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Research Article

Ion compaction effect in hollow FePt nanochains with ultrathin shell under low energy ion irradiation

Jialong Liu1( ), Jianguo Wu2,3, Long Cheng4, Suyun Niu5, Zhiqiang Wang6, Mengyuan Zhu7, Jingyan Zhang7, Shouguo Wang7( ), Wei Wang1( )
School of Mathematics and Physics, Beijing University of Chemical Technology, Beijing 100029, China
Key Laboratory of Shale Gas and Engineering, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
Innovation Academy for Earth Science, Chinese Academy of Sciences, Beijing 100029, China
School of Physics, Beihang University, Beijing 100029, China
Beijing Hangxing Machinery Manufacturing Co., Ltd., Beijing 100013, China
Beijing Smart-chip Microelectronics Technology Co., Ltd., Beijing 100192, China
Beijing Advanced Innovation Center for Materials Genome Engineering, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
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Graphical Abstract

The compaction effect has been observed in hollow FePt nanochains under low energy ions irradiation. The volume and microstructure of hollow architecture can be manipulated by ions.

Abstract

The morphology manipulation of nanomaterials by ion irradiation builds a way to precisely control physicochemical properties. Under the continuous irradiation of low energy Ga+, Ne+, and He+ ions, an ion compaction effect has been found in hollow FePt nanochains with ultrathin shell that the volumes of the nanochains are gradually compacted by ions. The deep learning algorithm has been successfully applied to automatically and precisely measure average sizes of spheres in hollow FePt nanochains. The compaction under ion irradiation is very fast in the very early period and then proceeds to a slow region. The compaction rates in both regions are linearly fitted and all the values are in the order of 10–17 to 10–14 cm2/ion. Ion species and ion current have effect on the compaction rate. For example, the compaction rate of Ga+ ions is larger than those of Ne+ and He+ ions under an identical current, while irradiation with larger current can compact nanochains faster. The ion compaction effect originates from the local shear deformation caused by the interaction between incident ions and the electrons of Fe and Pt atoms in the ultrathin shell. With continuous irradiation, the crystalline clusters of FePt nanchains firstly grow larger and then become amorphous. The ion compaction effect can be applied to tune the size and crystal structure of hollow structures with a precise rate by choosing appropriate ion species and current.

Keywords

ion compaction effecthollow structureion irradiationFePt

Electronic Supplementary Material

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Nano Research
Volume 15 Issue 10,
October 2022
Pages 9309-9318
DOI: 10.1007/s12274-022-4531-z
Cite this article:
Liu J, Wu J, Cheng L, et al. Ion compaction effect in hollow FePt nanochains with ultrathin shell under low energy ion irradiation. Nano Research, 2022, 15(10): 9309-9318. https://doi.org/10.1007/s12274-022-4531-z
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Received: 07 March 2022
Revised: 27 April 2022
Accepted: 11 May 2022
Published: 27 June 2022
© Tsinghua University Press 2022
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