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Research Article | Open Access

High-performance flexible all-solid-state asymmetric supercapacitors based on binder-free MXene/cellulose nanofiber anode and carbon cloth/polyaniline cathode

Xiaoyu Bi1, Meichun Li2, Guoqiang Zhou1, Chaozheng Liu1, Runzhou Huang1( ), Yang Shi1, Ben Bin Xu3, Zhanhu Guo3( ), Wei Fan4, Hassan Algadi3,5,6, Shengbo Ge1( )
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China
Integrated Composites Lab, Department of Mechanical and Construction Engineering, Northumbria University, Newcastle Upon Tyne, NE1 8ST, UK
School of Textile Science and Engineering & Key Laboratory of Functional Textile Material and Product of Ministry of Education, Xi'an Polytechnic University, Xi'an 710048, China
College of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China
Department of Electrical Engineering, Faculty of Engineering, Najran University, Najran, 11001, Saudi Arabia
Show Author Information

Graphical Abstract

The added cellulose nanofibers (CNFs) not only improve the mechanical properties of the composite film electrode, but also adjust the electrode structure of the MXene/CNF (MCNF), thus effectively improving its electrochemical properties and facilitating the charge balance between the MCNF anode and the positive electrodes (CP) cathode. The assemble of asymmetric devices effectively expands the operating voltage window to 1.5 V and yields ultra-high weight power and energy density.

Abstract

The search for wearable electronics has been attracted great efforts, and there is an ever-growing demand for all-solid-state flexible energy storage devices. However, it is a challenge to obtain both positive and negative electrodes with excellent mechanical strength and match positive and negative charges to achieve high energy densities and operate voltages to satisfy practical application requirements. Here, flexible MXene (Ti3C2Tx)/cellulose nanofiber (CNF) composite film negative electrodes (MCNF) were fabricated with a vacuum filtration method, as well as positive electrodes (CP) by combining polyaniline (PANI) with carbon cloth (CC) using an in-situ polymerization method. Both positive and negative free-standing electrodes exhibited excellent electrochemical behavior and bendable/foldable flexibility. As a result, the all-pseudocapacitance asymmetric device of MCNF//CP assembled with charge-matched between anode and cathode achieves an extended voltage window of 1.5 V, high energy density of 30.6 Wh·kg−1 (1211 W·kg−1), and 86% capacitance retention after 5000 cycles, and the device maintains excellent bendability, simultaneously. This work will pave the way for the development of all-pseudocapacitive asymmetric supercapacitors (ASC) with simultaneously preeminent mechanical properties, high energy density, and wide operating voltage window.

Keywords

MXenecellulose nanofiberpolyanilineasymmetric supercapacitors

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Nano Research
Volume 16 Issue 5,
May 2023
Pages 7696-7709
DOI: 10.1007/s12274-023-5586-1
Cite this article:
Bi X, Li M, Zhou G, et al. High-performance flexible all-solid-state asymmetric supercapacitors based on binder-free MXene/cellulose nanofiber anode and carbon cloth/polyaniline cathode. Nano Research, 2023, 16(5): 7696-7709. https://doi.org/10.1007/s12274-023-5586-1
Topics:
Electrolytic capacitors

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Received: 03 January 2023
Revised: 16 February 2023
Accepted: 16 February 2023
Published: 22 March 2023
© The Author(s) 2023

Copyright: © 2023 by the author(s). This article is an open access article distributed under Creative Commons Attribution License (CC BY 4.0), visit https://creativecommons.org/licenses/by/4.0/.
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