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Research Article

Free-standing Na2C6O6/MXene composite paper for high-performance organic sodium-ion batteries

Zhengran Wang1,2,§, Yuchan Zhang1,§, Huiyu Jiang1, Chuanliang Wei1, Yongling An1, Liwen Tan1, Shenglin Xiong2, Jinkui Feng1,2( )
Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Research Center for Carbon Nanomaterials, School of Materials Science and Engineering, Shandong University, Jinan 250061, China
Shenzhen Institute of Shandong University, Shenzhen 518057, China

§ Zhengran Wang and Yuchan Zhang contributed equally to this work.

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Graphical Abstract

In this work, flexible and highly conductive MXene paper is utilized as an efficienct host to address the dissolution and low electronic conductivity issues of disodium rhodizonate electrode for sodium-ion batteries.

Abstract

Sodium-ion batteries (SIBs) are regarded as the ideal low-cost choice for next-generation large-scale energy storage system. Carbonyl-based organic salt-disodium rhodizonate (Na2C6O6) with high theoretical specific capacity (501 mAh·g−1) is considered as a promising cathode material for SIBs. However, the dissolution of active material in electrolyte and low electronic conductivity lead to rapidly capacity decay and poor rate performance. Herein, a simple method is designed to construct free-standing and flexible Ti3C2Tx Na2C6O6/MXene paper via vacuum-assisted filtration and antisolvent approach. The MXene can form an electronic conductive network, adsorb the active materials, and offer additional active sites for Na storage. The binder-free Na2C6O6/MXene paper delivers excellent electrochemical property with a high rate performance of 231 mAh·g−1 at 1,000 mA·g−1 and a high capacity of 215 mAh·g−1 after 100 cycles. This work provides an attractive strategy for designing high-performance organic electrode materials of SIBs.

Keywords

sodium-ion batteriesNa2C6O6 cathodeMXeneorganic batteryflexiblefree-standing

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Nano Research
Volume 16 Issue 1,
January 2023
Pages 458-465
DOI: 10.1007/s12274-022-4696-5
Cite this article:
Wang Z, Zhang Y, Jiang H, et al. Free-standing Na2C6O6/MXene composite paper for high-performance organic sodium-ion batteries. Nano Research, 2023, 16(1): 458-465. https://doi.org/10.1007/s12274-022-4696-5
Topics:
Secondary batteries

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Received: 22 May 2022
Revised: 07 June 2022
Accepted: 23 June 2022
Published: 16 July 2022
© Tsinghua University Press 2022
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