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Research Article

Synthesis, crystal structure, and magnetic properties of a new one-dimensional chain antiferromagnet Co(ox)(bib)·H2O (ox = oxalate; bib = 1,4-bis(imidazole-1-yl)benzene)

Yan She1,§, Yanhong Wang1,§, Shuang Li1, Tao Wang2, Hongcheng Lu1( )
School of Chemistry and Chemical Engineering, Key Laboratory of Material Chemistry for Energy Conversion and Storage, Hubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, Huazhong University of Science and Technology, Wuhan 430074, China
Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, China

§ Yan She and Yanhong Wang contributed equally to this work.

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Graphical Abstract

A new oxalate-bridged compound Co(ox)(bib)·H2O (bib = 1,4-bis(imidazole-1-yl)benzene) with linear CoII–ox–CoII spin chains has been successfully synthesized by hydrothermal method. Due to the negligible interchain interactions through bib ligand and weak hydrogen bonds, the magnetic susceptibility and heat capacity results indicate that Co(ox)(bib)·H2O exhibits a good one-dimensional (1D) magnetism.

Abstract

A new one-dimensional (1D) chain antiferromagnet Co(ox)(bib)·H2O 1 (ox = oxalate; bib = 1,4-bis(imidazole-1-yl)benzene) has been successfully synthesized under hydrothermal condition and characterized by single crystal X-ray crystallography, powder X-ray diffraction, thermogravimetric analysis, Fourier transform infrared (FTIR) spectroscopy, magnetic susceptibility, and heat capacity measurements. The CoII ion is connected by oxalate ions in trans-configuration to form 1D CoII–ox–CoII spin chains, which are further separated by the long organic molecule bib. The magnetic susceptibility curve shows that 1 exhibits a feature of broad maximum around 29 K, indicating strong antiferromagnetic interactions with short spin–spin correlations along the spin chains. However, no long-range order is observed due to the negligible interchain interactions through bib ligand and weak hydrogen bonds, which is further confirmed by the heat capacity data. The intrachain interaction J of −8.4 K is estimated. Both magnetic susceptibility and heat capacity results indicate that 1 exhibits a good 1D magnetism.

Keywords

1,4-bis(imidazole-1-yl)benzeneantiferromagneticcobaltchain structureoxalate

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Nano Research
Volume 16 Issue 2,
February 2023
Pages 3552-3557
DOI: 10.1007/s12274-022-5206-5
Cite this article:
She Y, Wang Y, Li S, et al. Synthesis, crystal structure, and magnetic properties of a new one-dimensional chain antiferromagnet Co(ox)(bib)·H2O (ox = oxalate; bib = 1,4-bis(imidazole-1-yl)benzene). Nano Research, 2023, 16(2): 3552-3557. https://doi.org/10.1007/s12274-022-5206-5
Topics:
Cobalt compoundsStructural design

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Received: 27 September 2022
Revised: 13 October 2022
Accepted: 15 October 2022
Published: 29 November 2022
© Tsinghua University Press 2022
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