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Review Article

Recent advances in nature-inspired nanocatalytic reduction of organic molecules with water

Hongli Sun1, Wei Ou1, Like Sun1, Bo Wang2, Chenliang Su1( )
International Collaboration Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518060, China
CAS Key Laboratory of Quantitative Engineering Biology, Shenzhen Institute of Synthetic Biology, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China
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Graphical Abstract

The [H]s-involved semi-artificial organic synthesis and artificial nanocatalytic reduction of organic molecules with water as the hydrogen donor. In the presence of nanocatalysts, the proton or the water can be reduced by the photocatalytically or electrocatalytically generated electrons to furnish reactive hydrogen species [H]s, which function in the form of powerful reducing equivalents (NAD(P)H, etc.) in semi-artificial systems. These reactive hydrogen species can efficiently assist the reduction of CO2 or organic molecules to synthesize green liquid fuels, and fine chemicals and pharmaceuticals.

Abstract

Nature has provided us the assurance and inspiration for thousands of years in synthesizing value-added chemicals, with the assistance of reactive hydrogen species, and water as the ultimate hydrogen source. However, the natural photosynthesis is inefficient due to some intrinsic properties, urging people not only to learn from but also surpass during nature imitation. In this review, we summarized recent progresses on reactive hydrogen species-assisted nanocatalytic reduction of organic molecules towards value-added fine chemicals and pharmaceuticals, with water as the hydrogen source, and especially highlighted how photocatalytically or electrocatalytically evolved reactive hydrogen species synergize with biocatalytic centers and nanocatalytic sites for reduction of organic molecules. The design principles of collaborative semi-artificial systems and nanocatalytic artificial systems, the structure tuning of catalysts for the evolution and utilization of hydrogen species, and the determination of reactive hydrogen species for mechanistic insights were discussed in detail. Finally, perspectives were provided for further advancing this emerging area of nanocatalytic reduction of organic molecules from water (or proton) and organics.

Keywords

nano-catalystsreactive hydrogen speciesnature inspirationreduction of organic molecules

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Nano Research
Volume 15 Issue 12,
December 2022
Pages 10292-10315
DOI: 10.1007/s12274-022-4737-0
Cite this article:
Sun H, Ou W, Sun L, et al. Recent advances in nature-inspired nanocatalytic reduction of organic molecules with water. Nano Research, 2022, 15(12): 10292-10315. https://doi.org/10.1007/s12274-022-4737-0
Topics:
Nanocatalysts
Part of a topical collection:
NR45 Awards in Nanocatalysis, 2022

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Received: 13 May 2022
Revised: 29 June 2022
Accepted: 02 July 2022
Published: 15 August 2022
© Tsinghua University Press 2022
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