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Research Article

Atomic mechanisms of hexagonal close-packed Ni nanocrystallization revealed by in situ liquid cell transmission electron microscopy

Junyu Zhang1( ), Miao Li2, Zewen Kang3, Bensheng Xiao2, Haichen Lin7, Jingyu Lu6, Haodong Liu7, Xue Zhang4( ), Dong-Liang Peng2, Qiaobao Zhang2,5( )
Instrumental Analysis Center, Laboratory and Equipment Management Department, Huaqiao University, Xiamen 361021, China
Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005, China
College of Chemical Engineering, Huaqiao University, Xiamen 361021, China
Center for Materials and Interfaces, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, 1068 Xueyuan Avenue, Shenzhen 518055, China
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen 361005, China
School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China
Chemical Engineering, University of California San Diego, La Jolla, CA 92093, USA
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Graphical Abstract

The amorphous-phase-mediated crystallization of Ni hexagonal close-packed nanoparticles in homogeneous solution through spinodal decomposition, solidification and crystallization is explicitly unraveled by combining in situ liquid cell transmission electron microscopy (TEM) and theoretical analysis.

Abstract

The fundamental understanding of the mechanism underlying the early stages of crystallization of hexagonal-close-packed (hcp) nanocrystals is crucial for their synthesis with desired properties, but it remains a significant challenge. Here, we report using in situ liquid cell transmission electron microscopy (TEM) to directly capture the dynamic nucleation process and track the real-time growth pathway of hcp Ni nanocrystals at the atomic scale. It is demonstrated that the growth of amorphous-phase-mediated hcp Ni nanocrystals is from the metal-rich liquid phases. In addition, the reshaped preatomic facet development of a single nanocrystal is also imaged. Theoretical calculations further identify the non-classical features of hcp Ni crystallization. These discoveries could enrich the nucleation and growth model theory and provide useful information for the rational design of synthesis pathways of hcp nanocrystals.

Keywords

hexagonal-close-packed (hcp) nanocrystalsliquid cell transmission electron microscopy (TEM)amorphous-phase-mediatedreshape

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References

1

Shao, Q.; Wang, Y.; Yang, S. Z.; Lu, K. Y.; Zhang, Y.; Tang, C. Y.; Song, J.; Feng, Y. G.; Xiong, L. K.; Peng, Y. et al. Stabilizing and activating metastable nickel nanocrystals for highly efficient hydrogen evolution electrocatalysis. ACS Nano 2018, 12, 11625–11631.
Crossref Google Scholar
2

Zhuang, J. H.; Liu, X. L.; Ji, Y. J.; Gu, F. N.; Xu, J.; Han, Y. F.; Xu, G. W.; Zhong, Z. Y.; Su, F. B. Phase-controlled synthesis of Ni nanocrystals with high catalytic activity in 4-nitrophenol reduction. J. Mater. Chem. A 2020, 8, 22143–22154.
Crossref Google Scholar
3

Han, M.; Liu, Q.; He, J.; Song, Y.; Xu, Z.; Zhu, J. M. Controllable synthesis and magnetic properties of cubic and hexagonal phase NICKEL nanocrystals. Adv. Mater. 2007, 19, 1096–1100.
Crossref Google Scholar
4

LaGrow, A. P.; Cheong, S.; Watt, J.; Ingham, B.; Toney, M. F.; Jefferson, D. A.; Tilley, R. D. Can polymorphism be used to form branched metal nanostructures? Adv. Mater. 2013, 25, 1552–1556.
Crossref Google Scholar
5
Richard-Plouet, M.; Guillot, M.; Vilminot, S. ; Leuvrey, C.; Estournès, C.; Kurmoo, M. hcp and fcc Nickel nanoparticles prepared from organically functionalized layered phyllosilicates of nickel(II). Chem. Mater. 2007, 19, 865–871.https://doi.org/10.1021/cm062521c
Crossref
6

Kim, C.; Kim, C.; Lee, K.; Lee, H. Shaped Ni nanoparticles with an unconventional hcp crystalline structure. Chem. Commun. 2014, 50, 6353–6356.
Crossref Google Scholar
7

Singh, J.; Kaurav, N.; Lallac, N. P.; Okram, G. S. Naturally self-assembled nickel nanolattice. J. Mater. Chem. C 2014, 2, 8918–8924.
Crossref Google Scholar
8

Tan, X. Y.; Geng, S. Z.; Ji, Y. J.; Shao, Q.; Zhu, T.; Wang, P. T.; Li, Y. Y.; Huang, X. Q. Closest packing polymorphism interfaced metastable transition metal for efficient hydrogen evolution. Adv. Mater. 2020, 32, 2002857.
Crossref Google Scholar
9

He, K.; Sawczyk, M.;  Liu, C.; Yuan, Y. F.; Song, B. A.; Deivanayagam, R.; Nie, A. M.; Hu, X. B.; Dravid, V. P.; Lu, J. et al. Revealing nanoscale mineralization pathways of hydroxyapatite using in situ liquid cell transmission electron microscopy. Sci. Adv. 2020, 6, eaaz7524.
Crossref Google Scholar
10
Nielsen, M. H. ; Aloni, S. ; De Yoreo, J. J. In situ TEM imaging of CaCO3 nucleation reveals coexistence of direct and indirect pathways. Science 2014, 345, 1158–1162.https://doi.org/10.1126/science.1254051
Crossref
11

De Yoreo, J. J.; Gilbert, P. U. P. A.; Sommerdijk, N. A. J. M.; Lee Penn, R.; Whitelam, S.; Joester, D.; Zhang, H. Z.; Rimer, J. D.; Navrotsky, A.; Banfield, J. F. et al. Crystallization by particle attachment in synthetic, biogenic, and geologic environments. Science 2015, 349, aaa6760.
Crossref Google Scholar
12

Woehl, T. J. Metal nanocrystal formation during liquid phase transmission electron microscopy: Thermodynamics and kinetics of precursor conversion, nucleation, and growth. Chem. Mater. 2020, 32, 7569–7581.
Crossref Google Scholar
13
Lupulescu, A. I. ; Rimer, J. D. In situ imaging of silicalite-1 surface growth reveals the mechanism of crystallization. Science 2014, 344, 729–732.https://doi.org/10.1126/science.1250984
Crossref
14

Cölfen, H.; Antonietti, M. Mesocrystals: Inorganic superstructures made by highly parallel crystallization and controlled alignment. Angew. Chem. , Int. Ed. 2005, 44, 5576–5591.
Crossref Google Scholar
15

Navrotsky, A. Energetic clues to pathways to biomineralization: Precursors, clusters, and nanoparticles. Proc. Natl. Acad. Sci. USA 2004, 101, 12096–12101.
Crossref Google Scholar
16

Tan, S. F.; Chee, S. W.; Lin, G.; Mirsaidov, U. Direct observation of interactions between nanoparticles and nanoparticle self-assembly in solution. Acc. Chem. Res. 2017, 50, 1303–1312.
Crossref Google Scholar
17

Zheng, H. M. Imaging, understanding, and control of nanoscale materials transformations. MRS Bull. 2021, 46, 443–450.
Crossref Google Scholar
18

Zheng, W. J.; Hauwiller, M. R.; Liang, W. I.; Ophus, C.; Ercius, P.; Chan, E. M.; Chu, Y. H.; Asta, M.; Du, X. W.; Alivisatos, A. P. et al. Real time imaging of two-dimensional iron oxide spherulite nanostructure formation. Nano Res. 2019, 12, 2889–2893.
Crossref Google Scholar
19

Liao, H. G.; Zherebetskyy, D.; Xin, H. L.; Czarnik, C.; Ercius, P.; Elmlund, H.; Pan, M.; Wang, L. W.; Zheng, H. M. Facet development during platinum nanocube growth. Science 2014, 345, 916–919.
Crossref Google Scholar
20

Liao, H. G.; Zheng, H. M. Liquid cell transmission electron microscopy study of platinum iron nanocrystal growth and shape evolution. J. Am. Chem. Soc. 2013, 135, 5038–5043.
Crossref Google Scholar
21

Kim, B. H.; Heo, J.; Kim, S.; Reboul, C. F.; Chun, H.; Kang, D.; Bae, H.; Hyun, H.; Lim, J.; Lee, H. et al. Critical differences in 3D atomic structure of individual ligand-protected nanocrystals in solution. Science 2020, 368, 60–67.
Crossref Google Scholar
22

Wang, M.; Leff, A. C.; Li, Y.; Woehl, T. J. Visualizing ligand-mediated bimetallic nanocrystal formation pathways with in situ liquid-phase transmission electron microscopy synthesis. ACS Nano 2021, 15, 2578–2588.
Crossref Google Scholar
23

Liu, Z. M.; Zhang, Z. S.; Wang, Z. M.; Jin, B.; Li, D. S.; Tao, J. H.; Tang, R. K.; De Yoreo, J. J. Shape-preserving amorphous-to-crystalline transformation of CaCO3 revealed by in situ TEM. Proc. Natl. Acad. Sci. USA 2020, 117, 3397–3404.
Crossref Google Scholar
24

Ke, C. Z.; Xiao B. S.; Li, M.; Lu, J. Y.; He, Y.; Zhang, L.; Zhang, Q. B. Research progress in understanding of lithium storage behavior and reaction mechanism of electrode materials through in situ transmission electron microscopy. Energy Storage Sci. Technol. 2021, 10, 1219–1236.
Google Scholar
25

Feng, X. Y.; Wu, H. H.; Gao, B.; Świętosławski, M.; He, X.; Zhang, Q. B. Lithiophilic N-doped carbon bowls induced Li deposition in layeredgraphene film for advanced lithium metal batteries. Nano Res. 2022, 15, 352–360.
Crossref Google Scholar
26

Sutter, P.; Sutter, E. Real-time electron microscopy of nanocrystal synthesis, transformations, and self-assembly in solution. Acc. Chem. Res. 2021, 54, 11–21.
Crossref Google Scholar
27

Loh, N. D.; Sen, S.; Bosman, M.; Tan, S. F.; Zhong, J.; Nijhuis, C. A.; Král, P.; Matsudaira, P.; Mirsaidov, U. Multistep nucleation of nanocrystals in aqueous solution. Nat. Chem. 2017, 9, 77–82.
Crossref Google Scholar
28
Zhang, J. Y. ; Sun, S. G. ; Liao, H. G. In-situ liquid cell TEM investigation on assembly and symmetry transformation of Pt superlattice. Sci. China Mater. 2020, 63, 602–610.https://doi.org/10.1007/s40843-019-1219-y
Crossref
29

Jin, B.; Wang, Y. M.; Liu, Z. M.; France-Lanord, A.; Grossman, J. C.; Jin, C. H.; Tang, R. K. Revealing the cluster-cloud and its role in nanocrystallization. Adv. Mater. 2019, 31, 1808225.
Crossref Google Scholar
30

Dachraoui, W.; Keller, D.; Henninen, T. R.; Ashton, O. J.; Erni, R. Atomic mechanisms of nanocrystallization via cluster-clouds in solution studied by liquid-phase scanning transmission electron microscopy. Nano Lett. 2021, 21, 2861–2869.
Crossref Google Scholar
31

Yang, J.; Koo, J.; Kim, S.; Jeon, S.; Choi, B. K.; Kwon, S.; Kim, J.; Kim, B. H.; Lee, W. C.; Lee, W. B. et al. Amorphous-phase-mediated crystallization of Ni nanocrystals revealed by high-resolution liquid-phase electron microscopy. J. Am. Chem. Soc. 2019, 141, 763–768.
Crossref Google Scholar
32

Zhang, J. Y.; Li, G.; Liao, H. G.; Sun, S. G. Tracking the atomic pathways of Pt3Ni-Ni(OH)2 core-shell structures at the gas-liquid interface by in-situ liquid cell TEM. Sci. China Chem. 2020, 63, 513–518.
Crossref Google Scholar
33

Zhang, J. Y.; Zhang, X.; Yang, D. P.; Zhao, P. Ligand-induced motion and self-assembly pathways between nanocubes. J. Phys. Chem. Lett. 2021, 12, 2429–2436.
Crossref Google Scholar
34

Zhang, J. Y.; Jiang, Y. H.; Fan, Q. Y.; Qu, M.; He, N.; Deng, J. X.; Sun, Y.; Cheng, J.; Liao, H. G.; Sun, S. G. Atomic scale tracking of single layer oxide formation: Self-peeling and phase transition in solution. Small Methods 2021, 5, 20001234.
Crossref Google Scholar
35

Zhang, J. Y. Atomic-scale imaging of the growth and transformation of Pt3Ni-NiO nanoparticles. New J. Chem. 2021, 45, 2217–2220.
Crossref Google Scholar
36
Geng, L. ; Liu, Q. N. ; Chen, J. Z. ; Jia, P. ; Ye, H. J. ; Yan, J. T. ; Zhang, L. Q. ; Tang, Y. F. ; Huang, J. Y. In situ observation of electrochemical Ostwald ripening during sodium deposition. Nano Res. 2022, 15, 2650–2654.https://doi.org/10.1007/s12274-021-3861-6
Crossref
37

VandeVondele, J.; Krack, M.; Mohamed, F.; Parrinello, M.; Chassaing, T.; Hutter, J. QUICKSTEP: Fast and accurate density functional calculations using a mixed Gaussian and plane waves approachPhys. Comput. Phys. Commun. 2005, 167, 103–128.
Crossref Google Scholar
38

VandeVondele, J.; Hutter, J. Gaussian basis sets for accurate calculations on molecular systems in gas and condensed phases. J. Chem. Phys. 2007, 127, 114105.
Crossref Google Scholar
39

Goedecker, S.; Teter, M.; Hutter, J. Separable dual-space Gaussian pseudopotentials. Phys. Rev. B. 1996, 54, 1703–1710.
Crossref Google Scholar
40

Hartwigsen, C.; Goedecker, S.; Hutter, J. Relativistic separable dual-space Gaussian pseudopotentials from H to Rn. Phys. Rev. B. 1998, 58, 3641–3662.
Crossref Google Scholar
41

Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868.
Crossref Google Scholar
42

Grimme, S.; Antony, J.; Ehrlich, S.; Krieg, H. A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. J. Chem. Phys. 2010, 132, 154104.
Crossref Google Scholar
43

Monkhorst, H. J.; Pack, J. D. Special points for Brillouin-zone integrations. Phys. Rev. B 1976, 13, 5188–5192.
Crossref Google Scholar
44

Liu, J. X.; Zhang, B. Y.; Chen, P. P.; Su, H. Y.; Li, W. X. CO dissociation on face-centered cubic and hexagonal close-packed nickel catalysts: A first-principles study. J. Phys. Chem. C 2016, 120, 24895–24903.
Crossref Google Scholar
Nano Research
Volume 15 Issue 7,
July 2022
Pages 6772-6778
DOI: 10.1007/s12274-022-4475-3
Cite this article:
Zhang J, Li M, Kang Z, et al. Atomic mechanisms of hexagonal close-packed Ni nanocrystallization revealed by in situ liquid cell transmission electron microscopy. Nano Research, 2022, 15(7): 6772-6778. https://doi.org/10.1007/s12274-022-4475-3
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Received: 27 January 2022
Revised: 24 April 2022
Accepted: 26 April 2022
Published: 13 May 2022
© Tsinghua University Press 2022
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