AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

A double-layer covered architecture with spinel phase induced by LiPP for Co-free Li-rich cathode with high-rate performance and long lifespan

Ruiqi Zhao1,3, Manman Wu1,2,3, Peixin Jiao3,4,5, Xueting Wang1,3, Jie Zhu1,3, Yang Zhao1,3, Hongtao Zhang1,3( ), Kai Zhang3,4,5, Chenxi Li1,3, Yanfeng Ma1,3, Yongsheng Chen1,2,3( )
The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Renewable Energy Conversion and Storage Center (RECAST), Nankai University, Tianjin 300071, China
Department Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China
Engineering Research Center of High-efficiency Energy Storage (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China
Show Author Information

Graphical Abstract

An in-situ simple and low-cost strategy with a nanoscale double-layer covered architecture is developed for Li1.2Mn0.6Ni0.2O2 (LMNO@S-LiPP). This half-cell delivers an extremely high capacity of 202.5 mAh·g−1 at 5 C and retains 85.3% after 300 cycles.

Abstract

Co-free Li-rich Mn-based layered oxides are promising candidates for next-generation lithium-ion batteries (LIBs) due to their high specific capacity, high voltage, and low cost. However, their commercialization is hindered by limited cycle life and poor rate performance. Herein, an in-situ simple and low-cost strategy with a nanoscale double-layer architecture of lithium polyphosphate (LiPP) and spinel phase covered on top of the bulk layered phase, is developed for Li1.2Mn0.6Ni0.2O2 (LMNO) using Li+-conductor LiPP (denoted as LMNO@S-LiPP). With such a double-layer covered architecture, the half-cell of LMNO@S-LiPP delivers an extremely high capacity of 202.5 mAh·g−1 at 1 A·g−1 and retains 85.3% of the initial capacity after 300 cycles, so far, the best high-rate electrochemical performance of all the previously reported LMNOs. The energy density of the full-cell assembled with commercial graphite reaches 620.9 Wh·kg−1 (based on total weight of active materials in cathode and anode). Mechanism studies indicate that the superior electrochemical performance of LMNO@S-LiPP is originated from such a nanoscale double-layer covered architecture, which accelerates Li-ion diffusion, restrains oxygen release, inhibits interfacial side reactions, and suppresses structural degradation during cycling. Moreover, this strategy is applicable for other high-energy-density cathodes, such as LiNi0.8Co0.1Mn0.1O2, Li1.2Ni0.13Co0.13Mn0.54O2, and LiCoO2. Hence, this work presents a simple, cost-effective, and scalable strategy for the development of high-performance cathode materials.

Keywords

Co-free Li-rich layered oxidesdouble-layer covered architecturelithium polyphosphatehigh-rate performancelong cycle life

Electronic Supplementary Material

Download File(s)
12274_2022_5333_MOESM1_ESM.pdf (1.9 MB)

References

[1]

Li, M.; Lu, J.; Chen, Z. W.; Amine, K. 30 years of lithium-ion batteries. Adv. Mater. 2018, 30, 1800561.
Crossref Google Scholar
[2]

Murdock, B. E.; Toghill, K. E.; Tapia-Ruiz, N. A perspective on the sustainability of cathode materials used in lithium-ion batteries. Adv. Energy Mater. 2021, 11, 2102028.
Crossref Google Scholar
[3]

Huang, A. M.; Ma, Y. C.; Peng, J.; Li, L. L.; Chou, S. L.; Ramakrishna, S.; Peng, S. J. Tailoring the structure of silicon-based materials for lithium-ion batteries via electrospinning technology. eScience 2021, 1, 141–162.
Crossref Google Scholar
[4]

Wu, M. M.; Zhao, Y.; Zhang, H. T.; Zhu, J.; Ma, Y. F.; Li, C. X.; Zhang, Y. M.; Chen, Y. S. A 2D covalent organic framework with ultra-large interlayer distance as high-rate anode material for lithium-ion batteries. Nano Res. 2022, 15, 9779–9784.
Crossref Google Scholar
[5]

Wang, J.; He, X.; Paillard, E.; Laszczynski, N.; Li, J.; Passerini, S. Lithium- and manganese-rich oxide cathode materials for high-energy lithium ion batteries. Adv. Energy Mater. 2016, 6, 1600906.
Crossref Google Scholar
[6]

Zheng, J. M.; Myeong, S.; Cho, W.; Yan, P. F.; Xiao, J.; Wang, C. M.; Cho, J.; Zhang, J. G. Li- and Mn-rich cathode materials: Challenges to commercialization. Adv. Energy Mater. 2017, 7, 1601284.
Crossref Google Scholar
[7]

He, W.; Guo, W. B.; Wu, H. L.; Lin, L.; Liu, Q.; Han, X.; Xie, Q. S.; Liu, P. F.; Zheng, H. F.; Wang, L. S. et al. Challenges and recent advances in high capacity Li-rich cathode materials for high energy density lithium-ion batteries. Adv. Mater. 2021, 33, 2005937.
Crossref Google Scholar
[8]

Assat, G.; Tarascon, J. M. Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries. Nat. Energy 2018, 3, 373–386.
Crossref Google Scholar
[9]

Zuo, W. H.; Luo, M. Z.; Liu, X. S.; Wu, J.; Liu, H. D.; Li, J.; Winter, M.; Fu, R. Q.; Yang, W. L.; Yang, Y. Li-rich cathodes for rechargeable Li-based batteries: Reaction mechanisms and advanced characterization techniques. Energy Environ. Sci. 2020, 13, 4450–4497.
Crossref Google Scholar
[10]

Zhang, H. L.; Liu, H.; Piper, L. F. J.; Whittingham, M. S.; Zhou, G. W. Oxygen loss in layered oxide cathodes for Li-ion batteries: Mechanisms, effects, and mitigation. Chem. Rev. 2022, 122, 5641–5681.
Crossref Google Scholar
[11]

Eum, D.; Kim, B.; Kim, S. J.; Park, H.; Wu, J. P.; Cho, S. P.; Yoon, G.; Lee, M. H.; Jung, S. K.; Yang, W. L. et al. Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes. Nat. Mater. 2020, 19, 419–427.
Crossref Google Scholar
[12]

Zheng, J. M.; Shi, W.; Gu, M.; Xiao, J.; Zuo, P. J.; Wang, C. M.; Zhang, J. G. Electrochemical kinetics and performance of layered composite cathode material Li[Li0.2Ni0.2Mn0.6]O2. J. Electrochem. Soc. 2013, 160, A2212.
Crossref Google Scholar
[13]

Yu, X. Q.; Lyu, Y.; Gu, L.; Wu, H. M.; Bak, S. M.; Zhou, Y. N.; Amine, K.; Ehrlich, S. N.; Li, H.; Nam, K. W. et al. Understanding the rate capability of high-energy-density Li-rich layered Li1.2Ni0.15Co0.1Mn0.55O2 cathode materials. Adv. Energy Mater. 2014, 4, 1300950.
Crossref Google Scholar
[14]

Zhao, H.; Lam, W. Y. A.; Sheng, L.; Wang, L.; Bai, P.; Yang, Y.; Ren, D. S.; Xu, H.; He, X. M. Cobalt-free cathode materials: Families and their prospects. Adv. Energy Mater. 2022, 12, 2103894.
Crossref Google Scholar
[15]

Zhang, X. F.; Belharouak, I.; Li, L.; Lei, Y.; Elam, J. W.; Nie, A. M.; Chen, X. Q.; Yassar, R. S.; Axelbaum, R. L. Structural and electrochemical study of Al2O3 and TiO2 coated Li1.2Ni0.13Mn0.54Co0.13O2 cathode material using ALD. Adv. Energy Mater. 2013, 3, 1299–1307.
Crossref Google Scholar
[16]

Liu, H. D.; Qian, D. N.; Verde, M. G.; Zhang, M. H.; Baggetto, L.; An, K.; Chen, Y.; Carroll, K. J.; Lau, D.; Chi, M. F. et al. Understanding the role of NH4F and Al2O3 surface co-modification on lithium-excess layered oxide Li1.2Ni0.2Mn0.6O2. ACS Appl. Mater. Interfaces 2015, 7, 19189–19200.
Crossref Google Scholar
[17]

Zhang, C. X.; Feng, Y. Z.; Wei, B.; Liang, C. P.; Zhou, L. J.; Ivey, D. G.; Wang, P.; Wei, W. F. Heteroepitaxial oxygen-buffering interface enables a highly stable cobalt-free Li-rich layered oxide cathode. Nano Energy 2020, 75, 104995.
Crossref Google Scholar
[18]

Zheng, J. M.; Gu, M.; Xiao, J.; Polzin, B. J.; Yan, P. F.; Chen, X. L.; Wang, C. M.; Zhang, J. G. Functioning mechanism of AlF3 coating on the Li- and Mn-rich cathode materials. Chem. Mater. 2014, 26, 6320–6327.
Crossref Google Scholar
[19]

Zhu, W.; Tai, Z. G.; Shu, C. Y.; Chong, S. K.; Guo, S. W.; Ji, L. J.; Chen, Y. Z.; Liu, Y. N. The superior electrochemical performance of a Li-rich layered cathode material with Li-rich spinel Li4Mn5O12 and MgF2 double surface modifications. J. Mater. Chem. A 2020, 8, 7991–8001.
Crossref Google Scholar
[20]

Zhao, H.; Li, W. T.; Li, J. X.; Xu, H. Y.; Zhang, C.; Li, J.; Han, C.; Li, Z. L.; Chu, M.; Qiu, X. P. Enhance performances of Co-free Li-rich cathode by eutesctic melting salt treatment. Nano Energy 2022, 92, 106760.
Crossref Google Scholar
[21]

Ma, Y. T.; Liu, P. F.; Xie, Q. S.; Zhang, G. B.; Zheng, H. F.; Cai, Y. X.; Li, Z.; Wang, L. S.; Zhu, Z. Z.; Mai, L. Q. et al. Double-shell Li-rich layered oxide hollow microspheres with sandwich-like carbon@spinel@layered@spinel@carbon shells as high-rate lithium ion battery cathode. Nano Energy 2019, 59, 184–196.
Crossref Google Scholar
[22]

Si, M. T.; Wang, D. D.; Zhao, R.; Pan, D.; Zhang, C.; Yu, C. Y.; Lu, X.; Zhao, H. L.; Bai, Y. Local electric-field-driven fast Li diffusion kinetics at the piezoelectric LiTaO3 modified Li-rich cathode-electrolyte interphase. Adv. Sci. 2020, 7, 1902538.
Crossref Google Scholar
[23]

Zhao, E. Y.; Liu, X. F.; Hu, Z. B.; Sun, L. M.; Xiao, X. L. Facile synthesis and enhanced electrochemical performances of Li2TiO3-coated lithium-rich layered Li1.13Ni0.30Mn0.57O2 cathode materials for lithium-ion batteries. J. Power Sources 2015, 294, 141–149.
Crossref Google Scholar
[24]

Lee, Y.; Lee, J.; Lee, K. Y.; Mun, J.; Lee, J. K.; Choi, W. Facile formation of a Li3PO4 coating layer during the synthesis of a lithium-rich layered oxide for high-capacity lithium-ion batteries. J. Power Sources 2016, 315, 284–293.
Crossref Google Scholar
[25]

Guo, W. B.; Zhang, C. Y.; Zhang, Y. G.; Lin, L.; He, W.; Xie, Q. S.; Sa, B.; Wang, L. S.; Peng, D. L. A universal strategy toward the precise regulation of initial coulombic efficiency of Li-rich Mn-based cathode materials. Adv. Mater. 2021, 33, 2103173.
Crossref Google Scholar
[26]

Zhu, X. H.; Meng, F. Q.; Zhang, Q. H.; Xue, L.; Zhu, H.; Lan, S.; Liu, Q.; Zhao, J.; Zhuang, Y. H.; Guo, Q. B. et al. LiMnO2 cathode stabilized by interfacial orbital ordering for sustainable lithium-ion batteries. Nat. Sustain. 2021, 4, 392–401.
Crossref Google Scholar
[27]

Liu, J. X.; Wang, J. Q.; Ni, Y. X.; Zhang, Y. D.; Luo, J.; Cheng, F. Y.; Chen, J. Spinel/lithium-rich manganese oxide hybrid nanofibers as cathode materials for rechargeable lithium-ion batteries. Small Methods 2019, 3, 1900350.
Crossref Google Scholar
[28]

Liu, P. F.; Zhang, H.; He, W.; Xiong, T. F.; Cheng, Y.; Xie, Q. S.; Ma, Y. T.; Zheng, H. F.; Wang, L. S.; Zhu, Z. Z. et al. Lithium deficiencies engineering in Li-rich layered oxide Li1.098Mn0.533Ni0.113Co0.138O2 for high-stability cathode. J. Am. Chem. Soc. 2019, 141, 10876–10882.
Crossref Google Scholar
[29]

Zhang, X. D.; Shi, J. L.; Liang, J. Y.; Yin, Y. X.; Zhang, J. N.; Yu, X. Q.; Guo, Y. G. Suppressing surface lattice oxygen release of Li-rich cathode materials via heterostructured spinel Li4Mn5O12 coating. Adv. Mater. 2018, 30, 1801751.
Crossref Google Scholar
[30]

Zhu, Y. F.; Xiao, Y.; Dou, S. X.; Kang, Y. M.; Chou, S. L. Spinel/post-spinel engineering on layered oxide cathodes for sodium-ion batteries. eScience 2021, 1, 13–27.
Crossref Google Scholar
[31]

Zhu, A. P.; Wu, J. H.; Wang, B. Y.; Zhou, J. W.; Zhang, Y.; Guo, Y.; Wu, K. P.; Wu, H.; Wang, Q.; Zhang, Y. Harmonious dual-riveting interface induced from niobium oxides coating toward superior stability of Li-rich Mn-based cathode. ACS Appl. Mater. Interfaces 2021, 13, 61248–61257.
Crossref Google Scholar
[32]

Li, Q. Y.; Zhou, D.; Zhang, L. J.; Ning, D.; Chen, Z. H.; Xu, Z. J.; Gao, R.; Liu, X. Z.; Xie, D. H.; Schumacher, G. et al. Tuning anionic redox activity and reversibility for a high-capacity Li-rich Mn-based oxide cathode via an integrated strategy. Adv. Funct. Mater. 2019, 29, 1806706.
Crossref Google Scholar
[33]

Xiao, Y. H.; Miara, L. J.; Wang, Y.; Ceder, G. Computational screening of cathode coatings for solid-state batteries. Joule 2019, 3, 1252–1275.
Crossref Google Scholar
[34]

Du, Y. H.; Sheng, H.; Meng, X. H.; Zhang, X. D.; Zou, Y. G.; Liang, J. Y.; Fan, M.; Wang, F. Y.; Tang, J. L.; Cao, F. F. et al. Chemically converting residual lithium to a composite coating layer to enhance the rate capability and stability of single-crystalline Ni-rich cathodes. Nano Energy 2022, 94, 106901.
Crossref Google Scholar
[35]

Xu, L. Q.; Sun, Z. H.; Zhu, Y.; Han, Y.; Wu, M. M.; Ma, Y. F.; Huang, Y.; Zhang, H. T.; Chen, Y. S. A Li-rich layered-spinel cathode material for high capacity and high rate lithium-ion batteries fabricated via a gas-solid reaction. Sci. China Mater. 2020, 63, 2435–2442.
Crossref Google Scholar
[36]

Sun, Z. H.; Xu, L. Q.; Dong, C. Q.; Zhang, H. T.; Zhang, M. T.; Ma, Y. F.; Liu, Y. Y.; Li, Z. J.; Zhou, Y.; Han, Y. et al. A facile gaseous sulfur treatment strategy for Li-rich and Ni-rich cathode materials with high cycling and rate performance. Nano Energy 2019, 63, 103887.
Crossref Google Scholar
[37]

Meng, J. X.; Xu, L. S.; Ma, Q. X.; Yang, M. Q.; Fang, Y. Z.; Wan, G. Y.; Li, R. H.; Yuan, J. J.; Zhang, X. K.; Yu, H. J. et al. Modulating crystal and interfacial properties by W-gradient doping for highly stable and long life Li-rich layered cathodes. Adv. Funct. Mater. 2022, 32, 2113013.
Crossref Google Scholar
[38]

Zheng, H. F.; Zhang, C. Y.; Zhang, Y. G.; Lin, L.; Liu, P. F.; Wang, L. S.; Wei, Q. L.; Lin, J.; Sa, B.; Xie, Q. S. et al. Manipulating the local electronic structure in Li-rich layered cathode towards superior electrochemical performance. Adv. Funct. Mater. 2021, 31, 2100783.
Crossref Google Scholar
[39]

Luo, D.; Ding, X. K.; Hao, X. D.; Xie, H. X.; Cui, J. X.; Liu, P. Z.; Yang, X. H.; Zhang, Z. H.; Guo, J. J.; Sun, S. H. et al. Ni/Mn and Al dual concentration-gradients to mitigate voltage decay and capacity fading of Li-rich layered cathodes. ACS Energy Lett. 2021, 6, 2755–2764.
Crossref Google Scholar
[40]

Cai, Y. X.; Ku, L.; Wang, L. S.; Ma, Y. T.; Zheng, H. F.; Xu, W. J.; Han, J. T.; Qu, B. H.; Chen, Y. Z.; Xie, Q. S. et al. Engineering oxygen vacancies in hierarchically Li-rich layered oxide porous microspheres for high-rate lithium ion battery cathode. Sci. China Mater. 2019, 62, 1374–1384.
Crossref Google Scholar
[41]

Lee, M. J.; Lho, E.; Oh, P.; Son, Y.; Cho, J. Simultaneous surface modification method for 0.4Li2MnO3-0.6LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries:Acid treatment and LiCoPO4 coating. Nano Res. 2017, 10, 4210–4220.
Crossref Google Scholar
[42]

Peng, J. M.; Li, Y.; Chen, Z. Q.; Liang, G. M.; Hu, S. J.; Zhou, T. F.; Zheng, F. H.; Pan, Q. C.; Wang, H. Q.; Li, Q. Y. et al. Phase compatible NiFe2O4 coating tunes oxygen redox in Li-rich layered oxide. ACS Nano 2021, 15, 11607–11618.
Crossref Google Scholar
[43]

Sun, J. M.; Sheng, C. C.; Cao, X.; Wang, P. F.; He, P.; Yang, H. J.; Chang, Z.; Yue, X. Y.; Zhou, H. S. Restraining oxygen release and suppressing structure distortion in single-crystal Li-rich layered cathode materials. Adv. Funct. Mater. 2022, 32, 2110295.
Crossref Google Scholar
[44]

Zhang, X. D.; Shi, J. L.; Liang, J. Y.; Yin, Y. X.; Guo, Y. G.; Wan, L. J. Structurally modulated Li-rich cathode materials through cooperative cation doping and anion hybridization. Sci. China Chem. 2017, 60, 1554–1560.
Crossref Google Scholar
[45]

Ruther, R. E.; Callender, A. F.; Zhou, H.; Martha, S. K.; Nanda, J. Raman microscopy of lithium-manganese-rich transition metal oxide cathodes. J. Electrochem. Soc. 2015, 162, A98.
Crossref Google Scholar
[46]

Lanz, P.; Villevieille, C.; Novák, P. Ex situ and in situ Raman microscopic investigation of the differences between stoichiometric LiMO2 and high-energy xLi2MnO3·(1 − x)LiMO2 (M = Ni, Co, Mn). Electrochim. Acta 2014, 130, 212.
Crossref Google Scholar
[47]

Huang, W. W.; Frech, R. In situ Raman spectroscopic studies of electrochemical intercalation in LixMn2O4-based cathodes. J. Power Sources 1999, 81–82, 616–620.
Crossref Google Scholar
[48]

Ding, X. K.; Luo, D.; Cui, J. X.; Xie, H. X.; Ren, Q. Q.; Lin, Z. An ultra-long-life lithium-rich Li1.2Mn0. 6Ni0. 2O2 cathode by three-in-one surface modification for lithium-ion batteries. Angew. Chem., Int. Ed. 2020, 59, 7778–7782.
Crossref Google Scholar
[49]

Johnson, C. S.; Li, N.; Lefief, C.; Vaughey, J. T.; M. Thackeray, M. Synthesis, characterization and electrochemistry of lithium battery electrodes: xLi2MnO3·(1 − x)LiMn0.333Ni0.333Co0.333O2 (0 ≤ x ≤ 0.7). Chem. Mater. 2008, 20, 6095–6106.
Crossref Google Scholar
[50]

Li, Q. Y.; Ning, D.; Zhou, D.; An, K.; Schuck, G.; Wong, D.; Kong, W. J.; Schulz, C.; Schumacher, G.; Liu, X. F. Tuning both anionic and cationic redox chemistry of Li-Rich Li1.2Mn0.6Ni0.2O2 via a “Three-in-One” Strategy. Chem. Mater. 2020, 32, 9404–9414.
Crossref Google Scholar
[51]

Chen, Q.; Pei, Y.; Chen, H. W.; Song, Y.; Zhen, L.; Xu, C. Y.; Xiao, P. H.; Henkelman, G. Highly reversible oxygen redox in layered compounds enabled by surface polyanions. Nat. Commun. 2020, 11, 3411.
Crossref Google Scholar
[52]

Vu, N. H.; Im, J. C.; Unithrattil, S.; Im, W. B. Synergic coating and doping effects of Ti-modified integrated layered-spinel Li1.2Mn0.75Ni0. 25O2+δ as a high capacity and long lifetime cathode material for Li-ion batteries. J. Mater. Chem. A 2018, 6, 2200–2211.
Crossref Google Scholar
[53]

Li, L.; Wang, L. C.; Zhang, X. X.; Xue, Q.; Wei, L.; Wu, F.; Chen, R. J. 3D reticular Li1.2Ni0.2Mn0.6O2 cathode material for lithium-ion batteries. ACS Appl. Mater. Interfaces 2017, 9, 1516–1523.
Crossref Google Scholar
[54]

Hua, W. B.; Wu, Z. G.; Chen, M. Z.; Knapp, M.; Guo, X. D.; Indris, S.; Binder, J. R.; Bramnik, N. N.; Zhong, B. H.; Guo, H. P. et al. Shape-controlled synthesis of hierarchically layered lithium transition-metal oxide cathode materials by shear exfoliation in continuous stirred-tank reactors. J. Mater. Chem. A 2017, 5, 25391–25400.
Crossref Google Scholar
[55]

Zhao, T. L.; Li, L.; Chen, R. J.; Wu, H. M.; Zhang, X. X.; Chen, S.; Xie, M.; Wu, F.; Lu, J.; Amine, K. Design of surface protective layer of LiF/FeF3 nanoparticles in Li-rich cathode for high-capacity Li-ion batteries. Nano Energy 2015, 15, 164–176.
Crossref Google Scholar
[56]

Liu, Y. C.; Wang, J.; Wu, J. W.; Ding, Z. Y.; Yao, P. H.; Zhang, S. L.; Chen, Y. A. 3D cube-maze-like Li-rich layered cathodes assembled from 2D porous nanosheets for enhanced cycle stability and rate capability of lithium-ion batteries. Adv. Energy Mater. 2020, 10, 1903139.
Crossref Google Scholar
[57]

Yang, X. R.; Wang, C. W.; Yan, P. F.; Jiao, T. P.; Hao, J. L.; Jiang, Y. Y.; Ren, F. C.; Zhang, W. G.; Zheng, J. M.; Cheng, Y. et al. Pushing lithium cobalt oxides to 4.7 V by lattice-matched interfacial engineering. Adv. Energy Mater. 2022, 12, 2200197.
Crossref Google Scholar
[58]

Wang, E. R.; Xiao, D. D.; Wu, T. H.; Liu, X. S.; Zhou, Y. N.; Wang, B. Y.; Lin, T.; Zhang, X.; Yu, H. J. Al/Ti synergistic doping enhanced cycle stability of Li-rich layered oxides. Adv. Funct. Mater. 2022, 32, 2201744.
Crossref Google Scholar
[59]

Zhu, Z.; Gao, R.; Waluyo, I.; Dong, Y. H.; Hunt, A.; Lee, J.; Li, J. Stabilized Co-free Li-rich oxide cathode particles with an artificial surface prereconstruction. Adv. Energy Mater. 2020, 10, 2001120.
Crossref Google Scholar
[60]

Zhang, J. C.; Zhang, Q. H.; Wong, D.; Zhang, N.; Ren, G. X.; Gu, L.; Schulz, C.; He, L. H.; Yu, Y.; Liu, X. F. Addressing voltage decay in Li-rich cathodes by broadening the gap between metallic and anionic bands. Nat. Commun. 2021, 12, 3071.
Crossref Google Scholar
[61]

Wang, Y.; Wang, Z. X.; Wu, D. X.; Niu, Q. H.; Lu, P. S.; Ma, T. H.; Su, Y. B.; Chen, L. Q.; Li, H.; Wu, F. Stable Ni-rich layered oxide cathode for sulfide-based all-solid-state lithium battery. eScience 2022, 2, 537–545.
Crossref Google Scholar
[62]

Han, J. G.; Lee, J. B.; Cha, A.; Lee, T. K.; Cho, W.; Chae, S.; Kang, S. J.; Kwak, S. K.; Cho, J.; Hong, S. Y. et al. Unsymmetrical fluorinated malonatoborate as an amphoteric additive for high-energy-density lithium-ion batteries. Energy Environ. Sci. 2018, 11, 1552–1562.
Crossref Google Scholar
[63]

Mu, P. Z.; Zhang, H. R.; Jiang, H. Z.; Dong, T. T.; Zhang, S.; Wang, C.; Li, J. D.; Ma, Y.; Dong, S. M.; Cui, G. L. Bioinspired antiaging binder additive addressing the challenge of chemical degradation of electrolyte at cathode/electrolyte interphase. J. Am. Chem. Soc. 2021, 143, 18041–18051.
Crossref Google Scholar
[64]

Andersson, A. M.; Abraham, D. P.; Haasch, R.; MacLaren, S.; Liu, J.; Amine, K. Surface characterization of electrodes from high power lithium-ion batteries. J. Electrochem. Soc. 2002, 149, A1358.
Crossref Google Scholar
[65]

Zhang, F. L.; Zhou, X. A.; Fu, X. L.; Wang, C.; Wang, B.; Liang, W. B.; Wang, P.; Huang, J.; Li, S. Y. Which is the winner between the single-crystalline and polycrystalline LiNi0.80Co0.15Al0.05O2 cathode in the lithium-ion battery? Mater. Today Energy 2021, 22, 100873.
Crossref Google Scholar
[66]

Wu, S. X.; Yang, Y. J.; Liu, C. B.; Liu, T. F.; Zhang, Y. P.; Zhang, B. K.; Luo, D.; Pan, F.; Lin, Z. In-situ polymerized binder: A three-in-one design strategy for all-integrated SiOx anode with high mass loading in lithium ion batteries. ACS Energy Lett. 2021, 6, 290–297.
Crossref Google Scholar
[67]

Aurbach, D.; Zaban, A.; Ein-Eli, Y.; Weissman, I.; Chusid, O.; Markovsky, B.; Levi, M.; Levi, E.; Schechter, A.; Granot, E. Recent studies on the correlation between surface chemistry, morphology, three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems. J. Power Sources 1997, 68, 91–98.
Crossref Google Scholar
[68]

Kawamura, T.; Okada, S.; Yamaki, J. I. Decomposition reaction of LiPF6-based electrolytes for lithium ion cells. J. Power Sources 2006, 156, 547–554.
Crossref Google Scholar
[69]

Jo, C. H.; Cho, D. H.; Noh, H. J.; Yashiro, H.; Sun, Y. K.; Myung, S. T. An effective method to reduce residual lithium compounds on Ni-rich Li[Ni0.6Co0.2Mn0.2]O2 active material using a phosphoric acid derived Li3PO4 nanolayer. Nano Res. 2015, 8, 1464–1479.
Crossref Google Scholar
[70]

Luo, D.; Cui, J. X.; Zhang, B. K.; Fan, J. M.; Liu, P. Z.; Ding, X. K.; Xie, H. X.; Zhang, Z. H.; Guo, J. J.; Pan, F. et al. Ti-based surface integrated layer and bulk doping for stable voltage and long life of Li-rich layered cathodes. Adv. Funct. Mater. 2021, 31, 2009310.
Crossref Google Scholar
[71]

Li, Q. Y.; Ning, D.; Zhou, D.; An, K.; Wong, D.; Zhang, L. J.; Chen, Z. H.; Schuck, G.; Schulz, C.; Xu, Z. J. et al. The effect of oxygen vacancy and spinel phase integration on both anionic and cationic redox in Li-rich cathode materials. J. Mater. Chem. A 2020, 8, 7733–7745.
Crossref Google Scholar
[72]

Bao, L. Y.; Wei, L.; Fu, N. T.; Dong, J. Y.; Chen, L.; Su, Y. F.; Li, N.; Lu, Y.; Li, Y. J.; Chen, S. et al. Urea-assisted mixed gas treatment on Li-rich layered oxide with enhanced electrochemical performance. J. Energy Chem. 2022, 66, 123–132.
Crossref Google Scholar
[73]

Yang, J. C.; Chen, Y. X.; Li, Y. J.; Xi, X. M.; Zheng, J. C.; Zhu, Y. L.; Xiong, Y. K.; Liu, S. W. Encouraging voltage stability upon long cycling of Li-rich Mn-based cathode materials by Ta-Mo dual doping. ACS Appl. Mater. Interfaces 2021, 13, 25981–25992.
Crossref Google Scholar
[74]

Yu, R. Z.; Wang, X. Y.; Fu, Y. Q.; Wang, L. W.; Cai, S. Y.; Liu, M. H.; Lu, B.; Wang, G.; Wang, D.; Ren, Q. F. et al. Effect of magnesium doping on properties of lithium-rich layered oxide cathodes based on a one-step co-precipitation strategy. J. Mater. Chem. A 2016, 4, 4941–4951.
Crossref Google Scholar
[75]

Ni, L. S.; Guo, R. T.; Fang, S. S.; Chen, J.; Gao, J. Q.; Mei, Y.; Zhang, S.; Deng, W. T.; Zou, G. Q.; Hou, H. S. et al. Crack-free single-crystalline Co-free Ni-rich LiNi0.95Mn0.05O2 layered cathode. eScience 2022, 2, 116–124.
Crossref Google Scholar
Nano Research
Volume 16 Issue 5,
May 2023
Pages 6805-6814
DOI: 10.1007/s12274-022-5333-z
Cite this article:
Zhao R, Wu M, Jiao P, et al. A double-layer covered architecture with spinel phase induced by LiPP for Co-free Li-rich cathode with high-rate performance and long lifespan. Nano Research, 2023, 16(5): 6805-6814. https://doi.org/10.1007/s12274-022-5333-z
Topics:
Energy storageLithium batteries

7500

Views

7

Crossref

7

Web of Science

7

Scopus

0

CSCD

Altmetrics
Received: 26 August 2022
Revised: 05 November 2022
Accepted: 16 November 2022
Published: 06 February 2023
© Tsinghua University Press 2022
Return