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Communication

Luminescent nanoparticle-arrays synthesized via polymer pen lithography

Ping Wang1,§, Shuyi Bao1,§, Shuqian Qiao2, Ce Li1, Zhang Jiang1, Hao Song1, Yilin Wang1, Qiuqiang Zhan2( ), Ling Huang1,3( )
Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University, Nanjing 211816, China
Centre for Optical and Electromagnetic Research, Guangdong Provincial Key Laboratory of Optical Information Materials and Technology, National Centre for International Research on Green Optoelectronics, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou 510006, China
College of Chemistry, State Key Laboratory of the Chemistry and Utilization of Carbon Based Energies, Xinjiang University, Urumqi 830046, China

§ Ping Wang and Shuyi Bao contributed equally to this work.

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Graphical Abstract

Large area (1 cm2) and 100% repeatable in-situ synthesis of luminescent upconversion nanoparticle (UCNP) arrays is achieved through poly-pen lithography based on a facile and efficient ink preparation method.

Abstract

We report a high-throughput approach to generating lanthanide-doped upconversion nanoparticle (UCNP) arrays through polymer pen lithography (PPL), where instead of the expensive block co-polymer, two types of polymers are employed with one working as ink carrier, e.g., polyethylene glycol-400 (PEG-400) to facilitate smooth transfer from the tip to the substrate and the other, e.g., polyvinyl pyrrolidone (PVP), as chelator to ensure successful patterning of metal ions. The strong coordination of PVP with rare earth ions (RE3+) is the key for weakening the interaction between RE3+ ions and the carrier PEG-400 so that the good mobility of ink can be retained. Further experimental results have shown that besides PVP, small molecules with functional groups that can coordinate with RE3+ ions, such as oleic acid, can also serve the same role as PVP, which greatly enriches the ink library for PPL. Over 1 cm2 area arrays comprising individual UCNP can be reliably generated with characteristic upconversion luminescence. This strategy not only allows reliable production of individual UCNP arrays, it also paves new avenue to the precise synthesis of multifunctional NPs for lasing, imaging, encryption, and anticounterfeiting.

Keywords

polymer pen lithographyupconversion luminescencenanoparticlearrayligand

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References

[1]

Kar, A.; Patra, A. Impacts of core–shell structures on properties of lanthanide-based nanocrystals: Crystal phase, lattice strain, downconversion, upconversion and energy transfer. Nanoscale 2012, 4, 3608–3619.
Crossref Google Scholar
[2]

Haase, M.; Schäfer, H. Upconverting nanoparticles. Angew. Chem., Int. Ed. 2011, 50, 5808–5829.
Crossref Google Scholar
[3]

Gorris, H. H.; Wolfbeis, O. S. Photon-upconverting nanoparticles for optical encoding and multiplexing of cells, biomolecules, and microspheres. Angew. Chem., Int. Ed. 2013, 52, 3584–3600.
Crossref Google Scholar
[4]

Tian, G.; Gu, Z. J.; Zhou, L. J.; Yin, W. Y.; Liu, X. X.; Yan, L.; Jin, S.; Ren, W. L.; Xing, G. M.; Li, S. J. et al. Mn2+ dopant-controlled synthesis of NaYF4:Yb/Er upconversion nanoparticles for in vivo imaging and drug delivery. Adv. Mater. 2012, 24, 1226–1231.
Crossref Google Scholar
[5]

Auzel, F. Upconversion and anti-stokes processes with f and d ions in solids. Chem. Rev. 2004, 104, 139–174.
Crossref Google Scholar
[6]

Downing, E.; Hesselink, L.; Ralston, J.; Macfarlane, R. A three-color, solid-state, three-dimensional display. Science 1996, 273, 1185–1189.
Crossref Google Scholar
[7]

Xie, H. B.; Zhang, J. N.; Wang, F.; Shen, D. Y.; Wang, J.; Tang, D. Y. High-power 1,640 nm Er:Y2O3 ceramic laser at room temperature. Opt. Lett. 2022, 47, 246–248.
Crossref Google Scholar
[8]

Sun, L. D.; Dong, H.; Zhang, P. Z.; Yan, C. H. Upconversion of rare earth nanomaterials. Annu. Rev. Phys. Chem. 2015, 66, 619–642.
Crossref Google Scholar
[9]

Zhang, H. X.; Chen, Z. H.; Liu, X.; Zhang, F. A mini-review on recent progress of new sensitizers for luminescence of lanthanide doped nanomaterials. Nano Res. 2020, 13, 1795–1809.
Crossref Google Scholar
[10]

Kostyuk, A. B.; Vorotnov, A. D.; Ivanov, A. V.; Volovetskiy, A. B.; Kruglov, A. V.; Sencha, L. M.; Liang, L. E.; Guryev, E. L.; Vodeneev, V. A.; Deyev, S. M. et al. Resolution and contrast enhancement of laser-scanning multiphoton microscopy using thulium-doped upconversion nanoparticles. Nano Res. 2019, 12, 2933–2940.
Crossref Google Scholar
[11]

Mor, F. M.; Sienkiewicz, A.; Forró, L.; Jeney, S. Upconversion particle as a local luminescent Brownian probe: A photonic force microscopy study. ACS Photonics 2014, 1, 1251–1257.
Crossref Google Scholar
[12]

Lu, Y. Q.; Zhao, J. B.; Zhang, R.; Liu, Y. J.; Liu, D. M.; Goldys, E. M.; Yang, X. S.; Xi, P.; Sunna, A.; Lu, J. et al. Tunable lifetime multiplexing using luminescent nanocrystals. Nat. Photonics 2014, 8, 32–36.
Crossref Google Scholar
[13]

You, W. W.; Tu, D. T.; Li, R. F.; Zheng, W.; Chen, X. Y. “Chameleon-like” optical behavior of lanthanide-doped fluoride nanoplates for multilevel anti-counterfeiting applications. Nano Res. 2019, 12, 1417–1422.
Crossref Google Scholar
[14]

Hartman, T.; Geitenbeek, R. G.; Whiting, G. T.; Weckhuysen, B. M. Operando monitoring of temperature and active species at the single catalyst particle level. Nat. Catal. 2019, 2, 986–996.
Crossref Google Scholar
[15]

Xie, S. T.; Du, Y. L.; Zhang, Y.; Wang, Z. M.; Zhang, D. L.; He, L.; Qiu, L. P.; Jiang, J. H.; Tan, W. H. Aptamer-based optical manipulation of protein subcellular localization in cells. Nat. Commun. 2020, 11, 1347.
Crossref Google Scholar
[16]

Ke, J. X.; Lu, S.; Li, Z.; Shang, X. Y.; Li, X. J.; Li, R. F.; Tu, D. T.; Chen, Z.; Chen, X. Y. Multiplexed intracellular detection based on dual-excitation/dual-emission upconversion nanoprobes. Nano Res. 2020, 13, 1955–1961.
Crossref Google Scholar
[17]

Chen, S.; Weitemier, A. Z.; Zeng, X.; He, L. M.; Wang, X. Y.; Tao, Y. Q.; Huang, A. J. Y.; Hashimotodani, Y.; Kano, M.; Iwasaki, H. et al. Near-infrared deep brain stimulation via upconversion nanoparticle-mediated optogenetics. Science 2018, 359, 679–684.
Crossref Google Scholar
[18]

Richards, B. S.; Hudry, D.; Busko, D.; Turshatov, A.; Howard, I. A. Photon upconversion for photovoltaics and photocatalysis: A critical review. Chem. Rev. 2021, 121, 9165–9195.
Crossref Google Scholar
[19]

Liu, X. Y.; Liu, W. D.; Yang, B. Deep-elliptical-silver-nanowell arrays (d-EAgNWAs) fabricated by stretchable imprinting combining colloidal lithography: A highly sensitive plasmonic sensing platform. Nano Res. 2019, 12, 845–853.
Crossref Google Scholar
[20]

Bhingardive, V.; Menahem, L.; Schvartzman, M. Soft thermal nanoimprint lithography using a nanocomposite mold. Nano Res. 2018, 11, 2705–2714.
Crossref Google Scholar
[21]

Williams, G.; Hunt, M.; Boehm, B.; May, A.; Taverne, M.; Ho, D.; Giblin, S.; Read, D.; Rarity, J.; Allenspach, R. et al. Two-photon lithography for 3D magnetic nanostructure fabrication. Nano Res. 2017, 11, 845–854.
Crossref Google Scholar
[22]

Piner, R. D.; Zhu, J.; Xu, F.; Hong, S.; Mirkin, C. A. “Dip-pen” nanolithography. Science 1999, 283, 661–663.
Crossref Google Scholar
[23]

Demers, L. M.; Ginger, D. S.; Park, S. J.; Li, Z.; Chung, S. W.; Mirkin, C. A. Direct patterning of modified oligonucleotides on metals and insulators by dip-pen nanolithography. Science 2002, 296, 1836–1838.
Crossref Google Scholar
[24]

Lim, J. H.; Ginger, D. S.; Lee, K. B.; Heo, J.; Nam, J. M.; Mirkin, C. A. Direct-write dip-pen nanolithography of proteins on modified silicon oxide surfaces. Angew. Chem., Int. Ed. 2003, 42, 2309–2312.
Crossref Google Scholar
[25]

Huang, L.; Braunschweig, A. B.; Shim, W.; Qin, L. D.; Lim, J. K.; Hurst, S. J.; Huo, F. W.; Xue, C.; Jang, J. W.; Mirkin, C. A. Matrix-assisted dip-pen nanolithography and polymer pen lithography. Small 2010, 6, 1077–1081.
Crossref Google Scholar
[26]

Du, J. S.; Chen, P. C.; Meckes, B.; Kluender, E. J.; Xie, Z.; Dravid, V. P.; Mirkin, C. A. Windowless observation of evaporation-induced coarsening of Au-Pt nanoparticles in polymer nanoreactors. J. Am. Chem. Soc. 2018, 140, 7213–7221.
Crossref Google Scholar
[27]

Qin, L. D.; Park, S.; Huang, L.; Mirkin, C. A. On-wire lithography. Science 2005, 309, 113–115.
Crossref Google Scholar
[28]

Sanedrin, R. G.; Huang, L.; Jang, J. W.; Kakkassery, J.; Mirkin, C. A. Polyethylene glycol as a novel resist and sacrificial material for generating positive and negative nanostructures. Small 2008, 4, 920–924.
Crossref Google Scholar
[29]

Chai, J. N.; Huo, F. W.; Zheng, Z. J.; Giam, L. R.; Shim, W.; Mirkin, C. A. Scanning probe block copolymer lithography. Proc. Natl. Acad. Sci. USA 2010, 107, 20202–20206.
Crossref Google Scholar
[30]

Chen, P. C.; Liu, X. L.; Hedrick, J. L.; Xie, Z.; Wang, S. Z.; Lin, Q. Y.; Hersam, M. C.; Dravid, V. P.; Mirkin, C. A. Polyelemental nanoparticle libraries. Science 2016, 352, 1565–1569.
Crossref Google Scholar
[31]

Ali, F. M.; Kershi, R. M. Synthesis and characterization of La3+ ions incorporated (PVA/PVP) polymer composite films for optoelectronics devices. J. Mater. Sci. Mater. Electron. 2020, 31, 2557–2566.
Crossref Google Scholar
[32]

Kumar, B.; Kaur, G.; Rai, S. B. Sensitized green emission of terbium with dibenzoylmethane and 1,10-phenanthroline in polyvinyl alcohol and polyvinyl pyrrolidone blends. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2017, 187, 75–81.
Crossref Google Scholar
[33]

Chai, J. N.; Liao, X.; Giam, L. R.; Mirkin, C. A. Nanoreactors for studying single nanoparticle coarsening. J. Am. Chem. Soc. 2012, 134, 158–161.
Crossref Google Scholar
[34]

Xing, M. M.; Cao, W. H.; Zhong, H. Y.; Zhang, Y. H.; Luo, X. X.; Fu, Y.; Feng, W.; Pang, T.; Yang, X. F. Synthesis and upconversion luminescence properties of monodisperse Y2O3: Yb, Ho spherical particles. J. Alloys Compd. 2011, 509, 5725–5730.
Crossref Google Scholar
[35]

Eichelsdoerfer, D. J.; Liao, X.; Cabezas, M. D.; Morris, W.; Radha, B.; Brown, K. A.; Giam, L. R.; Braunschweig, A. B.; Mirkin, C. A. Large-area molecular patterning with polymer pen lithography. Nat. Protoc. 2013, 8, 2548–2560.
Crossref Google Scholar
Nano Research
Volume 16 Issue 2,
February 2023
Pages 3125-3129
DOI: 10.1007/s12274-022-4968-0
Cite this article:
Wang P, Bao S, Qiao S, et al. Luminescent nanoparticle-arrays synthesized via polymer pen lithography. Nano Research, 2023, 16(2): 3125-3129. https://doi.org/10.1007/s12274-022-4968-0
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Received: 03 August 2022
Revised: 25 August 2022
Accepted: 25 August 2022
Published: 11 October 2022
© Tsinghua University Press 2022
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