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Research Article

In-situ synthesis of high thermal stability and salt resistance carbon dots for injection pressure reduction and enhanced oil recovery

Yining Wu1( )Lisha Tang1Dayu Liu1Demin Kong2Liu Kai2Mengjiao Cao1Qingshan Zhao2( )
School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China
State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China
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Graphical Abstract

Benzene sulfonate-modified carbon dots (BS-CDs) was synthesized by the in-situ modification electrochemical exfoliation with petroleum coke-asphalt as carbon sources. BS-CDs nanofluid possesses excellent dispersibility, high temperature and salt resistance, and is capable to reduce injection pressure and enhance oil recovery concomitantly.

Abstract

Carbon dots (CDs) show great potential as a new type of oil-displacing agent for unconventional oil and gas development. However, the instability and easy aggregation epitomize the challenges that accompany the application of CDs in high temperature and high salinity (HT/HS) reservoirs. In this research, novel benzene sulfonate-modified carbon dots (BS-CDs) with remarkable thermal stability and salt resistance were fabricated through an in-situ electrochemical exfoliation method. Molecular simulation verifies that the introduction of benzene sulfonate groups substantially strengthens the electrostatic repulsion between BS-CDs, leading to outstanding dispersibility and stability even at a temperature of 100 °C and salinity of 14 × 104 mg/L. Core flooding tests show that 0.05 wt.% BS-CDs nanofluid can significantly reduce the water injection pressure by 50.00% and enhanced oil recovery (EOR) to 68.39% under HT/HS conditions. According to the atomic force microscopy (AFM) scanning results, the adhesion force between the core (after BS-CDs treatment) and oil decreased by 11.94 times, indicating that the hydrophilicity of the core surface was increased. In addition, the distribution of the adhesion force curve is more concentrated, which means that the micro-scale wettability of the core changes from oil-wet to more homogeneous water-wet. This study provides a feasible way for the development and application of good thermal stability and salt resistance CDs in unconventional reservoir development.

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References

[1]
Idogun, A. K.; Iyagba, E. T.; Ukwotije-Ikwut, R. P.; Aseminaso, A. A review study of oil displacement mechanisms and challenges of nanoparticle enhanced oil recovery. In Society of Petroleum Engineers Nigeria Annual International Conference and Exhibition, Lagos, Nigeria, 2016, pp 184352.
[2]

Qing, F.; Yan, J. P.; Wang, J.; Hu, Q. H.; Wang, M.; Geng, B.; Chao, J. Pore structure and fluid saturation of near-oil source low-permeability turbidite sandstone of the Dongying Sag in the Bohai Bay Basin, east China. J. Petrol. Sci. Eng. 2021, 196, 108106.

[3]

Wang, L.; Tian, Y.; Yu, X. Y.; Wang, C.; Yao, B. W.; Wang, S. H.; Winterfeld, P. H.; Wang, X.; Yang, Z. Z.; Wang, Y. H. et al. Advances in improved/enhanced oil recovery technologies for tight and shale reservoirs. Fuel 2017, 210, 425–445.

[4]

Yuan, W. W. Study on percolation mechanism of low permeability reservoir. IOP Conf. Ser. Earth Environ. Sci. 2021, 770, 012045.

[5]

Akbar, I.; Zhou, H. T.; Liu, W.; Qureshi, A. S.; Memon, A.; Muther, T.; Ansari, U.; UsmanTahir, M.; Bakhsh, A.; Shaikh, A. et al. Nano-suspension combined effect with polymer gels for enhanced oil recovery in low permeability reservoir. Arab. J. Geosci. 2021, 14, 1473.

[6]

Wang, F. J.; Liu, Y. K.; Wang, Y. P.; Hu, C. Y. Study on the theory of effective displacement in low permeability reservoir. Adv. Mater. Res. 2013, 868, 551–555.

[7]

Yue, L.; Pu, W. F.; Zhao, S.; Zhang, S.; Ren, F.; Xu, D. S. Insights into mechanism of low salinity water flooding in sandstone reservoir from interfacial features of oil/brine/rock via intermolecular forces. J. Mol. Liquids 2020, 313, 113435.

[8]

Arab, D.; Bryant, S. L.; Torsæter, O.; Kantzas, A. Water flooding of sandstone oil reservoirs: Underlying mechanisms in imbibition vs. drainage displacement. J. Petrol. Sci. Eng. 2022, 213, 110379.

[9]

Guo, W. J.; Fu, S. S.; Li, A. F.; Xie, H. J.; Cui, S. T.; Nangendo, J. Experimental research on the mechanisms of improving water flooding in fractured-vuggy reservoirs. J. Petrol. Sci. Eng. 2022, 213, 110383.

[10]

Mahmoudzadeh, A.; Fatemi, M.; Masihi, M. Microfluidics experimental investigation of the mechanisms of enhanced oil recovery by low salinity water flooding in fractured porous media. Fuel 2022, 314, 123067.

[11]

Sun, L. D.; Wu, X. L.; Zhou, W. F.; Li, X. J.; Han, P. H. Technologies of enhancing oil recovery by chemical flooding in Daqing Oilfield, NE China. Petrol Explor. Dev. 2018, 45, 673–684.

[12]

Liu, W. D.; Wang, G. F.; Liao, G. Z.; Wang, H. Z.; Wang, Z. M.; Wang, Q.; Wang, Z. B. Production calculation of the second and tertiary recovery combination reservoirs under chemical flooding. Petrol. Explor. Dev. 2021, 48, 1403–1410.

[13]

Wei, L. X.; Zhang, L.; Chao, M.; Jia, X. L.; Liu, C.; Shi, L. J. Synthesis and study of a new type of nonanionic demulsifier for chemical flooding emulsion demulsification. ACS Omega 2021, 6, 17709–17719.

[14]

Tavakkoli, O.; Kamyab, H.; Shariati, M.; Mohamed, A. M.; Junin R. Effect of nanoparticles on the performance of polymer/surfactant flooding for enhanced oil recovery: A review. Fuel 2022, 312, 122867.

[15]

Li, Y. Y.; Dai, C. L.; Zhou, H. D.; Wang, X. K.; Lv, W. J.; Wu, Y. N.; Zhao, M. W. A novel nanofluid based on fluorescent carbon nanoparticles for enhanced oil recovery. Ind. Eng. Chem. Res. 2017, 56, 12464–12470.

[16]

Shen, M.; Resasco, D. E. Emulsions stabilized by carbon nanotube-silica nanohybrids. Langmuir 2009, 25, 10843–10851.

[17]

Luo, D.; Wang, F.; Zhu, J. Y.; Tang, L.; Zhu, Z.; Bao, J. M.; Willson, R. C.; Yang, Z. Z.; Ren, Z. F. Secondary oil recovery using graphene-based amphiphilic janus nanosheet fluid at an ultralow concentration. Ind. Eng. Chem. Res. 2017, 56, 11125–11132.

[18]

Hendraningrat, L.; Li, S. D.; Torsæter, O. A core flood investigation of nanofluid enhanced oil recovery. J. Petrol. Sci. Eng. 2013, 111, 128–138.

[19]

Zhu, H.; Xia, J. H.; Sun, Z. G.; Zhang, J.; Zhang, Y. M.; Wang, F. H. Application of nanometer-silicon dioxide in tertiary oil recovery. Acta Petrol. Sin. 2006, 27, 96–99.

[20]

Feng, X. Y.; Hou, J. R.; Cheng, T. T.; Zhai, H. Y. Preparation and oil displacement properties of oleic acid-modified nano-TiO2. Oilfield Chem. 2019, 36, 280–285.

[21]

Lai, N. J.; Tang, L.; Jia, N.; Qiao, D. Y.; Chen, J. L.; Wang, Y.; Zhao, X. B. Feasibility study of applying modified nano-SiO2 hyperbranched copolymers for enhanced oil recovery in low-mid permeability reservoirs. Polymers (Basel) 2019, 11, 1483–1483.

[22]

Eltoum, H.; Yang, Y. L.; Hou, J. R. The effect of nanoparticles on reservoir wettability alteration: A critical review. Petrol. Sci. 2021, 18, 136–153.

[23]

Manshad, A. K.; Rezaei, M.; Moradi, S.; Nowrouzi, I.; Mohammadi, A. H. Wettability alteration and interfacial tension (IFT) reduction in enhanced oil recovery (EOR) process by ionic liquid flooding. J. Mol. Liquids 2017, 248, 153–162.

[24]

Binks, B. P.; Lumsdon, S. O. Pickering emulsions stabilized by monodisperse latex particles: Effects of particle size. Langmuir 2001, 17, 4540–4547.

[25]

Hong, W. H.; Yu, L. Experiment research on flooding by nano-solution in Jiangsu oil field. Petrochem. Ind. Appl. 2011, 30, 8–12.

[26]

Liu, M. L.; Chen, B. B.; Li, C. M.; Huang, C. Z. Carbon dots: Synthesis, formation mechanism, fluorescence origin and sensing applications. Green Chem. 2019, 21, 449–471.

[27]

Hu, C.; Li, M. Y.; Qiu, J. S.; Sun, Y. P. Design and fabrication of carbon dots for energy conversion and storage. Chem. Soc. Rev. 2019, 48, 2315–2337.

[28]

Lim, S. Y.; Shen, W.; Gao, Z. Q. Carbon quantum dots and their applications. Chem. Soc. Rev. 2015, 44, 362–381.

[29]

Soleimani, H.; Baig, M. K.; Yahya, N.; Khodapanah, L.; Sabet, M.; Demiral, B. M. R.; Burda, M. Impact of carbon nanotubes based nanofluid on oil recovery efficiency using core flooding. Results Phys. 2018, 9, 39–48.

[30]

Sikiru, S.; Rostami, A.; Soleimani, H.; Yahya, N.; Afeez, Y.; Aliu, O.; Yusuf, J. Y.; Oladosu, T. L. Graphene: Outlook in the enhance oil recovery (EOR). J. Mol. Liq. 2021, 321, 114519.

[31]

Wu, Y. N.; Li, Y.; Cao, M. J.; Dai, C. L.; He, L.; Yang, Y. P. Preparation and stabilization mechanism of carbon dots nanofluids for drag reduction. Petrol. Sci. 2020, 17, 1717–1725.

[32]

Baragau, I. A.; Lu, Z.; Power, N. P.; Morgan, D. J.; Bowen, J.; Diaz, P.; Kellici, S. Continuous hydrothermal flow synthesis of S-functionalised carbon quantum dots for enhanced oil recovery. Chem. Eng. J. 2021, 405, 126631.

[33]

Wu, Y. N.; Cao, M. J.; Zhao, Q. S.; Wu, X. C.; Guo, F.; Tang, L. S.; Tian, X. J.; Wu, W. T.; Shi, Y. F.; Dai, C. L. Novel high-hydrophilic carbon dots from petroleum coke for boosting injection pressure reduction and enhancing oil recovery. Carbon 2021, 184, 186–194.

[34]

Lu, J.; Yang, J. X.; Wang, J. Z.; Lim, A.; Wang, S.; Loh, K. P. One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids. ACS Nano 2009, 3, 2367–2375.

[35]

Travlou, N. A.; Secor, J.; Bandosz, T. J. Corrigendum to “highly luminescent S-doped carbon dots for the selective detection of ammonia” [Carbon 114 (2017) 544–556]. Carbon 2017, 116, 275–277.

[36]

Xu, Q.; Li, B. F.; Ye, Y. C.; Cai, W.; Li, W. J.; Yang, C. S.; Chen, Y.; Xu, M.; Li, N.; Zheng, X. S. et al. Synthesis, mechanical investigation, and application of nitrogen and phosphorus co-doped carbon dots with a high photoluminescent quantum yield. Nano Res. 2018, 11, 3691–3701.

[37]

Sun, X. Y.; Ge, J. J. Synergism between lipophilic surfactant and lipophilic SiO2 nanoparticles enhances self-emulsification performance. J Petrol. Sci Eng. 2022, 216, 110760.

[38]

Zhao, M. W.; Song, X. G.; Zhou, D.; Lv, W. J.; Dai, C. L.; Yang, Q. R.; Li, Y.; Zhang, B. H.; Zhao, Y. R.; Wu, Y. N. Study on the reducing injection pressure regulation of hydrophobic carbon nanoparticles. Langmuir 2020, 36, 3989–3996.

[39]

Wei, B.; Li, Q. Z.; Jin, F. Y.; Li, H.; Wang, C. Y. The potential of a novel nanofluid in enhancing oil recovery. Energy Fuels 2016, 30, 2882–2891.

Nano Research
Pages 12058-12065
Cite this article:
Wu Y, Tang L, Liu D, et al. In-situ synthesis of high thermal stability and salt resistance carbon dots for injection pressure reduction and enhanced oil recovery. Nano Research, 2023, 16(10): 12058-12065. https://doi.org/10.1007/s12274-022-5083-y
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Received: 04 August 2022
Revised: 06 September 2022
Accepted: 20 September 2022
Published: 05 December 2022
© Tsinghua University Press 2022
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