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Research Article

Epitaxial interface stabilizing iridium dioxide toward the oxygen evolution reaction under high working potentials

Guoqiang Zhao1, Zhouxin Luo1, Baohua Zhang1, Yaping Chen1, Xiangzhi Cui2,3, Jian Chen4, Yongfeng Liu1, Mingxia Gao1, Hongge Pan1,4, Wenping Sun1,5( )
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310058, China
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, China
Institute of Science and Technology for New Energy, Xi'an Technological University, Xi'an 710021, China
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China
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Graphical Abstract

Epitaxial boron nitride (BN)–iridium dioxide (IrO2) interface was established by anchoring IrO2 nanoparticles (NPs) on exfoliated h-BN nanosheets toward substantially enhanced oxygen evolution reaction (OER) activity and stability. The epitaxial interface stabilizes the highly active Ir(V) species, and hence improves the electrocatalytic stability of IrO2 NPs, in particular in high working potential regions.

Abstract

Proton exchange membrane water electrolyzer (PEMWE) driven by renewable electricity is a promising technique toward green hydrogen production, but the corrosive environment and high working potential pose severe challenges for developing advanced electrocatalysts for the oxygen evolution reaction (OER). Although Ir-based materials possess relatively balanced activity and stability for the OER, their dissolution behavior cannot be neglected, in particular under high working potentials. In this work, iridium dioxide (IrO2) nanoparticles (NPs) were anchored on the surface of exfoliated h-boron nitride (BN) nanosheets (NSs) toward the OER reaction in acid media. Highly active Ir(V) species were stabilized by the epitaxial interface between IrO2 and h-BN, and therefore the IrO2/BN delivered stable performance at increased working potentials, while the activity of bare IrO2 NPs without h-BN support decreased rapidly. Also, the smaller lattice spacing of h-BN induced compressive strain for IrO2, resulting in improved activity. Our results demonstrate the feasibility of stabilizing highly active Ir(V) species for the OER in acid media by constructing robust interface and provide new possibilities toward designing advanced heterostructured electrocatalysts.

Keywords

iridium oxideoxygen evolution reactionepitaxial interfaceelectrochemical stability

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Nano Research
Volume 16 Issue 4,
April 2023
Pages 4767-4774
DOI: 10.1007/s12274-022-5240-3
Cite this article:
Zhao G, Luo Z, Zhang B, et al. Epitaxial interface stabilizing iridium dioxide toward the oxygen evolution reaction under high working potentials. Nano Research, 2023, 16(4): 4767-4774. https://doi.org/10.1007/s12274-022-5240-3
Topics:
Material compositionElectrocatalysis

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Received: 04 October 2022
Revised: 20 October 2022
Accepted: 22 October 2022
Published: 11 January 2023
© Tsinghua University Press 2022
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