AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Thermally conductive polyvinyl alcohol composite films via introducing hetero-structured MXene@silver fillers

Mukun Li1, Yuyao Sun1, Dianying Feng3, Kunpeng Ruan2( ), Xia Liu3, Junwei Gu1,2( )
Queen Mary University of London Engineering School, Northwestern Polytechnical University, Xi’an 710072, China
Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an 710072, China
Shandong Nonmetallic Materials Institute, Jinan 250031, China
Show Author Information

Graphical Abstract

Ag nanoparticles were in-situ grown on the surface of MXene nanosheets to prepare thermally conductive hetero-structured MXene@Ag fillers. 60 wt.% MXene@Ag-III/PVA composite film shows dual functions of excellent thermal conductivity and electromagnetic interference (EMI) shielding performance, with λ∥, λ⊥, and EMI shielding effectiveness (EMI SE) of 3.72 and 0.41 W/(m·K), and 32 dB, respectively.

Abstract

Ag nanoparticles were in-situ grown on the surface of MXene nanosheets to prepare thermally conductive hetero-structured MXene@Ag fillers. With polyvinyl alcohol (PVA) as the polymer matrix, thermally conductive MXene@Ag/PVA composite films were fabricated by the processes of solution blending, pouring, and evaporative self-assembly. With the same mass fraction, MXene@Ag-III (MXene/Ag, 2:1, w/w) presents more significant improvement in thermal conductivity coefficient (λ) than MXene@Ag, single MXene, Ag, and simply blending MXene/Ag. MXene@Ag-III/PVA composite films show dual functions of excellent thermal conductivity and electromagnetic interference (EMI) shielding. When the mass fraction of MXene@Ag-III is 60 wt.%, the in-plane λ (λ∥), through-plane λ (λ⊥), and EMI shielding effectiveness (EMI SE) are 3.72 and 0.41 W/(m∙K), and 32 dB, which are increased by 3.1, 1.3, and 105.7 times than those of pure PVA film (0.91 and 0.18 W/(m∙K), and 0.3 dB), respectively. The 60 wt.% MXene@Ag-III/PVA composite film also has satisfying mechanical and thermal properties, with Young’s modulus, glass transition temperature, and heat resistance index of 3.8 GPa, 58.5 and 175.3 °C, respectively.

Keywords

hetero-structured MXene@Ag fillerspolyvinyl alcohol composite filmsthermal conductivityelectromagnetic interference shielding

Electronic Supplementary Material

Download File(s)
12274_2023_5594_MOESM1_ESM.pdf (2.3 MB)

References

[1]

Smith, A. T.; Shen, K. Y.; Hou, Z. L.; Zeng, S. S.; Jin, J.; Ning, C. J.; Zhao, Y. F.; Sun, L. Y. Dual photo- and mechanochromisms of graphitic carbon nitride/polyvinyl alcohol film. Adv. Funct. Mater. 2022, 32, 2110285.
Crossref Google Scholar
[2]

Ouyang, Z. F.; Cui, S. B.; Yu, H. Y.; Xu, D. W.; Wang, C.; Tang, D. P.; Tam, K. C. Versatile sensing devices for self-driven designated therapy based on robust breathable composite films. Nano Res. 2022, 15, 1027–1038.
Crossref Google Scholar
[3]

Li, Z. P.; Deng, L.; Lv, H. C.; Liang, L. R.; Deng, W. J.; Zhang, Y. C.; Chen, G. M. Mechanically robust and flexible films of ionic liquid-modulated polymer thermoelectric composites. Adv. Funct. Mater. 2021, 31, 2104836.
Crossref Google Scholar
[4]

Yu, J. W.; Gu, W. H.; Zhao, H. Q.; Ji, G. B. Lightweight, flexible, and freestanding PVA/PEDOT: PSS/Ag NWs film for high-performance electromagnetic interference shielding. Sci. China Mater. 2021, 64, 1723–1732.
Crossref Google Scholar
[5]

Wang, W.; Wang, S.; Xiang, C. X.; Xue, D.; Li, M. F.; Liu, Q. Z.; Piao, L.; Wang, D. Nanofiber-based transparent film with controllable optical transparency adjustment function for versatile bionic applications. Nano Res. 2022, 15, 564–572.
Crossref Google Scholar
[6]

Chen, W. H.; Liu, P. J.; Min, L. Z.; Zhou, Y. M.; Liu, Y.; Wang, Q.; Duan, W. Non-covalently functionalized graphene oxide-based coating to enhance thermal stability and flame retardancy of PVA film. Nano-Micro Lett. 2018, 10, 39.
Crossref Google Scholar
[7]

Ruan, K. P.; Guo, Y. Q.; Gu, J. W. Liquid crystalline polyimide films with high intrinsic thermal conductivities and robust toughness. Macromolecules 2021, 54, 4934–4944.
Crossref Google Scholar
[8]

Chen, Q.; Ma, Z. W.; Wang, Z. Z.; Liu, L.; Zhu, M. H.; Lei, W. W.; Song, P. G. Scalable, robust, low-cost, and highly thermally conductive anisotropic nanocomposite films for safe and efficient thermal management. Adv. Funct. Mater. 2022, 32, 2110782.
Crossref Google Scholar
[9]

Gong, S.; Sheng, X. X.; Li, X. L.; Sheng, M. J.; Wu, H.; Lu, X.; Qu, J. P. A multifunctional flexible composite film with excellent multi-source driven thermal management, electromagnetic interference shielding, and fire safety performance, inspired by a “brick-mortar” sandwich structure. Adv. Funct. Mater. 2022, 32, 2200570.
Crossref Google Scholar
[10]

Xu, C. Y.; Li, E. C.; Zeng, J. J.; Wang, Y.; Wang, T.; Ge, C.; Zhang, C.; Wang, Q.; Gao, T.; Yao, Y. G. et al. Interfacial thermal conductance enhancement of BN/PVA composites via plasma activations of fillers. Compos. Commun. 2021, 28, 100963.
Crossref Google Scholar
[11]

Wang, W. B.; Liu, B. T.; Lv, X. M. Robust PU foam skeleton coated with hydroxylated BN as PVA thermal conductivity filler via microwave-assisted curing. J. Mater. Sci. Mater. Electron. 2021, 32, 27524–27533.
Crossref Google Scholar
[12]

Zhang, Y.; He, H.; Huang, B.; Wang, S. Z.; He, X. F. Enhanced thermal conductivity of polyvinyl alcohol insulation composites with m-BN@CNW hybrid materials. Compos. Sci. Technol. 2021, 208, 108766.
Crossref Google Scholar
[13]

Luo, F. H.; Ma, C.; Tang, Y. H.; Zhou, L. T.; Ding, Y. P.; Chen, G. H. Sandwich-structured flexible PVA/CS@MWCNTs composite films with high thermal conductivity and excellent electrical insulation. Polymers 2022, 14, 2512.
Crossref Google Scholar
[14]

Zhang, H. Z.; Wu, K.; Jiao, E. X.; Chen, B.; Shi, J.; Lu, M. G. Greatly improved thermal conductivity and electrical insulation for PVA composites via introducing functional carbon nitride nanosheets. Eur. Polym. J. 2021, 159, 110718.
Crossref Google Scholar
[15]

Ruan, K. P.; Gu, J. W. Ordered alignment of liquid crystalline graphene fluoride for significantly enhancing thermal conductivities of liquid crystalline polyimide composite films. Macromolecules 2022, 55, 4134–4145.
Crossref Google Scholar
[16]

Zheng, J. L.; Deng, Y.; Liu, Y. L.; Wu, F. Z.; Wang, W. H.; Wang, H.; Sun, S. Y.; Lu, J. Paraffin/polyvinyl alcohol/MXene flexible phase change composite films for thermal management applications. Chem. Eng. J. 2023, 453, 139727.
Crossref Google Scholar
[17]

Yang, S. D.; He, Y. S.; Zhang, J. H. Fluorine-terminated functionalized liquid metal/silicon carbide binary nanoparticles for polyvinyl alcohol composite films with high in-plane thermal conductivity and ultra-low dielectric constant. Surf. Interfaces 2022, 35, 102408.
Crossref Google Scholar
[18]

Hu, J. J.; Hou, X. G.; Yang, T.; Wang, Y.; Si, K.; Xia, H. Y. Thermal management performance of polyvinyl alcohol composite with boron phosphide decorated reduced graphene oxide. Compos. Part A Appl. Sci. Manuf. 2022, 155, 106847.
Crossref Google Scholar
[19]

Chen, Q.; Wang, Z. Z. A copper organic phosphonate functionalizing boron nitride nanosheet for PVA film with excellent flame retardancy and improved thermal conductive property. Compos. Part A Appl. Sci. Manuf. 2022, 153, 106738.
Crossref Google Scholar
[20]

Luo, F. H.; Zhang, M.; Chen, S. L.; Xu, J. F.; Ma, C.; Chen, G. H. Sandwich-structured PVA/rGO films from self-construction with high thermal conductivity and electrical insulation. Compos. Sci. Technol. 2021, 207, 108707.
Crossref Google Scholar
[21]

Zhou, J. W.; Yu, Z. X.; Lv, Y. R.; Wang, C.; Hu, P.; Liu, Y. Highly thermal conductivity of PVA-based nanocomposites by constructing MWCNT-BNNS conductive paths. Compos. Part A Appl. Sci. Manuf. 2022, 163, 107195.
Crossref Google Scholar
[22]

Yan, C. Z.; Yu, T. H.; Ji, C.; Kang, D. J.; Wang, N.; Sun, R.; Wong, C. P. Tailoring highly thermal conductive properties of Te/MoS2/Ag heterostructure nanocomposites using a bottom–up approach. Adv. Electron. Mater. 2019, 5, 1800548.
Crossref Google Scholar
[23]

Ji, C.; Yan, C. Z.; Wang, Y.; Xiong, S. X.; Zhou, F. R.; Li, Y. Y.; Sun, R.; Wong, C. P. Thermal conductivity enhancement of CNT/MoS2/graphene-epoxy nanocomposites based on structural synergistic effects and interpenetrating network. Compos. Part B Eng. 2019, 163, 363–370.
Crossref Google Scholar
[24]

Fu, C. J.; Yan, C. Z.; Ren, L. L.; Zeng, X. L.; Du, G. P.; Sun, R.; Xu, J. B.; Wong, C. P. Improving thermal conductivity through welding boron nitride nanosheets onto silver nanowires via silver nanoparticles. Compos. Sci. Technol. 2019, 177, 118–126.
Crossref Google Scholar
[25]

Yan, W.; Zhang, Y.; Sun, H. W.; Liu, S. W.; Chi, Z. G.; Chen, X. D.; Xu, J. R. Polyimide nanocomposites with boron nitride-coated multi-walled carbon nanotubes for enhanced thermal conductivity and electrical insulation. J. Mater. Chem. A 2014, 2, 20958–20965.
Crossref Google Scholar
[26]

Ruan, K. P.; Yan, H.; Zhang, S. J.; Shi, X. T.; Guo, Y. Q.; Gu, J. W. In-situ fabrication of hetero-structured fillers to significantly enhance thermal conductivities of silicone rubber composite films. Compos. Sci. Technol. 2021, 210, 108799.
Crossref Google Scholar
[27]

Han, Y. X.; Ruan, K. P.; Gu, J. W. Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances. Nano Res. 2022, 15, 4747–4755.
Crossref Google Scholar
[28]

Wu, N.; Yang, Y. F.; Wang, C. X.; Wu, Q. L.; Pan, F.; Zhang, R. N.; Liu, J. R.; Zeng, Z. H. Ultrathin cellulose nanofiber assisted ambient-pressure-dried, ultralight, mechanically robust, multifunctional MXene aerogels. Adv. Mater. 2023, 35, 2207969.
Crossref Google Scholar
[29]

Zhang, Y. L.; Ma, Z. L.; Ruan, K. P.; Gu, J. W. Multifunctional Ti3C2Tx-(Fe3O4/polyimide) composite films with Janus structure for outstanding electromagnetic interference shielding and superior visual thermal management. Nano Res. 2022, 15, 5601–5609.
Crossref Google Scholar
[30]

Liu, S.; Wang, S.; Sang, M.; Zhou, J. Y.; Zhang, J. S.; Xuan, S. H.; Gong, X. L. Nacre-mimetic hierarchical architecture in polyborosiloxane composites for synergistically enhanced impact resistance and ultra-efficient electromagnetic interference shielding. ACS Nano 2022, 16, 19067–19086.
Crossref Google Scholar
[31]

Zhang, Y. L.; Kong, J.; Gu, J. W. New generation electromagnetic materials: Harvesting instead of dissipation solo. Sci. Bull. 2022, 67, 1413–1415.
Crossref Google Scholar
[32]

Ying, M. F.; Zhao, R. Z.; Hu, X.; Zhang, Z. H.; Liu, W. W.; Yu, J. Y.; Liu, X. L.; Liu, X. G.; Rong, H. W.; Wu, C. et al. Wrinkled titanium carbide (MXene) with surface charge polarizations through chemical etching for superior electromagnetic interference shielding. Angew. Chem., Int. Ed. 2022, 61, e202201323.
Crossref Google Scholar
[33]

Wang, B. B.; Jia, P. F.; Zhang, Y.; He, R. F.; Song, L.; Hu, Y. Multifunctional composite polyvinyl alcohol films prepared with economic conductive carbon black and MXene microcapsuled APP. Mater. Today Phys. 2023, 30, 100928.
Crossref Google Scholar
[34]

Pal Singh, P.; De, A.; Khatua, B. B. Hydro-tunable CZTO/SWCNT/PVA/PDMS hybrid composites for smart green EMI shielding. J. Mater. Chem. C 2022, 10, 16903–16913.
Crossref Google Scholar
[35]

Si, Y. F.; Jin, H. H.; Zhang, Q.; Xu, D. W.; Xu, R. X.; Ding, A. X.; Liu, D. Roll-to-roll processable MXene-rGO-PVA composite films with enhanced mechanical properties and environmental stability for electromagnetic interference shielding. Ceram. Int. 2022, 48, 24898–24905.
Crossref Google Scholar
[36]

Han, Y. X.; Ruan, K. P.; Gu, J. W. Multifunctional thermally conductive composite films based on fungal tree-like heterostructured silver nanowires@boron nitride nanosheets and aramid nanofibers. Angew. Chem., Int. Ed. 2023, 62, e202216093.
Crossref Google Scholar
[37]

Wan, S. J.; Li, X.; Chen, Y.; Liu, N. N.; Wang, S. J.; Du, Y.; Xu, Z. P.; Deng, X. L.; Dou, S. X.; Jiang, L. et al. Ultrastrong MXene films via the synergy of intercalating small flakes and interfacial bridging. Nat. Commun. 2022, 13, 7340.
Crossref Google Scholar
[38]

Cheng, Y.; Li, X. Y.; Qin, Y. X.; Fang, Y. T.; Liu, G. L.; Wang, Z. Y.; Matz, J.; Dong, P.; Shen, J. F.; Ye, M. X. Hierarchically porous polyimide/Ti3C2Tx film with stable electromagnetic interference shielding after resisting harsh conditions. Sci. Adv. 2021, 7, eabj1663.
Crossref Google Scholar
[39]
Zhang, Y. L.; Ruan, K. P.; Zhou, K.; Gu, J. W. Controlled distributed Ti3C2Tx hollow microspheres on thermally conductive polyimide composite films for excellent electromagnetic interference shielding. Adv. Mater., in press, https://doi.org/10.1002/adma.202211642.
Crossref
[40]

Li, J.; Yuan, X. T.; Lin, C.; Yang, Y. Q.; Xu, L.; Du, X.; Xie, J. L.; Lin, J. H.; Sun, J. L. Achieving high pseudocapacitance of 2D titanium carbide (MXene) by cation intercalation and surface modification. Adv. Energy Mater. 2017, 7, 1602725.
Crossref Google Scholar
[41]

Maiti, N.; Thomas, S.; Debnath, A.; Kapoor, S. Raman and XPS study on the interaction of taurine with silver nanoparticles. RSC Adv. 2016, 6, 56406–56411.
Crossref Google Scholar
[42]

Shen, J.; Liu, G. Z.; Ji, Y. F.; Liu, Q.; Cheng, L.; Guan, K. C.; Zhang, M. C.; Liu, G. P.; Xiong, J.; Yang, J. et al. 2D MXene nanofilms with tunable gas transport channels. Adv. Funct. Mater. 2018, 28, 1801511.
Crossref Google Scholar
[43]

Shuck, C. E.; Sarycheva, A.; Anayee, M.; Levitt, A.; Zhu, Y. Z.; Uzun, S.; Balitskiy, V.; Zahorodna, V.; Gogotsi, O.; Gogotsi, Y. Scalable Synthesis of Ti3C2Tx MXene. Adv. Eng. Mater. 2020, 22, 1901241.
Crossref Google Scholar
[44]

Lim, E. J.; Choi, S. M.; Seo, M. H.; Kim, Y.; Lee, S.; Kim, W. B. Highly dispersed Ag nanoparticles on nanosheets of reduced graphene oxide for oxygen reduction reaction in alkaline media. Electrochem. Commun. 2013, 28, 100–103.
Crossref Google Scholar
[45]

Yang, G.; Zhang, X. D.; Shang, Y.; Xu, P. H.; Pan, D.; Su, F. M.; Ji, Y. X.; Feng, Y. Z.; Liu, Y. Z.; Liu, C. T. Highly thermally conductive polyvinyl alcohol/boron nitride nanocomposites with interconnection oriented boron nitride nanoplatelets. Compos. Sci. Technol. 2021, 201, 108521.
Crossref Google Scholar
[46]

Zhao, K. C.; Liu, G.; Cao, W. X.; Su, Z. H.; Zhao, J. W.; Han, J. C.; Dai, B.; Cao, K. L.; Zhu, J. Q. A combination of nanodiamond and boron nitride for the preparation of polyvinyl alcohol composite film with high thermal conductivity. Polymer 2020, 206, 122885.
Crossref Google Scholar
[47]

Wang, X. D.; Hu, W. Z.; Hu, Y. Polydopamine-bridged synthesis of ternary h-BN@PDA@TiO2 as nanoenhancers for thermal conductivity and flame retardant of polyvinyl alcohol. Front. Chem. 2020, 8, 587474.
Crossref Google Scholar
[48]

Wang, X.; Ji, S. L.; Wang, X. Q.; Bian, H. Y.; Lin, L. R.; Dai, H. Q.; Xiao, H. N. Thermally conductive, super flexible, and flame-retardant BN-OH/PVA composite film reinforced by lignin nanoparticles. J. Mater. Chem. C 2019, 7, 14159–14169.
Crossref Google Scholar
[49]

Choi, B. K.; Lee, H. J.; Choi, W. K.; Lee, M. K.; Park, J. H.; Hwang, J. Y.; Seo, M. K. Effect of carbon fiber content on thermal and electrical conductivity, EMI shielding efficiency, and radiation energy of CMC/PVA composite papers with carbon fibers. Synth. Met. 2021, 273, 116708.
Crossref Google Scholar
[50]

El-Shamy, A. G. Polyvinyl alcohol and silver decorated carbon quantum-dots for new nano-composites with application electromagnetic interface (EMI) shielding. Prog. Org. Coat. 2020, 146, 105747.
Crossref Google Scholar
[51]

Yao, Y. Y.; Jin, S. H.; Wang, M. M.; Gao, F.; Xu, B. L.; Lv, X. J.; Shu, Q. H. MXene hybrid polyvinyl alcohol flexible composite films for electromagnetic interference shielding. Appl. Surf. Sci. 2022, 578, 152007.
Crossref Google Scholar
[52]

Wang, W.; Yuen, A. C. Y.; Long, H.; Yang, W.; Li, A.; Song, L.; Hu, Y.; Yeoh, G. H. Random nano-structuring of PVA/MXene membranes for outstanding flammability resistance and electromagnetic interference shielding performances. Compos. Part B Eng. 2021, 224, 109174.
Crossref Google Scholar
[53]

Cazón, P.; Vázquez, M.; Velazquez, G. Novel composite films based on cellulose reinforced with chitosan and polyvinyl alcohol: Effect on mechanical properties and water vapour permeability. Polym. Test. 2018, 69, 536–544.
Crossref Google Scholar
[54]

Tao, C. A.; Zhang, H.; Wang, F.; Zhu, H.; Zou, X. R.; Wang, J. F. Mechanical properties of graphene oxide/polyvinyl alcohol composite film. Polym. Polym. Compos. 2017, 25, 11–16.
Crossref Google Scholar
[55]

Aslam, M.; Kalyar, M. A.; Raza, Z. A. Investigation of structural and thermal properties of distinct nanofillers-doped PVA composite films. Polym. Bull. 2019, 76, 73–86.
Crossref Google Scholar
[56]

Rao, X.; Ou, Z. Q.; Zhou, Q.; Fu, L. Y.; Gong, Y.; Wen, Q.; Du, X. Y.; Liang, C. Green cross-linked coir cellulose nanocrystals/poly (vinyl alcohol) composite films with enhanced water resistance, mechanical properties, and thermal stability. J. Appl. Polym. Sci. 2022, 139, 52361.
Crossref Google Scholar
Nano Research
Volume 16 Issue 5,
May 2023
Pages 7820-7828
DOI: 10.1007/s12274-023-5594-1
Cite this article:
Li M, Sun Y, Feng D, et al. Thermally conductive polyvinyl alcohol composite films via introducing hetero-structured MXene@silver fillers. Nano Research, 2023, 16(5): 7820-7828. https://doi.org/10.1007/s12274-023-5594-1
Topics:
Nanocomposites
Part of a topical collection:
The winners of “Top Papers Award” in 2023

1236

Views

135

Crossref

138

Web of Science

140

Scopus

3

CSCD

Altmetrics
Received: 10 February 2023
Revised: 18 February 2023
Accepted: 19 February 2023
Published: 15 March 2023
© Tsinghua University Press 2023
Return