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Research Article

MoSe2/TiO2 heterostructure integrated in N-doped carbon nanosheets assembled porous core–shell microspheres for enhanced sodium storage

Nianxiang Shi1( ), Guangzeng Liu1, Baojuan Xi2, Xuguang An3, Changhui Sun1, Xinzheng Liu1, Shenglin Xiong2( )
School of Chemistry and Chemistry Engineering, Qilu Normal University, Jinan 250200, China
School of Chemistry and Chemical Engineering, and State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China
School of Mechanical Engineering, Chengdu University, Chengdu 610106, China
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Graphical Abstract

MoSe2/TiO2 heterostructure is integrated with N-doped carbon nanosheets to assemble into hierarchical flower-like porous core–shell microspheres, which is firstly reported by room-temperature stirring coupled with vulcanization treatment. The novel heterostructures of MoSe2/TiO2 not only enhance the utilization rate of electrode materials, but also facilitate electron transfer and accelerate reaction kinetics.

Abstract

Engineering the structure and composition of electrode materials is one of the essential means for achieving excellent electrochemical performance. The rational design of Na+ host materials is still a massive challenge for sodium ion batteries (SIBs). Herein, MoSe2/TiO2 heterostructure is integrated with N-doped carbon nanosheets to assemble into hierarchical flower-like porous core–shell microspheres (MoSe2/TiO2@N-C), which is firstly reported by room-temperature stirring coupled with vulcanization treatment. The cavity of the core–shell structure could provide enough storage space for Na+ and alleviate the volume expansion during charge/discharge processes. The apertures between nanosheets provide a guarantee for the rapid penetration of electrolyte to enhance the utilization rate of electrode materials. Furthermore, building heterostructures by combining different phase structures can facilitate electron transfer and accelerate reaction kinetics. Benefiting from the synergistic contributions of structure and composition, MoSe2/TiO2@N-C as SIBs anode material shows better reversible capacities of 302.5 mAh·g−1 at 1 A·g−1 for 400 cycles and 217.4 mAh·g−1 at 4 A·g−1 for 900 cycles. Strikingly, the reversible capacities can be restored entirely to the initial level after a high current density cycle.

Keywords

MoSe2/TiO2flower-like hierarchical porous core–shell microspheresheterostructuresodium ion batteries

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Nano Research
Volume 16 Issue 7,
July 2023
Pages 9398-9406
DOI: 10.1007/s12274-023-5604-3
Cite this article:
Shi N, Liu G, Xi B, et al. MoSe2/TiO2 heterostructure integrated in N-doped carbon nanosheets assembled porous core–shell microspheres for enhanced sodium storage. Nano Research, 2023, 16(7): 9398-9406. https://doi.org/10.1007/s12274-023-5604-3
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Secondary batteries

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Received: 18 December 2022
Revised: 20 February 2023
Accepted: 22 February 2023
Published: 22 March 2023
© Tsinghua University Press 2023
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