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Research Article

Interface regulation of Cu2Se via Cu–Se–C bonding for superior lithium-ion batteries

Kefu Zhu1,§, Shiqiang Wei1,§, Quan Zhou1,§, Shuangming Chen1( ), Yunxiang Lin2, Pengjun Zhang1, Yuyang Cao1, Changda Wang1, Yixiu Wang1, Yujian Xia1, Dengfeng Cao1, Zeinab Mohamed1, Xin Guo1, Xiya Yang1, Xiaojun Wu3, Li Song1( )
National Synchrotron Radiation Laboratory, Chinese Academy of Sciences (CAS) Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Institutes of Physical Science and Information Technology, Anhui University, Hefei 230601, China
School of Chemistry and Material Sciences, University of Science and Technology of China, Hefei 230026, China

§ Kefu Zhu, Shiqiang Wei, and Quan Zhou contributed equally to this work.

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Graphical Abstract

We devised the Cu-Se-C bonding regulated copper(I) selenide not only significantly promotes the interface stability and electronic conductivity, which makes it have superior capacity and long cycle life.

Abstract

Transition metal selenides have aroused great attention in recent years due to their high theoretical capacity. However, the huge volume fluctuation generated by conversion reaction during the charge/discharge process results in the significant electrochemical performance reduction. Herein, the carbon-regulated copper(I) selenide (Cu2Se@C) is designed to significantly promote the interface stability and ion diffusion for selenide electrodes. The systematic X-ray spectroscopies characterizations and density functional theory (DFT) simulations reveal that the Cu–Se–C bonding forming on the surface of Cu2Se not only improves the electronic conductivity of Cu2Se@C but also retards the volume change during electrochemical cycling, playing a pivotal role in interface regulation. Consequently, the storage kinetics of Cu2Se@C is mainly controlled by the capacitance process diverting from the ion diffusion-controlled process of Cu2Se. When employed this distinctive Cu2Se@C as anode active material in Li coin cell configuration, the ultrahigh specific capacity of 810.3 mA·h·g−1 at 0.1 A·g−1 and the capacity retention of 83% after 1,500 cycles at 5 A·g−1 is achieved, implying the best Cu-based Li+-storage capacity reported so far. This strategy of heterojunction combined with chemical bonding regulation opens up a potential way for the development of advanced electrodes for battery storage systems.

Keywords

Cu–Se–C bondinginterface regulationlithium-ion batteryX-ray absorption spectroscopy (XAS)operando synchrotron radiation X-ray diffraction (SRXRD)

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Nano Research
Volume 16 Issue 2,
February 2023
Pages 2421-2427
DOI: 10.1007/s12274-022-4953-7
Cite this article:
Zhu K, Wei S, Zhou Q, et al. Interface regulation of Cu2Se via Cu–Se–C bonding for superior lithium-ion batteries. Nano Research, 2023, 16(2): 2421-2427. https://doi.org/10.1007/s12274-022-4953-7
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Received: 20 June 2022
Revised: 04 August 2022
Accepted: 24 August 2022
Published: 30 September 2022
© Tsinghua University Press 2022
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