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Review Article

Interface engineering of MXene-based heterostructures for lithium-sulfur batteries

Siyu Wu1, Xiang Li1, Yongzheng Zhang1,2( ), Qinghua Guan3, Jian Wang3,4( ), Chunyin Shen1, Hongzhen Lin3, Jitong Wang1, Yanli Wang1, Liang Zhan1( ), Licheng Ling1
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China
Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China
i-Lab & CAS Key Laboratory of Nanophotonic Materials and Devices, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, China
Helmholtz Institute Ulm (HIU), Ulm D89081, Germany
Show Author Information

Graphical Abstract

Interface engineering of MXene-based heterostructures is an effective way to enhance the electrochemical performances of lithium-sulfur batteries because of the unique heterointerface structures. An overview of the recent progress in MXene-based heterostructures in sulfur hosts, modification layers, and Li protection layers is provided. The future developments of MXene-based materials for Li-S batteries are outlined.

Abstract

High energy density and low cost make lithium-sulfur (Li-S) batteries as one of the next generation's promising energy storage systems. However, the following problems need to be solved before commercialization: (i) the shuttling effect and sluggish redox kinetics of lithium polysulfides in sulfur cathode; (ii) the formation of lithium dendrites and the crack of solid electrolyte interphase; (iii) the large volume changes during charge and discharge processes. MXenes, as newly emerging two-dimensional transition metal carbides/nitrides/carbonitrides, have attracted widespread attention due to their abundant active surface terminals, adjustable vacancies, and high electrical conductivity. Designing MXene-based heterogeneous structures is expected to solve the stacking problem induced by hydrogen bonds or Van der Waals force and to provide other charming physiochemical properties. Herein, we generalize the design principles of MXene-based heterostructures and their functions, i.e., adsorption and catalysis in advanced conversion-based Li-S batteries. Firstly, the physiochemical properties of MXene and MXene-based heterostructures are briefly introduced. Secondly, the catalytic functions of MXene-based heterostructures with the compositional constituents including carbon materials, metal compounds, organic frameworks, polymers, single atoms and special high-entropy MXenes are comprehensively summarized in sulfur cathodes and lithium anodes. Finally, the challenges of MXene-based heterostructure in current Li-S batteries are pointed out and we also provide some enlightenments for future developments in high-energy-density Li-S batteries.

Keywords

MXeneheterostructureslithium-sulfur batteryshuttle effectinterface engineering

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Nano Research
Volume 16 Issue 7,
July 2023
Pages 9158-9178
DOI: 10.1007/s12274-023-5532-2
Cite this article:
Wu S, Li X, Zhang Y, et al. Interface engineering of MXene-based heterostructures for lithium-sulfur batteries. Nano Research, 2023, 16(7): 9158-9178. https://doi.org/10.1007/s12274-023-5532-2
Topics:
Lithium sulfur batteries

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Received: 30 December 2022
Revised: 18 January 2023
Accepted: 29 January 2023
Published: 25 May 2023
© Tsinghua University Press 2023
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