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Research Article

Wrinkling modes of graphene oxide assembled on curved surfaces

Kaiwen Li1,§, Zhanpo Han2,§, Lidan Wang1, Jiaqing Wang1, Chuanwei Zhang3, Jiahao Lin1, Shiyu Luo1, Li Peng1, Wenzhang Fang1, Yingjun Liu1,4, Ziliang Wu3, Yeqiang Tan2, Chao Gao1, Zhen Xu1( )
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Zhejiang University, Hangzhou 310027, China
State Key Laboratory of Bio-Fibers and Eco-Textiles, Collaborative Innovation Center of Marine Biobased Fiber and Ecological Textile Technology, School of Materials Science and Engineering, Qingdao University, Qingdao 266071, China
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan 030000, China

§ Kaiwen Li and Zhanpo Han contributed equally to this work.

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Graphical Abstract

We revealed the mismatch of curvature as the origin of the wrinkling modes selection and offered a new description paradigm to quantitatively measure the complex wrinkling patterns.

Abstract

Assembling two-dimensional (2D) sheets into macroscopic three-dimensional (3D) forms has created a promising material family with rich functionalities. Multiscale wrinkles are intrinsic features of 2D sheets in their 3D assembles. Therefore, the precise wrinkling modulation optimizes the transition of outstanding properties of 2D sheets to expected performances of assembled materials and dominates their fabrication process. The wrinkling evolution of 2D sheets assembling onto flat surfaces has been extensively understood, however, the wrinkling behaviors on the more generally curved surface still remain unclear. Here, we investigate the wrinkling behaviors of graphene oxide sheets assembled onto curved surfaces and reveal the selection rule of wrinkling modes that determined by the curvature mismatch between 2D sheets and target surfaces. We uncover that three wrinkling modes including isotropic cracked land, labyrinth, and anisotropic curtain phases, respectively emerge on flat, spherical, and cylindrical surfaces. A favorable description paradigm is offered to quantitatively measure the complex wrinkling patterns and assess the curvature mismatch constraint underlying the wrinkling mode selection. This research provides a general and quantitative description framework of wrinkling modulation of 2D materials such as high performance graphene fibers, and guides the precise fabrication of particles and functional coatings.

Keywords

two-dimensional (2D) sheetsthree-dimensional (3D) assemblescurved surfaceswrinkling modes selectioncurvature mismatch constraintwrinkling modulation

Electronic Supplementary Material

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Nano Research
Volume 16 Issue 2,
February 2023
Pages 1801-1809
DOI: 10.1007/s12274-022-4895-0
Cite this article:
Li K, Han Z, Wang L, et al. Wrinkling modes of graphene oxide assembled on curved surfaces. Nano Research, 2023, 16(2): 1801-1809. https://doi.org/10.1007/s12274-022-4895-0
Topics:
Graphene oxide

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Received: 25 June 2022
Revised: 26 July 2022
Accepted: 10 August 2022
Published: 27 September 2022
© Tsinghua University Press 2022
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