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Research Article

Nucleation growth quenching for superior cluster catalysts

Ruyue Wang1,2,3,4, Feng Cheng5, Yonggang Wang2, Dongyu Fan2, Bohan Deng3, Yuanzheng Long3, Haolin Tang1( ), Kai Huang2,3( ), Zhaowei Qu2, Ming Lei2, Binghui Ge5( ), Hui Wu3( )
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
State Key Laboratory of Information Photonics and Optical Communications, School of Science, Beijing University of Posts and Telecommunications, Beijing 100876, China
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
Beijing Key Laboratory of Space-ground Interconnection and Convergence, Beijing University of Posts and Telecommunications (BUPT), Beijing 100876, China
Information Materials and Intelligent Sensing Laboratory of Anhui Province, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology, Anhui University, Hefei 230601, China
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Graphical Abstract

Adopting the quenching strategy of the local instantaneous high-temperature reaction, vacancy-defect rich metal compound clusters were rapidly generated. By the introduction of alkaline solutions, a unique method of rapidly and efficiently preparing metal oxide clusters has been further discovered, and the obtained oxide clusters can be uniformly dispersed and anchored onto the substrate. Synthesized IrO2-based electrode exhibited high oxygen evolution reaction (OER) activity and long-term operational stability in alkaline electrolyte solutions, superior to the commercial IrO2 and most other previously reported Ir-based catalysts.

Abstract

Cluster catalysts are rapidly growing into an important sub-field in heterogeneous catalysis, owing to their distinct geometric structure, neighboring metal sites, and unique electronic structure. Although the thermodynamics and kinetics of the formation of nanoparticles have been largely investigated, the precise synthesis of clusters in wet chemical methods still faces great challenges. In the study, a quenching strategy of asymmetric temperature in solution for the rapid generation of vacancy-defect rich clusters is reported. The quenching process can be used to synthesize multitudinous metal compound clusters, including metal oxides, fluorides, oxygen-sulfur compounds, and tungstate. For oxygen evolution reaction (OER), IrO2 clusters with abundant oxygen vacancies were obtained and uniformly dispersed in the solution. Compared to commercial IrO2, the prepared IrO2 cluster can be directly loaded on carbon paper and used as binder-free electrodes, which exhibit higher OER activity and long-term operational stability in alkaline electrolytes. The quenching strategy provides a simple and efficient method for the synthesis of clusters, which has tremendous potential for industrial-scale preparation and application, especially can be further applied to flow electrochemical generators.

Keywords

rapid-chillingcluster structuretransition metal compoundsbinder-free electrodeoxygen evolution reaction

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References

1

Boudart, M. Heterogeneous catalysis by metals. J. Mol. Catal. 1985, 30, 27–38.
Crossref Google Scholar
2

Gates, B. C. Supported metal clusters: Synthesis, structure, and catalysis. Chem. Rev. 1995, 95, 511–522.
Crossref Google Scholar
3

Ye, R.; Zhukhovitskiy, A. V.; Deraedt, C. V.; Toste, F. D.; Somorjai, G. A. Supported dendrimer-encapsulated metal clusters: Toward heterogenizing homogeneous catalysts. Acc. Chem. Res. 2017, 50, 1894–1901.
Crossref Google Scholar
4

Yamazoe, S.; Koyasu, K.; Tsukuda, T. Nonscalable oxidation catalysis of gold clusters. Acc. Chem. Res. 2014, 47, 816–824.
Crossref Google Scholar
5

Dong, C. Y.; Li, Y. L.; Cheng, D. Y.; Zhang, M. T.; Liu, J. J.; Wang, Y. G.; Xiao, D. Q.; Ma, D. Supported metal clusters: Fabrication and application in heterogeneous catalysis. ACS Catal. 2010, 10, 11011–11045.
Crossref Google Scholar
6

Wang, A. Q.; Li, J.; Zhang, T. Heterogeneous single-atom catalysis. Nat. Rev. Chem. 2018, 2, 65–81.
Crossref Google Scholar
7

Kuai, L.; Chen, Z.; Liu, S. J.; Kan, E. J.; Yu, N.; Ren, Y. M.; Fang, C. H.; Li, X. Y.; Li, Y. D.; Geng, B. Y. Titania supported synergistic palladium single atoms and nanoparticles for room temperature ketone and aldehydes hydrogenation. Nat. Commun. 2020, 11, 48.
Crossref Google Scholar
8

Mason, M. G. Electronic structure of supported small metal clusters. Phys. Rev. B 1983, 27, 748–762.
Crossref Google Scholar
9

Kaden, W. E.; Wu, T. P.; Kunkel, W. A.; Anderson, S. L. Electronic structure controls reactivity of size-selected Pd clusters adsorbed on TiO2 surfaces. Science 2009, 326, 826–829.
Crossref Google Scholar
10

Huang, K.; Xu, Y. Y.; Song, Y. P.; Wang, R. Y.; Wei, H. H.; Long, Y. Z.; Lei, M.; Tang, H. L.; Guo, J. G.; Wu, H. NiPS3 quantum sheets modified nitrogen-doped mesoporous carbon with boosted bifunctional oxygen electrocatalytic performance. J. Mater. Sci. Technol. 2021, 15, 1–6.
Crossref Google Scholar
11

Van Deelen, T. W.; Mejía, C. H.; De Jong, K. P. Control of metal–support interactions in heterogeneous catalysts to enhance activity and selectivity. Nat. Catal. 2019, 2, 955–970.
Crossref Google Scholar
12

Weiner, R. G.; Kunz, M. R.; Skrabalak, S. E. Seeding a new kind of garden: Synthesis of architecturally defined multimetallic nanostructures by seed-mediated Co-reduction. Acc. Chem. Res. 2015, 48, 2688–2695.
Crossref Google Scholar
13

Liu, H. L.; Nosheen, F.; Wang, X. Noble metal alloy complex nanostructures: Controllable synthesis and their electrochemical property. Chem. Soc. Rev. 2015, 44, 3056–3078.
Crossref Google Scholar
14

Gilroy, K. D.; Ruditskiy, A.; Peng, H. C.; Qin, D.; Xia, Y. N. Bimetallic nanocrystals: Syntheses, properties, and applications. Chem. Rev. 2016, 116, 10414–10472.
Crossref Google Scholar
15

Zhuang, G. X.; Chen, Y. W.; Zhuang, Z. Y.; Yu, Y.; Yu, J. G. Oxygen vacancies in metal oxides: Recent progress towards advanced catalyst design. Sci. China Mater. 2020, 63, 2089–2118.
Crossref Google Scholar
16

Shen, R. F.; Liu, Y. Y.; Wen, H.; Wu, X. L.; Han, G. S.; Yue, X. Z.; Mehdi, S.; Liu, T.; Cao, H. Q.; Liang, E. J. et al. Engineering bimodal oxygen vacancies and Pt to boost the activity toward water dissociation. Small 2022, 18, 2105588.
Crossref Google Scholar
17

Maurer, F.; Jelic, J.; Wang, J. J.; Gänzler, A.; Dolcet, P.; Wöll, C.; Wang, Y. M.; Studt, F.; Casapu, M.; Grunwaldt, J. D. Tracking the formation, fate and consequence for catalytic activity of Pt single sites on CeO2. Nat. Catal. 2020, 3, 824–833.
Crossref Google Scholar
18

Liu, J. Y. Catalysis by supported single metal atoms. ACS Catal. 2016, 7, 34–59.
Crossref Google Scholar
19

Hülsey, M. J.; Zhang, J. G.; Yan, N. Harnessing the wisdom in colloidal chemistry to make stable single-atom catalysts. Adv. Mater. 2018, 30, 1802304.
Crossref Google Scholar
20

Xia, Y. N.; Gilroy, K. D.; Peng, H. C.; Xia, X. H. Seed-mediated growth of colloidal metal nanocrystals. Angew. Chem., Int. Ed. 2017, 56, 60–95.
Crossref Google Scholar
21

Thanh, N. T. K.; Maclean, N.; Mahiddine, S. Mechanisms of nucleation and growth of nanoparticles in solution. Chem. Rev. 2014, 114, 7610–7630.
Crossref Google Scholar
22

Wu, K. J.; Tse, E. C. M.; Shang, C. X.; Guo, Z. X. Nucleation and growth in solution synthesis of nanostructures-from fundamentals to advanced applications. Prog. Mater. Sci. 2022, 123, 100821.
Crossref Google Scholar
23

Chen, D. T.; Zhang, L. H.; Du, J.; Wang, H. H.; Guo, J. Y.; Zhan, J. Y.; Li, F.; Yu, F. S. A tandem strategy for enhancing electrochemical CO2 reduction activity of single-atom Cu-S1N3 catalysts via integration with Cu nanoclusters. Angew. Chem., Int. Ed. 2021, 60, 24022–24027.
Crossref Google Scholar
24

Valencia, P. M.; Farokhzad, O. C.; Karnik, R.; Langer, R. Microfluidic technologies for accelerating the clinical translation of nanoparticles. Nat. Nanotechnol. 2012, 7, 623–629.
Crossref Google Scholar
25

Wei, H. H.; Huang, K; Zhang, L.; Ge, B. H.; Wang, D.; Lang, J. L.; Ma, J. Y.; Wang, D.; Zhang, S.; Li, Q. Y. et al. Ice melting to release reactants in solution syntheses. Angew. Chem., Int. Ed. 2018, 57, 3354–3359.
Crossref Google Scholar
26

Huang, K.; Zhang, L.; Xu, T.; Wei, H. H.; Zhang, R. Y.; Zhang, X. Y.; Ge, B. H.; Lei, M.; Ma, J. Y.; Liu, L. M. et al. –60 °C solution synthesis of atomically dispersed cobalt electrocatalyst with superior performance. Nat. Commun 2019, 10, 606.
Crossref Google Scholar
27

Zhang, C.; Shi, Y. M.; Yu, Y. F.; Du, Y. H.; Zhang, B. Engineering sulfur defects, atomic thickness, and porous structures into cobalt sulfide nanosheets for efficient electrocatalytic alkaline hydrogen evolution. ACS Catal. 2018, 8, 8077–8083.
Crossref Google Scholar
28

Zou, X. X.; Zhang, Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chem. Soc. Rev. 2015, 44, 5148–5180.
Crossref Google Scholar
29

Xu, M. L.; Li, D. D.; Sun, K.; Jiao, L.; Xie, C. F.; Ding, C. M.; Jiang, H. L. Interfacial microenvironment modulation boosting electron transfer between metal nanoparticles and MOFs for enhanced photocatalysis. Angew. Chem., Int. Ed. 2021, 60, 16372–16376.
Crossref Google Scholar
30

Huang, X. Y.; Liu, Y. Y.; Wen, H.; Shen, R. F.; Mehdi, S.; Wu, X. L.; Liang, E. J.; Guo, X. J.; Li, B. J. Ensemble-boosting effect of Ru-Cu alloy on catalytic activity towards hydrogen evolution in ammonia borane hydrolysis. Appl. Catal. B: Environ. 2021, 287, 119960.
Crossref Google Scholar
31

Huang, K.; Wang, R. Y.; Zhao, S. J.; Du, P.; Wang, H.; Wei, H. H.; Long, Y. Z.; Deng, B.; Lei, M.; Ge, B. H. et al. Atomic species derived CoOx clusters on nitrogen doped mesoporous carbon as advanced bifunctional electro-catalysts for Zn-air battery. Energy Storage Mater. 2020, 29, 156–162.
Crossref Google Scholar
32

Song, H.; Meng, X. G.; Wang, S. Y.; Zhou, W.; Song, S.; Kako, T.; Ye, J. H. Selective photo-oxidation of methane to methanol with oxygen over dual-cocatalyst-modified titanium dioxide. ACS Catal. 2020, 10, 14318–14326.
Crossref Google Scholar
33

To, T.; Sørensen, S. S.; Stepniewska, M.; Qiao, A.; Jensen, L. R.; Bauchy, M.; Yue, Y. Z.; Smedskjaer, M. M. Fracture toughness of a metal-organic framework glass. Nat. Commun. 2020, 11, 2593.
Crossref Google Scholar
34

Liu, S. H.; Zhang, Y. T.; Mao, X. N.; Li, L.; Zhang, Y.; Li, L. G.; Pan, Y.; Li, X. G.; Wang, L.; Shao, Q. et al. Ultrathin perovskite derived Ir-based nanosheets for high-performance electrocatalytic water splitting. Energy Environ. Sci. 2022, 15, 1672–1681.
Crossref Google Scholar
35

Zhang, J. Y.; Jiang, Y. H.; Fan, Q. Y.; Qu, M.; He, N. N.; Deng, J. X.; Sun, Y.; Cheng, J.; Liao, H. G.; Sun, S. G. Atomic scale tracking of single layer oxide formation: Self-peeling and phase transition in solution. Small Method 2021, 5, 2001234.
Crossref Google Scholar
36
Lide, D. R. Handbook of Chemistry and Physics; CRC Press: Boca Raton, 2004.
37

Xue, J. Y.; Ma, W. L.; Wang, L.; Cui, H. T. Surfactant-free large scale synthesis of Co3O4 quantum dots at room temperature. Adv. Powder Technol. 2016, 27, 2019–2024.
Crossref Google Scholar
38

Zhang, X. X.; Sun, X.; Li, Y. L.; Hu, F. C.; Xu, Y.; Tian, J.; Zhang, H.; Liu, Q. H.; Su, H.; Wei, S. Q. Reduced interfacial tension on ultrathin NiCr-LDH nanosheet arrays for efficient electrocatalytic water oxidation. J. Mater. Chem. A 2021, 9, 16706–16712.
Crossref Google Scholar
39

Zhao, R. R.; Zhang, J. L.; Lee, G. H.; Zhang, K.; Lau, V. W. H.; Lee, J. J.; Moudrakovski, I.; Yang, Y. L.; Zou, F.; Park, M. et al. The origin of heavy element doping to relieve the lattice thermal vibration of layered materials for high energy density Li ion cathodes. J. Mater. Chem. A 2020, 8, 12424–12435.
Crossref Google Scholar
40

Li, L.; Wang, B.; Zhang, G. W.; Yang, G.; Yang, T.; Yang, S.; Yang, S. C. Electrochemically modifying the electronic structure of IrO2 nanoparticles for overall electrochemical water splitting with extensive adaptability. Adv. Energy Mater. 2020, 10, 2001600.
Crossref Google Scholar
41

Kim, Y. T.; Lopes, P. P.; Park, S. A.; Lee, A. Y.; Lim, J.; Lee, H.; Back, S.; Jung, Y.; Danilovic, N.; Stamenkovic, V. et al. Balancing activity, stability and conductivity of nanoporous core–shell iridium/iridium oxide oxygen evolution catalysts. Nat. Commun. 2017, 8, 1449.
Crossref Google Scholar
42

Weerakkody, C.; Biswas, S.; Song, W. Q.; He, J. K.; Wasalathanthri, N.; Dissanayake, S.; Kriz, D. A.; Dutta, B.; Suib, S. L. Controllable synthesis of mesoporous cobalt oxide for peroxide free catalytic epoxidation of alkenes under aerobic conditions. Appl. Catal. B: Environ. 2018, 221, 681–690.
Crossref Google Scholar
43

Niu, H.; Yang, Q. H.; Wang, Q.; Jing, X. Y.; Zhu, K.; Ye, K.; Wang, G. L.; Cao, D. X.; Yang, J. Oxygen vacancies-enriched sub-7 nm cross-linked Bi288Fe5O12–x nanoparticles anchored MXene for electrochemical energy storage with high volumetric performances. Nano Energy 2020, 78, 105360.
Crossref Google Scholar
44

Wan, J. W.; Chen, W. X.; Jia, C. Y.; Zheng, L. R.; Dong, J. C.; Zheng, X. S.; Wang, Y.; Yan, W. S.; Chen, C.; Peng, Q. et al. Defect effects on TiO2 nanosheets: Stabilizing single atomic site Au and promoting catalytic properties. Adv. Mater. 2018, 30, 1705369.
Crossref Google Scholar
45

Kraftmakher, Y. Equilibrium vacancies and thermophysical properties of metals. Phys. Rep. 1998, 299, 79–188.
Crossref Google Scholar
46

Liu, T. T.; Yang, S. X.; Guan, J. Y.; Niu, J.; Zhang, Z. P.; Wang, F. Quenching as a route to defect-rich Ru-pyrochlore electrocatalysts toward the oxygen evolution reaction. Small Method 2022, 6, 2101156.
Crossref Google Scholar
47

Ye, C. C.; Liu, J. Z.; Zhang, Q. H.; Jin, X. J.; Zhao, Y.; Pan, Z. H.; Chen, G. X.; Qiu, Y. C.; Ye, D. Q.; Gu, L. et al. Activating metal oxides nanocatalysts for electrocatalytic water oxidation by quenching-induced near-surface metal atom functionality. J. Am. Chem. Soc. 2021, 143, 14169–14177.
Crossref Google Scholar
48

Ham, K.; Hong, S.; Kang, S. N. W. O.; Cho, K.; Lee, J. Extensive active-site formation in trirutile CoSb2O6 by oxygen vacancy for oxygen evolution reaction in anion exchange membrane water splitting. ACS Energy Lett. 2021, 6, 364–370.
Crossref Google Scholar
49

Choi, C.; Kwon, S.; Cheng, T.; Xu, M. J.; Tieu, P.; Lee, C.; Cai, J.; Lee, H. M.; Pan, X. Q.; Duan, X. F. et al. Highly active and stable stepped Cu surface for enhanced electrochemical CO2 reduction to C2H4. Nat. Catal. 2020, 3, 804–812.
Crossref Google Scholar
Nano Research
Volume 15 Issue 9,
September 2022
Pages 7933-7939
DOI: 10.1007/s12274-022-4465-5
Cite this article:
Wang R, Cheng F, Wang Y, et al. Nucleation growth quenching for superior cluster catalysts. Nano Research, 2022, 15(9): 7933-7939. https://doi.org/10.1007/s12274-022-4465-5
Topics:
Nanocatalysts

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Received: 03 March 2022
Revised: 12 April 2022
Accepted: 22 April 2022
Published: 30 June 2022
© Tsinghua University Press 2022
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