magnetic material are of great importance for the energy conversion, storage and spin electron devices, which remain a huge challenge. Herein, 1D porous Fe3O4 nanotubes (NTs) have been fabricated via a combined process of electrospinning and calcination. In the electrospinning precursors, by regulating the content ratio between two types of polyvinyl pyrrolidone with different molecular weight, porous Fe3O4 NTs with vortex-domain configuration have been fabricated. Based on the unique 1D nanotube structure encapsulated with multi-domains, the composite Fe3O4 NTs exhibit high complex permeability (μʹ, μʺ) values, and hold both strong magnetic storage and dissipation capacity. Our Fe3O4 NTs exhibit excellent microwave absorption (MA) performance with the maximum reflection loss value of −57.1 dB and the efficient absorption bandwidth of 12.0 GHz. The generated magnetic vortices make the crucial contribution to the spin-wave resonance which improves the MA dissipation under high-frequency. Related magnetic flux line distribution and magnetic domain moment were confirmed by the electron holography and micro-magnetic simulation, respectively, providing the deep insight to the microwave absorption mechanism.

Keywords

microwave absorptionvortex domainone-dimensional structureporous structure

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Nano Research
Volume 15 Issue 7,
July 2022
Pages 6743-6750
DOI: 10.1007/s12274-022-4401-8
Cite this article:
Zhang R, Wang L, Xu C, et al. Vortex tuning magnetization configurations in porous Fe3O4 nanotube with wide microwave absorption frequency. Nano Research, 2022, 15(7): 6743-6750. https://doi.org/10.1007/s12274-022-4401-8
Topics:
Iron research
Part of a topical collection:
EM Wave Functional Materials

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Received: 17 February 2022
Revised: 30 March 2022
Accepted: 06 April 2022
Published: 26 April 2022
© Tsinghua University Press 2022
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