AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Integrating molybdenum sulfide selenide-based cathode with C–O–Mo heterointerface design and atomic engineering for superior aqueous Zn-ion batteries

Hong Li1,2,3,4, Biao Chen3,5, Runhua Gao3, Fugui Xu6, Xinzhu Wen7( ), Xiongwei Zhong3, Chuang Li3, Zhihong Piao3, Nantao Hu4( ), Xiao Xiao3, Feng Shao4, Guangmin Zhou3( ), Jinlong Yang1( )
Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China
College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China
Tsinghua-Berkeley Shenzhen Institute & Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China
Key Laboratory for Thin Film and Microfabrication Technology of the Ministry of Education, School of Electronics, Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
School of Materials Science and Engineering and Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300350, China
School of Chemistry and Chemical Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, Shanghai 200240, China
School of Engineering and Technology College, Yang-en University, Quanzhou 362014, China
Show Author Information

Graphical Abstract

MoSSe alloys vertically anchored on graphene were fabricated via partial substitution of S atoms for Se atoms to in-situ generate abundant anion vacancies as cathodes for aqueous zinc-ion battery (AZIB). Heterointerface design and atomic engineering of molybdenum sulfide selenide-based cathode realize kinetics-enhanced and high-capacity of aqueous zinc-ion batteries.

Abstract

Transition metal dichalcogenides (TMDs) have been regarded as promising cathodes for aqueous zinc-ion batteries (AZIBs) but suffer from sluggish reaction kinetics due to their poor conductivity and the strong electrostatic interaction between Zn-ion and cathode materials. Herein, a well-defined structure with MoSSe nanosheets vertically anchored on graphene is used as the cathode for AZIBs. The dissolution of Se into MoS2 lattice together with heterointerface design via developing C–O–Mo bonds improves the inherent conductivity, enlarges interlayer spacing, and generates abundant anionic vacancies. As a result, the Zn2+ intercalation/deintercalation process is greatly improved, which is confirmed by theoretical modeling and ex-situ experimental results. Remarkably, the assembled AZIBs exhibit high-rate capability (124.2 mAh·g−1 at 5 A·g−1) and long cycling life (83% capacity retention after 1,200 cycles at 2 A·g−1). Moreover, the assembled quasi-solid-state Zn-ion batteries demonstrate a stable cycling performance over 100 cycles and high capacity retention over 94% after 2,500 bending cycles. This study provides a new strategy to unlock the electrochemical activity of TMDs via interface design and atomic engineering, which can also be applied to other TMDs for multivalent batteries.

Keywords

Zn2+ kineticsheterointerface designatomic engineeringanion vacancy

Electronic Supplementary Material

Download File(s)
12274_2022_5108_MOESM1_ESM.pdf (1.2 MB)

References

[1]

Wu, F. X.; Maier, J.; Yu, Y. Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries. Chem. Soc. Rev. 2020, 49, 1569–1614.
Crossref Google Scholar
[2]

Zhang, X.; Yang, Y. A.; Zhou, Z. Towards practical lithium-metal anodes. Chem. Soc. Rev. 2020, 49, 3040–3071.
Crossref Google Scholar
[3]

Fan, E. S.; Li, L.; Wang, Z. P.; Lin, J.; Huang, Y. X.; Yao, Y.; Chen, R. J.; Wu, F. Sustainable recycling technology for Li-ion batteries and beyond: Challenges and future prospects. Chem. Rev. 2020, 120, 7020–7063.
Crossref Google Scholar
[4]

Cabana, J.; Monconduit, L.; Larcher, D.; Palacín, M. R. Beyond intercalation-based Li-ion batteries: The state of the art and challenges of electrode materials reacting through conversion reactions. Adv. Mater. 2010, 22, E170–E192.
Crossref Google Scholar
[5]

Deng, D. Li-ion batteries: Basics, progress, and challenges. Energy Sci. Eng. 2015, 3, 385–418.
Crossref Google Scholar
[6]

Kubota, K.; Dahbi, M.; Hosaka, T.; Kumakura, S.; Komaba, S. Towards K-ion and Na-ion batteries as “beyond Li-ion”. Chem. Rec. 2018, 18, 459–479.
Crossref Google Scholar
[7]

Yang, D.; Zhou, Y. P.; Geng, H. B.; Liu, C. T.; Lu, B.; Rui, X. H.; Yan, Q. Y. Pathways towards high energy aqueous rechargeable batteries. Coord. Chem. Rev. 2020, 424, 213521.
Crossref Google Scholar
[8]

Jia, X. X.; Liu, C. F.; Neale, Z. G.; Yang, J. H.; Cao, G. Z. Active materials for aqueous zinc ion batteries: Synthesis, crystal structure, morphology, and electrochemistry. Chem. Rev. 2020, 120, 7795–7866.
Crossref Google Scholar
[9]

Lee, W. S. V.; Xiong, T.; Wang, X. P.; Xue, J. M. Unraveling MoS2 and transition metal dichalcogenides as functional zinc-ion battery cathode: A perspective. Small Methods 2021, 5, 2000815.
Crossref Google Scholar
[10]

Li, M.; Lu, J.; Ji, X. L.; Li, Y. G.; Shao, Y. Y.; Chen, Z. W.; Zhong, C.; Amine, K. Design strategies for nonaqueous multivalent-ion and monovalent-ion battery anodes. Nat. Rev. Mater. 2020, 5, 276–294.
Crossref Google Scholar
[11]

Li, W.; Wang, K. L.; Cheng, S. J.; Jiang, K. An ultrastable presodiated titanium disulfide anode for aqueous “rocking-chair” zinc ion battery. Adv. Energy Mater. 2019, 9, 1900993.
Crossref Google Scholar
[12]

Hao, J. N.; Yuan, L. B.; Johannessen, B.; Zhu, Y. L.; Jiao, Y.; Ye, C.; Xie F. X.; Qiao, S. Z. Studying the conversion mechanism to broaden cathode options in aqueous zinc-ion batteries. Angew. Chem., Int. Ed. 2021, 133, 25318–25325.
Crossref Google Scholar
[13]

Xu, W. W.; Sun, C. L.; Zhao, K. N.; Cheng, X.; Rawal, S.; Xu, Y.; Wang, Y. Defect engineering activating (boosting) zinc storage capacity of MoS2. Energy Storage Mater. 2019, 16, 527–534.
Crossref Google Scholar
[14]

Xiao, P.; Li, H. B.; Fu, J. Z.; Zeng, C.; Zhao, Y. H.; Zhai, T. Y.; Li, H. Q. An anticorrosive zinc metal anode with ultra-long cycle life over one year. Energy Environ. Sci. 2022, 15, 1638–1646.
Crossref Google Scholar
[15]

Chen, B.; Chao, D. L.; Liu, E. Z.; Jaroniec, M.; Zhao, N. Q.; Qiao, S. Z. Transition metal dichalcogenides for alkali metal ion batteries: Engineering strategies at the atomic level. Energy Environ. Sci. 2020, 13, 1096–1131.
Crossref Google Scholar
[16]

Wang, L. L.; Wu, Z. X.; Jiang, M. J. H.; Lu, J. Y.; Huang, Q. H.; Zhang, Y.; Fu, L. J.; Wu, M.; Wu, Y. P. Layered VSe2: A promising host for fast zinc storage and its working mechanism. J. Mater. Chem. A 2020, 8, 9313–9321.
Crossref Google Scholar
[17]

Pu, X. M.; Song, T. B.; Tang, L. B.; Tao, Y. Y.; Cao, T.; Xu, Q. J.; Liu, H. M.; Wang, Y. G.; Xia, Y. Y. Rose-like vanadium disulfide coated by hydrophilic hydroxyvanadium oxide with improved electrochemical performance as cathode material for aqueous zinc-ion batteries. J. Power Sources 2019, 437, 226917.
Crossref Google Scholar
[18]

He, P.; Yan, M. Y.; Zhang, G. B.; Sun, R. M.; Chen, L. N.; An, Q. Y.; Mai, L. Layered VS2 nanosheet-based aqueous Zn ion battery cathode. Adv. Energy Mater. 2017, 7, 1601920.
Crossref Google Scholar
[19]

Chen, B.; Wang, D. S.; Tan, J. Y.; Liu, Y. Q.; Jiao, M. L.; Liu, B. L.; Zhao, N. Q.; Zou, X. L.; Zhou, G. M.; Cheng, H. M. Designing electrophilic and nucleophilic dual centers in the ReS2 plane toward efficient bifunctional catalysts for Li-CO2 batteries. J. Am. Chem. Soc. 2022, 144, 3106–3116.
Crossref Google Scholar
[20]

Chen, B.; Zhong, X. W.; Zhou, G. M.; Zhao, N. Q.; Cheng, H. M. Graphene-supported atomically dispersed metals as bifunctional catalysts for next-generation batteries based on conversion reactions. Adv. Mater. 2022, 34, 2105812.
Crossref Google Scholar
[21]

Liang, H. F.; Cao, Z.; Ming, F. W.; Zhang, W. L.; Anjum, D. H.; Cui, Y.; Cavallo, L.; Alshareef, H. N. Aqueous zinc-ion storage in MoS2 by tuning the intercalation energy. Nano Lett. 2019, 19, 3199–3206.
Crossref Google Scholar
[22]

Jin, Y. Q.; Chen, H. Z.; Peng, L. H.; Chen, Z. H.; Cheng, L.; Song, J. D.; Zhang, H.; Chen, J.; Xie, F. Y.; Jin, Y. S. et al. Interfacial polarization triggered by glutamate accelerates dehydration of hydrated zinc ions for zinc-ion batteries. Chem. Eng. J. 2021, 416, 127704.
Crossref Google Scholar
[23]

Li, S. W.; Liu, Y. C.; Zhao, X. D.; Cui, K. X.; Shen, Q. Y.; Li, P.; Qu, X. H.; Jiao, L. F. Molecular engineering on MoS2 enables large interlayers and unlocked basal planes for high-performance aqueous Zn-ion storage. Angew. Chem., Int. Ed. 2021, 60, 20286–20293.
Crossref Google Scholar
[24]

Liu, H. Y.; Wang, J. G.; Hua, W.; You, Z. Y.; Hou, Z. D.; Yang, J. C.; Wei, C. G.; Kang, F. Y. Boosting zinc-ion intercalation in hydrated MoS2 nanosheets toward substantially improved performance. Energy Storage Mater. 2021, 35, 731–738.
Crossref Google Scholar
[25]

Liu, J. P.; Xu, P. T.; Liang, J. M.; Liu, H. B.; Peng, W. C.; Li, Y.; Zhang, F. B.; Fan, X. B. Boosting aqueous zinc-ion storage in MoS2 via controllable phase. Chem. Eng. J. 2020, 389, 124405.
Crossref Google Scholar
[26]

Liu, W. B.; Hao, J. W.; Xu, C. J.; Mou, J.; Dong, L. B.; Jiang, F. Y.; Kang, Z.; Wu, J. L.; Jiang, B. Z.; Kang, F. Y. Investigation of zinc ion storage of transition metal oxides, sulfides, and borides in zinc ion battery systems. Chem. Commun. 2017, 53, 6872–6874.
Crossref Google Scholar
[27]

Li, P.; Jeong, J. Y.; Jin, B. J.; Zhang, K.; Park, J. H. Vertically oriented MoS2 with spatially controlled geometry on nitrogenous graphene sheets for high-performance sodium-ion batteries. Adv. Energy Mater. 2018, 8, 1703300.
Crossref Google Scholar
[28]

Wang, T.; Shen, X. T.; Huang, J. F.; Xi, Q.; Zhao, Y. X.; Guo, Q.; Wang, X.; Xu, Z. W. Tulip-like MoS2 with a single sheet tapered structure anchored on N-doped graphene substrates via C–O–Mo bonds for superior sodium storage. J. Mater. Chem. A 2018, 6, 24433–24440.
Crossref Google Scholar
[29]

Chen, H.; Song, T. B.; Tang, L. B.; Pu, X. M.; Li, Z.; Xu, Q. J.; Liu, H. M.; Wang, Y. G.; Xia, Y. Y. In-situ growth of vertically aligned MoS2 nanowalls on reduced graphene oxide enables a large capacity and highly stable anode for sodium ion storage. J. Power Sources 2022, 445, 227271.
Crossref Google Scholar
[30]

He, H. N.; Huang, D.; Gan, Q. M.; Hao, J. N.; Liu, S. L.; Wu, Z. B.; Pang, W. K.; Johannessen, B.; Tang, Y. G.; Luo, J. L. et al. Anion vacancies regulating endows MoSSe with fast and stable potassium ion storage. ACS Nano 2019, 13, 11843–11852.
Crossref Google Scholar
[31]

Huang, Y. X.; Wang, Z. H.; Guan, M. R.; Wu, F.; Chen, R. J. Toward rapid-charging sodium-ion batteries using hybrid-phase molybdenum sulfide selenide-based anodes. Adv. Mater. 2020, 32, 2003534.
Crossref Google Scholar
[32]

Tian, Z. H.; Chui, N.; Lian, R. Q.; Yang, Q. F.; Wang, W.; Yang, C.; Rao, D. W.; Huang, J. J.; Zhang, Y. W.; Lai, F. L. et al. Dual anionic vacancies on carbon nanofiber threaded MoSSe arrays: A free-standing anode for high-performance potassium-ion storage. Energy Storage Mater. 2020, 27, 591–598.
Crossref Google Scholar
[33]

Jiao, T. P.; Yang, Q.; Wu, S. L.; Wang, Z. F.; Chen, D.; Shen, D.; Liu, B.; Cheng, J. Y.; Li, H. F.; Ma, L. T. et al. Binder-free hierarchical VS2 electrodes for high-performance aqueous Zn ion batteries towards commercial level mass loading. J. Mater. Chem. A 2019, 7, 16330–16338.
Crossref Google Scholar
[34]

Wang, L. W.; Gao, F.; Wang, A. Z.; Chen, X. Y.; Li, H.; Zhang, X.; Zheng, H.; Ji, R.; Li, B.; Yu, X. et al. Defect-rich adhesive molybdenum disulfide/rGO vertical heterostructures with enhanced nanozyme activity for smart bacterial killing application. Adv. Mater. 2020, 32, 2005423.
Crossref Google Scholar
[35]

Li, H. F.; Yang, Q.; Mo, F. N.; Liang, G. J.; Liu, Z. X.; Tang, Z. J.; Ma, L. T.; Liu, J.; Shi, Z. C.; Zhi, C. Y. MoS2 nanosheets with expanded interlayer spacing for rechargeable aqueous Zn-ion batteries. Energy Storage Mater. 2019, 19, 94–101.
Crossref Google Scholar
Nano Research
Volume 16 Issue 4,
April 2023
Pages 4933-4940
DOI: 10.1007/s12274-022-5108-6
Cite this article:
Li H, Chen B, Gao R, et al. Integrating molybdenum sulfide selenide-based cathode with C–O–Mo heterointerface design and atomic engineering for superior aqueous Zn-ion batteries. Nano Research, 2023, 16(4): 4933-4940. https://doi.org/10.1007/s12274-022-5108-6
Topics:
Energy

3663

Views

13

Crossref

12

Web of Science

13

Scopus

0

CSCD

Altmetrics
Received: 11 August 2022
Revised: 14 September 2022
Accepted: 26 September 2022
Published: 25 November 2022
© Tsinghua University Press 2022
Return