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Research Article

Zinc-catecholete frameworks biomimetically grown on marine polysaccharide microfibers for soft electronic platform

Kai Liu, Mingxin Zhang, Xinxin Du, Anqin Zhou, Bin Hui, Yanzhi Xia( ), Kewei Zhang( )
State Key Laboratory of Bio-Fibers and Eco-Textiles, Collaborative Innovation Center for Marine Biomass Fibers, Materials and Textiles of Shandong Province, College of Materials Science and Engineering, Institute of Marine Biobased Materials, Qingdao University, Qingdao 266071, China
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Graphical Abstract

A facile heteroepitaxial strategy is demonstrated to biomimetically grow conductive zinc-catecholate frameworks with honeycomb lattice on marine polysaccharide microfibers. Benefiting from amplification effect of the in-situ formed heterojunctions, promoted interfacial charge transfer is achieved, which allows for fabricating biocompatible and high-performance photodetector and chemiresistive sensors.

Abstract

Integrating functional nanomaterials on nonplanar organisms has emerged as a rising technology, while significant mismatch would cause interface failure and poor durability. Herein, we demonstrate a facile strategy to assemble crystalline catecholate frameworks with honeycomb lattice on seaweed-derived polysaccharide microfibers, which is expected to form biomimetic connections and maintain durable stability. By physiological coagulation, well-aligned ZnO nanoarrays are tightly attached on alginate fibers, which is fractionally adopted as sacrifice for heteroepitaxial growth of zinc-catecholate frameworks (Zn3(HHTP)2). Benefiting from amplification effect of in-situ formed heterojunctions, promoted interfacial charge transfer is achieved, which allows for fabricating broadband photodetectors. Combined with high porosity for gas adsorption, the heteroepitaxial catecholate framework further enables its use as highly selective ppb-level triethylamine sensors. This work provides a promising strategy for heteroepitaxial growth of catecholate frameworks on organo-substrates and opens new applications in wearable sensor platform based on comfortable biofibers.

Keywords

metal-organic frameworksepitaxial growthheterostructuressensorsbiofibers

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Nano Research
Volume 16 Issue 1,
January 2023
Pages 1296-1303
DOI: 10.1007/s12274-022-4798-0
Cite this article:
Liu K, Zhang M, Du X, et al. Zinc-catecholete frameworks biomimetically grown on marine polysaccharide microfibers for soft electronic platform. Nano Research, 2023, 16(1): 1296-1303. https://doi.org/10.1007/s12274-022-4798-0
Topics:
NanofibersNanosensors Organic frameworks Semiconductor junctions

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Received: 24 May 2022
Revised: 21 July 2022
Accepted: 21 July 2022
Published: 09 August 2022
© Tsinghua University Press 2022
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