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Research Article

Large-scale synthesis of fluorine-free carbonyl iron-organic silicon hydrophobic absorbers with long term corrosion protection property

Wei Tian1, Jinyao Li2,3, Yifan Liu3, Longjiang Deng1( ), Yang Guo4( ), Xian Jian1,2,3( )
National Engineering Researching Centre of Electromagnetic Radiation Control Materials, Key Laboratory of Multi-Spectral Absorbing Materials and Structures of Ministry of Education, State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 611731, China
The Yangtze Delta Region Institute (Huzhou) & School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Huzhou 313001, China
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China
School of Electrical and Information Engineering, Panzhihua University, Panzhihua 617000, China
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Graphical Abstract

Carbonyl iron (CI)@SiO2/1,1,1,3,3,3-hexamethyl disilazane (HMDS) hybrid exhibits excellent microwave absorption and long-term corrosion protection properties, largely due to the extraordinary wave-transparent and shielding ability of hydrophobic protective layer.

Abstract

Environmentally-friendly magnetic metallic absorbers with high-performing antioxidant property, thermal stability, and anti-corrosion capability have attracted great attention in real-world applications. A surface modification technology of magnetic metallic absorbers with dense and inert materials has been an effective strategy to solve the aforesaid problem. Herein, fluorine-free core–shell carbonyl iron-organic silicon absorbers (CI@SiO2/1,1,1,3,3,3-hexamethyl disilazane (HMDS)) were fabricated via a facile one-pot synthesis using tetraethyl orthosilicate (TEOS) and HMDS as the precursor of protective layer (SiO2/HMDS), and CI@SiO2/HMDS hybrid reveals its long-term corrosion resistance and excellent microwave absorption performance with a minimum reflection loss value of −44.3 dB and an effective absorption bandwidth of 5.3 GHz at a thin thickness of 2.0 mm after immersion in 5.0 wt.% NaCl acidic solutions for 2,160 h. Meanwhile, CI@SiO2/HMDS hybrid can still achieve the maximum radar cross-sectional (RCS) reduction values about 16.5 dB·m2 at the detection θ of 0°. The exceptional microwave absorption performance and structural stability are largely due to the extraordinary wave-transparent property and shielding ability against corrosive medium of SiO2/HMDS hydrophobic protective layer with a contact angle of 132.5°. The research paves the way for the large-scale and batch production of high-performance magnetic metallic absorbers and increases their survivability and reliability in the harsh environments.

Keywords

microwave absorptionlong-term corrosion resistancecarbonyl iron (CI)@SiO2/1,1,1,3,3,3-hexamethyl disilazane (HMDS) hybridcore–shellradar cross-sectional simulation

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Nano Research
Volume 15 Issue 10,
October 2022
Pages 9479-9491
DOI: 10.1007/s12274-022-4569-y
Cite this article:
Tian W, Li J, Liu Y, et al. Large-scale synthesis of fluorine-free carbonyl iron-organic silicon hydrophobic absorbers with long term corrosion protection property. Nano Research, 2022, 15(10): 9479-9491. https://doi.org/10.1007/s12274-022-4569-y
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Received: 10 April 2022
Revised: 17 May 2022
Accepted: 19 May 2022
Published: 08 July 2022
© Tsinghua University Press 2022
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