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Research Article

Efficient quantum dot infrared solar cells with enhanced low-energy photon conversion via optical engineering

Sisi Liu1,§, Ming-Yu Li1,§, Kao Xiong2, Jianbo Gao3, Xinzheng Lan2, Daoli Zhang2, Liang Gao2( ), Jianbing Zhang2,4,5( ), Jiang Tang2,6
School of Science, Wuhan University of Technology, Wuhan 430070, China
School of Optical and Electronic Information, Wuhan National Laboratory for Optoelectronics (WNLO), Huazhong University of Science and Technology (HUST), Wuhan 430074, China
Department of Chemistry, Brock University, St. Catharines, ON L2S 3A1, Canada
Wenzhou Advanced Manufacturing Technology Research Institute, Huazhong University of Science and Technology, Wenzhou 325035, China
Shenzhen Huazhong University of Science and Technology Research Institute, Shenzhen 518057, China
Optics Valley Laboratory, Wuhan 430074, China

§ Sisi Liu and Ming-Yu Li contributed equally to this work.

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Graphical Abstract

An optical resonance cavity is constructed to boost the utilization of low-energy infrared (IR) photons (1,150–1,300 nm) for quantum dot (QD) solar cells. Benefiting from the enhanced light harvesting and efficient carrier extraction, highly efficient photoelectric conversion in the IR region (> 1,100 nm,1.3%) of PbS QD IR solar cells is obtained, which is comparable to the highest value of QD IR solar cells.

Abstract

Infrared (IR) solar cells are promising devices for improving the power conversion efficiency (PCE) of conventional solar cells by expanding the utilization region of the sunlight spectrum to near-infrared range. IR solar cells based on colloidal quantum dots (QDs) have attracted extensive attention due to the widely tunable absorption spectrum controlled by dot size and the unique solution processibility. However, the trade-off in QD solar cells between light absorption and photo-generated carrier collection has limited the further improvement of PCE. Here, we present high-performance PbS QD IR solar cells resulting from the combination of boosted light absorption and optimized carrier extraction. By constructing an optical resonance cavity, the light absorption is significantly enhanced in the range of 1,150–1,300 nm at a relatively thin photoactive layer. Meanwhile, the thin photoactive layer facilitates efficient carrier extraction. Consequently, the PbS QD IR solar cells exhibit a highly efficient photoelectric conversion in the IR region, resulting in a high IR PCE of 1.3% which is comparable to the highest value of solution-processed IR solar cells based on PbSe QDs. These results demonstrate that constructing an optical resonance cavity is a reasonable strategy for effective conversion of photons in the devices aiming at light in a relatively narrow wavelength range, such as IR solar cells and narrow band photodetectors.

Keywords

infrared solar cellsPbS quantum dotsoptical resonancecarrier extraction

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References

[1]

Shi, G. Z.; Wang, H. B.; Zhang, Y. H.; Cheng, C.; Zhai, T. S.; Chen, B. T.; Liu, X. Y.; Jono, R.; Mao, X. N.; Liu, Y. et al. The effect of water on colloidal quantum dot solar cells. Nat. Commun. 2021, 12, 4381.
Crossref Google Scholar
[2]

Sun, B.; Johnston, A.; Xu, C.; Wei, M. Y.; Huang, Z. R.; Jiang, Z.; Zhou, H.; Gao, Y. J.; Dong, Y. T.; Ouellette, O. et al. Monolayer perovskite bridges enable strong quantum dot coupling for efficient solar cells. Joule 2020, 4, 1542–1556.
Crossref Google Scholar
[3]

Jia, D. L.; Chen, J. X.; Zheng, S. Y.; Phuyal, D.; Yu, M.; Tian, L.; Liu, J. H.; Karis, O.; Rensmo, H.; Johansson, E. M. J. et al. Highly stabilized quantum dot ink for efficient infrared light absorbing solar cells. Adv. Energy Mater. 2019, 9, 1902809.
Crossref Google Scholar
[4]

Sytnyk, M.; Yakunin, S.; Schöfberger, W.; Lechner, R. T.; Burian, M.; Ludescher, L.; Killilea, N. A.; Yousefiamin, A.; Kriegner, D.; Stangl, J. et al. Quasi-epitaxial metal-halide perovskite ligand shells on PbS nanocrystals. ACS Nano 2017, 11, 1246–1256.
Crossref Google Scholar
[5]

McDonald, S. A.; Konstantatos, G.; Zhang, S. G.; Cyr, P. W.; Klem, E. J. D.; Levina, L.; Sargent, E. H. Solution-processed PbS quantum dot infrared photodetectors and photovoltaics. Nat. Mater. 2005, 4, 138–142.
Crossref Google Scholar
[6]

Yang, Z. Y.; Voznyy, O.; Liu, M. X.; Yuan, M. J.; Ip, A. H.; Ahmed, O. S.; Levina, L.; Kinge, S.; Hoogland, S.; Sargent, E. H. All-quantum-dot infrared light-emitting diodes. ACS Nano 2015, 9, 12327–12333.
Crossref Google Scholar
[7]

Tang, H. D.; Zhong, J. L.; Chen, W.; Shi, K. M.; Mei, G. D.; Zhang, Y. N.; Wen, Z. L.; Müller-Buschbaum, P.; Wu, D.; Wang, K. et al. Lead sulfide quantum dot photodetector with enhanced responsivity through a two-step ligand-exchange method. ACS Appl. Nano Mater. 2019, 2, 6135–6143.
Crossref Google Scholar
[8]

Choi, H.; Ko, J. H.; Kim, Y. H.; Jeong, S. Steric-hindrance-driven shape transition in PbS quantum dots: Understanding size-dependent stability. J. Am. Chem. Soc. 2013, 135, 5278–5281.
Crossref Google Scholar
[9]

Yuan, M. J.; Liu, M. X.; Sargent, E. H. Colloidal quantum dot solids for solution-processed solar cells. Nat. Energy 2016, 1, 16016.
Crossref Google Scholar
[10]

Chen, J. X.; Zheng, S. Y.; Jia, D. L.; Liu, W. L.; Andruszkiewicz, A.; Qin, C. C.; Yu, M.; Liu, J. H.; Johansson, E. M. J.; Zhang, X. L. Regulating thiol ligands of p-type colloidal quantum dots for efficient infrared solar cells. ACS Energy Lett. 2021, 6, 1970–1979.
Crossref Google Scholar
[11]

Xia, Y.; Chen, W.; Zhang, P.; Liu, S. S.; Wang, K.; Yang, X. K.; Tang, H. D.; Lian, L. Y.; He, J. G.; Liu, X. X. et al. Facet control for trap-state suppression in colloidal quantum dot solids. Adv. Funct. Mater. 2020, 30, 2000594.
Crossref Google Scholar
[12]

Choi, M. J.; García de Arquer, F. P.; Proppe, A. H.; Seifitokaldani, A.; Choi, J.; Kim, J.; Baek, S. W.; Liu, M. X.; Sun, B.; Biondi, M. et al. Cascade surface modification of colloidal quantum dot inks enables efficient bulk homojunction photovoltaics. Nat. Commun. 2020, 11, 103.
Crossref Google Scholar
[13]

Kim, H. I.; Baek, S. W.; Cheon, H. J.; Ryu, S. U.; Lee, S.; Choi, M. J.; Choi, K.; Biondi, M.; Hoogland, S.; García de Arquer, F. P. et al. A tuned alternating D-A copolymer hole-transport layer enables colloidal quantum dot solar cells with superior fill factor and efficiency. Adv. Mater. 2020, 32, e2004985.
Crossref Google Scholar
[14]

Chuang, C. H. M.; Brown, P. R.; Bulovic, V.; Bawendi, M. G. Improved performance and stability in quantum dot solar cells through band alignment engineering. Nat. Mater. 2014, 13, 796–801.
Crossref Google Scholar
[15]

Liu, M. X.; Voznyy, O.; Sabatini, R.; García de Arquer, F. P.; Munir, R.; Balawi, A. H.; Lan, X. Z.; Fan, F. J.; Walters, G.; Kirmani, A. R. et al. Hybrid organic-inorganic inks flatten the energy landscape in colloidal quantum dot solids. Nat. Mater. 2017, 16, 258–263.
Crossref Google Scholar
[16]

Xu, J. X.; Voznyy, O.; Liu, M. X.; Kirmani, A. R.; Walters, G.; Munir, R.; Abdelsamie, M.; Proppe, A. H.; Sarkar, A.; García de Arquer, F. P. et al. 2D matrix engineering for homogeneous quantum dot coupling in photovoltaic solids. Nat. Nanotechnol. 2018, 13, 456–462.
Crossref Google Scholar
[17]

Fan, J. Z.; Andersen, N. T.; Biondi, M.; Todorović, P.; Sun, B.; Ouellette, O.; Abed, J.; Sagar, L. K.; Choi, M. J.; Hoogland, S. et al. Mixed lead halide passivation of quantum dots. Adv. Mater. 2019, 31, 1904304.
Crossref Google Scholar
[18]

Fan, J. Z.; Vafaie, M.; Bertens, K.; Sytnyk, M.; Pina, J. M.; Sagar, L. K.; Ouellette, O.; Proppe, A. H.; Rasouli, A. S.; Gao, Y. J. et al. Micron thick colloidal quantum dot solids. Nano Lett. 2020, 20, 5284–5291.
Crossref Google Scholar
[19]

Bi, Y.; Bertran, A.; Gupta, S.; Ramiro, I.; Pradhan, S.; Christodoulou, S.; Majji, S. N.; Akgul, M. Z.; Konstantatos, G. Solution processed infrared- and thermo-photovoltaics based on 0.7 eV bandgap PbS colloidal quantum dots. Nanoscale 2019, 11, 838–843.
Crossref Google Scholar
[20]

Jia, D. L.; Chen, J. X.; Qiu, J. M.; Ma, H. L.; Yu, M.; Liu, J. H.; Zhang, X. L. Tailoring solvent-mediated ligand exchange for CsPbI3 perovskite quantum dot solar cells with efficiency exceeding 16.5%. Joule 2022, 6, 1632–1653.
Crossref Google Scholar
[21]

Liu, M. X.; Che, F. L.; Sun, B.; Voznyy, O.; Proppe, A.; Munir, R.; Wei, M. Y.; Quintero-Bermudez, R.; Hu, L. L.; Hoogland, S. et al. Controlled steric hindrance enables efficient ligand exchange for stable, infrared-bandgap quantum dot inks. ACS Energy Lett. 2019, 4, 1225–1230.
Crossref Google Scholar
[22]

Leem, J. W.; Yu, J. S.; Kim, J. N.; Noh, S. K. Theoretical modeling and optimization of III–V GaInP/GaAs/Ge monolithic triple-junction solar cells. J. Korean Phys. Soc. 2014, 64, 1561–1565.
Crossref Google Scholar
[23]

Tang, X.; Ackerman, M. M.; Shen, G. H.; Guyot-Sionnest, P. Towards infrared electronic eyes: Flexible colloidal quantum dot photovoltaic detectors enhanced by resonant cavity. Small 2019, 15, 1804920.
Crossref Google Scholar
[24]

Lei, W.; Antoszewski, J.; Faraone, L. Progress, challenges, and opportunities for HgCdTe infrared materials and detectors. Appl. Phys. Rev. 2015, 2, 041303.
Crossref Google Scholar
[25]

Ip, A. H.; Kiani, A.; Kramer, I. J.; Voznyy, O.; Movahed, H. F.; Levina, L.; Adachi, M. M.; Hoogland, S.; Sargent, E. H. Infrared colloidal quantum dot photovoltaics via coupling enhancement and agglomeration suppression. ACS Nano 2015, 9, 8833–8842.
Crossref Google Scholar
[26]

Fan, J. Z.; Liu, M. X.; Voznyy, O.; Sun, B.; Levina, L.; Quintero-Bermudez, R.; Liu, M.; Ouellette, O.; García de Arquer, F. P.; Hoogland, S. et al. Halide re-shelled quantum dot inks for infrared photovoltaics. ACS Appl. Mater. Interfaces 2017, 9, 37536–37541.
Crossref Google Scholar
[27]

Liu, S. S.; Xiong, K.; Wang, K.; Liang, G. J.; Li, M. Y.; Tang, H. D.; Yang, X. K.; Huang, Z.; Lian, L. Y.; Tan, M. L. et al. Efficiently passivated PbSe quantum dot solids for infrared photovoltaics. ACS Nano 2021, 15, 3376–3386.
Crossref Google Scholar
[28]

Xia, Y.; Liu, S. S.; Wang, K.; Yang, X. K.; Lian, L. Y.; Zhang, Z. M.; He, J. G.; Liang, G. J.; Wang, S.; Tan, M. L. et al. Cation-exchange synthesis of highly monodisperse PbS quantum dots from ZnS nanorods for efficient infrared solar cells. Adv. Funct. Mater. 2020, 30, 1907379.
Crossref Google Scholar
[29]

Kim, Y.; Che, F. L.; Jo, J. W.; Choi, J.; García de Arquer, F. P.; Voznyy, O.; Sun, B.; Kim, J.; Choi, M. J.; Quintero-Bermudez, R. et al. A Facet-specific quantum dot passivation strategy for colloid management and efficient infrared photovoltaics. Adv. Mater. 2019, 31, 1805580.
Crossref Google Scholar
[30]

Zherebetskyy, D.; Scheele, M.; Zhang, Y. J.; Bronstein, N.; Thompson, C.; Britt, D.; Salmeron, M.; Alivisatos, P.; Wang, L. W. Hydroxylation of the surface of PbS nanocrystals passivated with oleic acid. Science 2014, 344, 1380–1384.
Crossref Google Scholar
[31]

Jo, J. W.; Choi, J.; García de Arquer, F. P.; Seifitokaldani, A.; Sun, B.; Kim, Y.; Ahn, H.; Fan, J.; Quintero-Bermudez, R.; Kim, J. et al. Acid-assisted ligand exchange enhances coupling in colloidal quantum dot solids. Nano Lett. 2018, 18, 4417–4423.
Crossref Google Scholar
[32]

Pattantyus-Abraham, A. G.; Kramer, I. J.; Barkhouse, A. R.; Wang, X. H.; Konstantatos, G.; Debnath, R.; Levina, L.; Raabe, I.; Nazeeruddin, M. K.; Grätzel, M. et al. Depleted-heterojunction colloidal quantum dot solar cells. ACS Nano 2010, 4, 3374–3380.
Crossref Google Scholar
[33]

Carey, G. H.; Levina, L.; Comin, R.; Voznyy, O.; Sargent, E. H. Record charge carrier diffusion length in colloidal quantum dot solids via mutual dot-to-dot surface passivation. Adv. Mater. 2015, 27, 3325–3330.
Crossref Google Scholar
[34]

Lan, X. Z.; Voznyy, O.; García de Arquer, F. P.; Liu, M. X.; Xu, J. X.; Proppe, A. H.; Walters, G.; Fan, F. J.; Tan, H. R.; Liu, M. et al. 10.6% certified colloidal quantum dot solar cells via solvent-polarity-engineered halide passivation. Nano Lett. 2016, 16, 4630–4634.
Crossref Google Scholar
[35]

Sun, B.; Ouellette, O.; García de Arquer, F. P.; Voznyy, O.; Kim, Y.; Wei, M. Y.; Proppe, A. H.; Saidaminov, M. I.; Xu, J. X.; Liu, M. X. et al. Multibandgap quantum dot ensembles for solar-matched infrared energy harvesting. Nat. Commun. 2018, 9, 4003.
Crossref Google Scholar
[36]

Georgitzikis, E.; Malinowski, P. E.; Maes, J.; Hadipour, A.; Hens, Z.; Heremans, P.; Cheyns, D. Optimization of charge carrier extraction in colloidal quantum dots short-wave infrared photodiodes through optical engineering. Adv. Funct. Mater. 2018, 28, 1804502.
Crossref Google Scholar
[37]

Liu, S. S.; Zhang, C. J.; Li, S. Y.; Xia, Y.; Wang, K.; Xiong, K.; Tang, H. D.; Lian, L. Y.; Liu, X. X.; Li, M. Y. et al. Efficient infrared solar cells employing quantum dot solids with strong inter-dot coupling and efficient passivation. Adv. Funct. Mater. 2021, 31, 2006864.
Crossref Google Scholar
[38]

Lian, L. Y.; Xia, Y.; Zhang, C. W.; Xu, B.; Yang, L.; Liu, H.; Zhang, D. L.; Wang, K.; Gao, J. B.; Zhang, J. B. In situ tuning the reactivity of selenium precursor to synthesize wide range size, ultralarge-scale, and ultrastable PbSe quantum dots. Chem. Mater. 2018, 30, 982–989.
Crossref Google Scholar
[39]

Huang, Z.; Zhai, G. M.; Zhang, Z. M.; Zhang, C. W.; Xia, Y.; Lian, L. Y.; Fu, X. M.; Zhang, D. L.; Zhang, J. B. Low cost and large scale synthesis of PbS quantum dots with hybrid surface passivation. CrystEngComm 2017, 19, 946–951.
Crossref Google Scholar
[40]

Willis, S. M.; Cheng, C.; Assender, H. E.; Watt, A. A. R. The transitional heterojunction behavior of PbS/ZnO colloidal quantum dot solar cells. Nano Lett. 2012, 12, 1522–1526.
Crossref Google Scholar
[41]

Yang, X. K.; Hu, L.; Deng, H.; Qiao, K. K.; Hu, C.; Liu, Z. Y.; Yuan, S. J.; Khan, J.; Li, D. B.; Tang, J. et al. Improving the performance of PbS quantum dot solar cells by optimizing ZnO window layer. Nano-Micro Lett. 2017, 9, 24.
Crossref Google Scholar
[42]

Grinolds, D. D. W.; Brown, P. R.; Harris, D. K.; Bulovic, V.; Bawendi, M. G. Quantum-dot size and thin-film dielectric constant: Precision measurement and disparity with simple models. Nano Lett. 2015, 15, 21–26.
Crossref Google Scholar
[43]

Jia, D. L.; Chen, J. X.; Mei, X. Y.; Fan, W. T.; Luo, S.; Yu, M.; Liu, J. H.; Zhang, X. L. Surface matrix curing of inorganic CsPbI3 perovskite quantum dots for solar cells with efficiency over 16%. Energy Environ. Sci. 2021, 14, 4599–4609.
Crossref Google Scholar
[44]

Chen, J. X.; Jia, D. L.; Qiu, J. M.; Zhuang, R. S.; Hua, Y.; Zhang, X. L. Multidentate passivation crosslinking perovskite quantum dots for efficient solar cells. Nano Energy 2022, 96, 107140.
Crossref Google Scholar
[45]

Kim, J. K.; Song, J. H.; Choi, H.; Baik, S. J.; Jeong, S. Space charge limited conduction in ultrathin PbS quantum dot solid diodes. J. Appl. Phys. 2014, 115, 054302.
Crossref Google Scholar
Nano Research
Volume 16 Issue 2,
February 2023
Pages 2392-2398
DOI: 10.1007/s12274-022-4906-1
Cite this article:
Liu S, Li M-Y, Xiong K, et al. Efficient quantum dot infrared solar cells with enhanced low-energy photon conversion via optical engineering. Nano Research, 2023, 16(2): 2392-2398. https://doi.org/10.1007/s12274-022-4906-1
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Received: 27 July 2022
Revised: 12 August 2022
Accepted: 14 August 2022
Published: 07 October 2022
© Tsinghua University Press 2022
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