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Research Article

A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion

Yuntai Xi1,2, Fang Dong1,3( ), Xin Xu4, Shixing Wu2, Zhicheng Tang1( ), Jiyi Zhang2( )
State Key Laboratory for Oxo Synthesis and Selective Oxidation, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
School of Petroleum and Chemical, Lanzhou University of Technology, Lanzhou 730050, China
Dalian National Laboratory for Clean Energy, Dalian 116023, China
Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China
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Graphical Abstract

A novel monolithic ordered macro–mesoporous catalyst decorated by hierarchical Co-phyllosilicate ultrathin nanosheets was successfully constructed with three-dimensional (3D) printing technology. We observed that this monolithic catalyst structure exhibited superior catalytic activity, excellent thermal stability, and water resistance, and the catalytic combustion of benzene is achieved through the synergistic promotion of Co&+ species, abundant acid sites, and active oxygen.

Abstract

In this study, a novel three-dimensional (3D)-OMm-Co3O4/SiO2-0.5AP (OMm = ordered macro–meso porous, AP = aluminum phosphate) monolithic catalyst was for the first time constructed successfully with the hierarchical Co-phyllosilicate ultrathin nanosheets growth on the surface of 3D printed ordered macropore–mesoporous SiO2 support. On the one hand, we discovered that the construction of ordered macropore–mesoporous structures is beneficial to the diffusion and adsorption of reactants, intermediates, and products. On the other hand, the formation of hierarchical Co-phyllosilicate ultrathin nanosheets could provide more active Co&+ species, abundant acid sites, and active oxygen. The above factors are in favor of improving the catalytic performance of benzene oxidation, and then a 3D-OMm-Co3O4/SiO2-0.5AP catalyst exhibited the superior catalytic activity. To explore the effect of catalysts structure and morphology, various Co-based catalysts were also constructed. Simultaneously, the 3D-OMm-Co3O4/SiO2-0.5AP catalyst has excellent catalytic performance, water resistance, and thermal stability in the catalytic combustion of benzene due to the strong interactions between Co&+ species and SiO2 in the phyllosilicate. Therefore, this study proposes a new catalyst synthesis method through 3D printing, and presents considerable prospects for the removal of VOCs from industrial applications.

Keywords

Co-phyllosilicatethree-dimensional (3D) printingordered porousvolatile organic compounds (VOCs)catalytic oxidation

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References

[1]

Wen, M.; Dong, F.; Yao, J. F.; Tang, Z. C.; Zhang, J. Y. Pt nanoparticles confined in the ordered mesoporous CeO2 as a highly efficient catalyst for the elimination of VOCs. J. Catal. 2022, 412, 42–58.
Crossref Google Scholar
[2]

Chen, J.; Chen, X.; Chen, X.; Xu, W. J.; Xu, Z.; Jia, H. P.; Chen, J. Homogeneous introduction of CeOy into MnOx-based catalyst for oxidation of aromatic VOCs. Appl. Catal. B: Environ. 2018, 224, 825–835.
Crossref Google Scholar
[3]

Li, L.; Liu, S. Q.; Liu, J. X. Surface modification of coconut shell based activated carbon for the improvement of hydrophobic VOC removal. J. Hazard. Mater. 2011, 192, 683–690.
Crossref Google Scholar
[4]

Destaillats, H.; Sleiman, M.; Sullivan, D. P.; Jacquiod, C.; Sablayrolles, J.; Molins, L. Key parameters influencing the performance of photocatalytic oxidation (PCO) air purification under realistic indoor conditions. Appl. Catal. B: Environ. 2012, 128, 159–170.
Crossref Google Scholar
[5]

Parmar, G. R.; Rao, N. N. Emerging control technologies for volatile organic compounds. Crit. Rev. Environ. Sci. Technol. 2008, 39, 41–78.
Crossref Google Scholar
[6]

Luo, Y. J.; Wang, K. C.; Chen, Q. H.; Xu, Y. X.; Xue, H.; Qian, Q. R. Preparation and characterization of electrospun La1−xCexCoOδ: Application to catalytic oxidation of benzene. J. Hazard. Mater. 2015, 296, 17–22.
Crossref Google Scholar
[7]

Zhang, C. H.; Guo, Y. L.; Guo, Y.; Lu, G. Z.; Boreave, A.; Retailleau, L.; Baylet, A.; Giroir-Fendler, A. LaMnO3 perovskite oxides prepared by different methods for catalytic oxidation of toluene. Appl. Catal. B: Environ. 2014, 148–149, 490–498.
Crossref Google Scholar
[8]

Wang, X. Y.; Liu, Y.; Zhang, T. H.; Luo, Y. J.; Lan, Z. X.; Zhang, K.; Zuo, J. C.; Jiang, L. L.; Wang, R. H. Geometrical-site-dependent catalytic activity of ordered mesoporous Co-based spinel for benzene oxidation: In situ DRIFTS study coupled with Raman and XAFS spectroscopy. ACS Catal. 2017, 7, 1626–1636.
Crossref Google Scholar
[9]

Feng, X. B.; Chen, C. W.; He, C.; Chai, S. N.; Yu, Y. K.; Cheng, J. Non-thermal plasma coupled with MOF-74 derived Mn-Co-Ni-O porous composite oxide for toluene efficient degradation. J. Hazard. Mater. 2020, 383, 121143.
Crossref Google Scholar
[10]

Solsona, B.; Garcia, T.; Aylón, E.; Dejoz, A. M.; Vázquez, I.; Agouram, S.; Davies, T. E.; Taylor, S. H. Promoting the activity and selectivity of high surface area Ni-Ce-O mixed oxides by gold deposition for VOC catalytic combustion. Chem. Eng. J. 2011, 175, 271–278.
Crossref Google Scholar
[11]

Wang, C.; Zhang, C. H.; Hua, W. C.; Guo, Y. L.; Lu, G. Z.; Gil, S.; Giroir-Fendler, A. Catalytic oxidation of vinyl chloride emissions over Co-Ce composite oxide catalysts. Chem. Eng. J. 2017, 315, 392–402.
Crossref Google Scholar
[12]

Wang, Y. F.; Zhang, C. B.; Yu, Y. B.; Yue, R. L.; He, H. Ordered mesoporous and bulk Co3O4 supported Pd catalysts for catalytic oxidation of o-xylene. Catal. Today 2015, 242, 294–299.
Crossref Google Scholar
[13]

Liu, Y. X.; Dai, H. X.; Deng, J. G.; Xie, S. H.; Yang, H. G.; Tan, W.; Han, W.; Jiang, Y.; Guo, G. S. Mesoporous Co3O4-supported gold nanocatalysts: Highly active for the oxidation of carbon monoxide, benzene, toluene, and o-xylene. J. Catal. 2014, 309, 408–418.
Crossref Google Scholar
[14]

Liotta, L. F.; Wu, H. J.; Pantaleo, G.; Venezia, A. M. Co3O4 nanocrystals and Co3O4-MOx binary oxides for CO, CH4 and VOC oxidation at low temperatures: A review. Catal. Sci. Technol. 2013, 3, 3085–3102.
Crossref Google Scholar
[15]

Li, J. J.; Xu, X. Y.; Hao, Z. P.; Zhao, W. Mesoporous silica supported cobalt oxide catalysts for catalytic removal of benzene. J. Porous Mater. 2008, 15, 163–169.
Crossref Google Scholar
[16]

Araújo, R. S.; Azevedo, D. C. S.; Rodríguez-Castellón, E.; Jiménez-López, A.; Cavalcante, C. Jr. Al and Ti-containing mesoporous molecular sieves: Synthesis, characterization and redox activity in the anthracene oxidation. J. Mol. Catal. A: Chem. 2008, 281, 154–163.
Crossref Google Scholar
[17]

Todorova, S.; Pârvulescu, V.; Kadinov, G.; Tenchev, K.; Somacescu, S.; Su, B. L. Metal states in cobalt-and cobalt-vanadium-modified MCM-41 mesoporous silica catalysts and their activity in selective hydrocarbons oxidation. Micropor. Mesopor. Mater. 2008, 113, 22–30.
Crossref Google Scholar
[18]

Szegedi, Á.; Popova, M.; Minchev, C. Catalytic activity of Co/MCM-41 and Co/SBA-15 materials in toluene oxidation. J. Mater. Sci. 2009, 44, 6710–6716.
Crossref Google Scholar
[19]

Kim, D. J.; Dunn, B. C.; Cole, P.; Turpin, G.; Ernst, R. D.; Pugmire, R. J.; Kang, M.; Kim, J. M.; Eyring, E. M. Enhancement in the reducibility of cobalt oxides on a mesoporous silica supported cobalt catalyst. Chem. Commun. 2005, 11, 1462–1464.
Crossref Google Scholar
[20]

Katsoulidis, A. P.; Petrakis, D. E.; Armatas, G. S.; Trikalitis, P. N.; Pomonis, P. J. Ordered mesoporous CoOx/MCM-41 materials exhibiting long-range self-organized nanostructured morphology. Micropor. Mesopor. Mater. 2006, 92, 71–80.
Crossref Google Scholar
[21]

Dong, F.; Han, W. G.; Han, W. L.; Tang, Z. C. Assembling core–shell SiO2@NiaCobOx nanotube decorated by hierarchical NiCo-phyllisilicate ultrathin nanosheets for highly efficient catalytic combustion of VOCs. Appl. Catal. B: Environ. 2022, 315, 121524.
Crossref Google Scholar
[22]

Xu, C. F.; Chen, G. X.; Zhao, Y.; Liu, P. X.; Duan, X. P.; Gu, L.; Fu, G.; Yuan, Y. Z.; Zheng, N. F. Interfacing with silica boosts the catalysis of copper. Nat. Commun. 2018, 9, 3367.
Crossref Google Scholar
[23]

Kong, X.; Zhu, Y. F.; Zheng, H. Y.; Li, X. Q.; Zhu, Y. L.; Li, Y. W. Ni nanoparticles inlaid nickel phyllosilicate as a metal–acid bifunctional catalyst for low-temperature hydrogenolysis reactions. ACS Catal. 2015, 5, 5914–5920.
Crossref Google Scholar
[24]

Kim, J. S.; Park, I.; Jeong, E. S.; Jin, K.; Seong, W. M.; Yoon, G.; Kim, H.; Kim, B.; Nam, K. T.; Kang, K. Amorphous cobalt phyllosilicate with layered crystalline motifs as water oxidation catalyst. Adv. Mater. 2017, 29, 1606893.
Crossref Google Scholar
[25]

Wen, M.; Dong, F.; Tang, Z. C.; Zhang, J. Y. In situ confined encapsulation strategy for construction of Co3O4@SiO2 catalyst for the efficient elimination of toluene. Micropor. Mesopor. Mater. 2021, 322, 111156.
Crossref Google Scholar
[26]

Mitchell, S.; Michels, N. L.; Kunze, K.; Pérez-Ramírez, J. Visualization of hierarchically structured zeolite bodies from macro to nano length scales. Nat. Chem. 2012, 4, 825–831.
Crossref Google Scholar
[27]

Freiding, J.; Kraushaar-Czarnetzki, B. Novel extruded fixed-bed MTO catalysts with high olefin selectivity and high resistance against coke deactivation. Appl. Catal. A: Gen. 2011, 391, 254–260.
Crossref Google Scholar
[28]

Williams, J. L. Monolith structures, materials, properties and uses. Catal. Today 2001, 69, 3–9.
Crossref Google Scholar
[29]

Díaz-Marta, A. S.; Tubío, C. R.; Carbajales, C.; Fernández, C.; Escalante, L.; Sotelo, E.; Guitián, F.; Barrio, V. L.; Gil, A.; Coelho, A. Three-dimensional printing in catalysis: Combining 3D heterogeneous copper and palladium catalysts for multicatalytic multicomponent reactions. ACS Catal. 2018, 8, 392–404.
Crossref Google Scholar
[30]
Crawley, M. L.; Trost, B. M. Applications of Transition Metal Catalysis in Drug Discovery and Development: An Industrial Perspective; John Wiley & Sons, Inc. : Hoboken, 2012.
Crossref
[31]

Ciriminna, R.; Carà, P. D.; Sciortino, M.; Pagliaro, M. Catalysis with doped sol-gel silicates. Adv. Synth. Catal. 2011, 353, 677–687.
Crossref Google Scholar
[32]

Xu, X.; Zhang, M. X.; Jiang, P.; Liu, D. S.; Wang, Y. X.; Xu, X.; Ji, Z. Y.; Jia, X.; Wang, H. Z.; Wang, X. L. Direct ink writing of Pd-decorated Al2O3 ceramic based catalytic reduction continuous flow reactor. Ceram. Int. 2022, 48, 10843–10851.
Crossref Google Scholar
[33]

Muth, J. T.; Dixon, P. G.; Woish, L.; Gibson, L. J.; Lewis, J. A. Architected cellular ceramics with tailored stiffness via direct foam writing. Proc. Natl. Acad. Sci. USA 2017, 114, 1832–1837.
Crossref Google Scholar
[34]

Liu, D. S.; Jiang, P.; Li, X. C.; Liu, J. X.; Zhou, L. C.; Wang, X. L.; Zhou, F. 3D printing of metal–organic frameworks decorated hierarchical porous ceramics for high-efficiency catalytic degradation. Chem. Eng. J. 2020, 397, 125392.
Crossref Google Scholar
[35]

Liu, M.; Sun, J. R.; Chen, Q. F. Influences of heating temperature on mechanical properties of polydimethylsiloxane. Sens. Actuators A: Phys. 2009, 151, 42–45.
Crossref Google Scholar
[36]

Quintanilla, A.; Casas, J. A.; Miranzo, P.; Osendi, M. I.; Belmonte, M. 3D-printed Fe-doped silicon carbide monolithic catalysts for wet peroxide oxidation processes. Appl. Catal. B: Environ. 2018, 235, 246–255.
Crossref Google Scholar
[37]

Mu, Z.; Li, J. J.; Tian, H.; Hao, Z. P.; Qiao, S. Z. Synthesis of mesoporous Co/Ce-SBA-15 materials and their catalytic performance in the catalytic oxidation of benzene. Mater. Res. Bull. 2008, 43, 2599–2606.
Crossref Google Scholar
[38]

Wang, X. Y.; Zuo, J. C.; Luo, Y. J.; Jiang, L. L. New route to CeO2/LaCoO3 with high oxygen mobility for total benzene oxidation. Appl. Surf. Sci. 2017, 396, 95–101.
Crossref Google Scholar
[39]

Zuo, S. F.; Liu, F. J.; Tong, J.; Qi, C. Z. Complete oxidation of benzene with cobalt oxide and ceria using the mesoporous support SBA-16. Appl. Catal. A: Gen. 2013, 467, 1–6.
Crossref Google Scholar
[40]

Han, D. W.; Xiao, M. L.; Wei, Y. C.; Yang, X. Q.; Guo, Y. C.; Ma, L. J.; Yu, X. L.; Ge, M. F. Enhanced sulfur resistance by constructing MnOx-Co3O4 interface on Ni foam in the removal of benzene. Environ. Sci.: Nano 2023, 10, 284–294.
Crossref Google Scholar
[41]

Xiang, Y.; Zhu, Y.; Lu, J.; Zhu, C. Z.; Zhu, M. Y.; Xie, Q. Q.; Chen, T. H. Co3O4/α-Fe2O3 catalyzed oxidative degradation of gaseous benzene: Preparation, characterization and its catalytic properties. Solid State Sci. 2019, 93, 79–86.
Crossref Google Scholar
[42]

Yao, J. F.; Dong, F.; Xu, X.; Wen, M.; Ji, Z. Y.; Feng, H.; Wang, X. L.; Tang, Z. C. Rational design and construction of monolithic ordered mesoporous Co3O4@SiO2 catalyst by a novel 3D printed technology for catalytic oxidation of toluene. ACS Appl. Mater. Interfaces 2022, 14, 22170–22185.
Crossref Google Scholar
[43]

Zhang, L.; Yang, J. W.; Wang, A. Q.; Chai, S. H.; Guan, J.; Nie, L. F.; Fan, G. J.; Han, N.; Chen, Y. F. High performance ozone decomposition spinel (Mn,Co)3O4 catalyst accelerating the rate-determining step. Appl. Catal. B: Environ. 2022, 303, 120927.
Crossref Google Scholar
[44]

Scott, S. L.; Gunnoe, T. B.; Fornasiero, P.; Crudden, C. M. To err is human; to reproduce takes time. ACS Catal. 2022, 12, 3644–3650.
Crossref Google Scholar
[45]

Lefevere, J.; Protasova, L.; Mullens, S.; Meynen, V. 3D-printing of hierarchical porous ZSM-5: The importance of the binder system. Mater. Des. 2017, 134, 331–341.
Crossref Google Scholar
[46]

Dong, F.; Han, W. G.; Guo, Y.; Han, W. L.; Tang, Z. C. CeCoOx-MNS catalyst derived from three-dimensional mesh nanosheet Co-based metal-organic frameworks for highly efficient catalytic combustion of VOCs. Chem. Eng. J. 2021, 405, 126948.
Crossref Google Scholar
[47]

Wang, H.; Chen, C. L.; Zhang, Y. X.; Peng, L. X.; Ma, S.; Yang, T.; Guo, H. H.; Zhang, Z. D.; Su, D. S.; Zhang, J. In situ oxidation of carbon-encapsulated cobalt nanocapsules creates highly active cobalt oxide catalysts for hydrocarbon combustion. Nat. Commun. 2015, 6, 7181.
Crossref Google Scholar
[48]

Sun, S. J.; Gao, Q. M.; Wang, H. L.; Zhu, J. K.; Guo, H. L. Influence of textural parameters on the catalytic behavior for CO oxidation over ordered mesoporous Co3O4. Appl. Catal. B: Environ. 2010, 97, 284–291.
Crossref Google Scholar
[49]

Díaz-Marta, A. S.; Yáñez, S.; Tubio, C. R.; Barrio, V. L.; Piñeiro, Y.; Pedrido, R.; Rivas, J.; Amorín, M.; Guitián, F.; Coelho, A. Multicatalysis combining 3D-printed devices and magnetic nanoparticles in one-pot reactions: Steps forward in compartmentation and recyclability of catalysts. ACS Appl. Mater. Interfaces 2019, 11, 25283–25294.
Crossref Google Scholar
[50]

Yang, Q. X.; Lu, R.; Ren, S. S.; Zhou, H. M.; Wu, Q. X.; Zhen, Y. Y.; Chen, Z. J.; Fang, S. M. Magnetic beads embedded in poly (sodium-p-styrenesulfonate) and ZIF-67: Removal of nitrophenol from water. J. Solid State Chem. 2018, 265, 200–207.
Crossref Google Scholar
[51]

Peng, M. W.; Shi, D. L.; Sun, Y. H.; Cheng, J.; Zhao, B.; Xie, Y. M.; Zhang, J. C.; Guo, W.; Jia, Z.; Liang, Z. Q. et al. 3D printed mechanically robust graphene/CNT electrodes for highly efficient overall water splitting. Adv. Mater. 2020, 32, 1908201.
Crossref Google Scholar
[52]

Ghasemzadeh, M. A.; Mirhosseini-Eshkevari, B.; Abdollahi-Basir, M. H. Rapid and efficient one-pot synthesis of 3,4-dihydroquinoxalin-2-amine derivatives catalyzed by Co3O4@SiO2 core−shell nanoparticles under ultrasound irradiation. Comb. Chem. High Throughput Screen. 2016, 19, 592–601.
Crossref Google Scholar
[53]

Kucharczyk, S.; Zajac, M.; Stabler, C.; Thomsen, R. M.; Haha, M. B.; Skibsted, J.; Deja, J. Structure and reactivity of synthetic CaO-Al2O3-SiO2 glasses. Cem. Concr. Res. 2019, 120, 77–91.
Crossref Google Scholar
[54]

Gu, F.; Li, C. Z.; Hu, Y. J.; Zhang, L. Synthesis and optical characterization of Co3O4 nanocrystals. J. Cryst. Growth 2007, 304, 369–373.
Crossref Google Scholar
[55]

Mamontov, E.; Egami, T.; Brezny, R.; Koranne, M.; Tyagi, S. Lattice defects and oxygen storage capacity of nanocrystalline ceria and ceria-zirconia. J. Phys. Chem. B 2000, 104, 11110–11116.
Crossref Google Scholar
[56]

Cheng, Q. P.; Tian, Y.; Lyu, S. S.; Zhao, N.; Ma, K.; Ding, T.; Jiang, Z.; Wang, L. H.; Zhang, J.; Zheng, L. R. et al. Confined small-sized cobalt catalysts stimulate carbon-chain growth reversely by modifying ASF law of Fischer–Tropsch synthesis. Nat. Commun. 2018, 9, 3250.
Crossref Google Scholar
[57]

Ward, M. R.; Boyes, E. D.; Gai, P. L. In situ aberration-corrected environmental TEM: Reduction of model Co3O4 in H2 at the atomic level. ChemCatChem 2013, 5, 2655–2661.
Crossref Google Scholar
[58]

Song, W. Q.; Poyraz, A. S.; Meng, Y. T.; Ren, Z.; Chen, S. Y.; Suib, S. L. Mesoporous Co3O4 with controlled porosity: Inverse micelle synthesis and high-performance catalytic CO oxidation at −60 °C. Chem. Mater. 2014, 26, 4629–4639.
Crossref Google Scholar
[59]

Subramanian, V.; Cheng, K.; Lancelot, C.; Heyte, S.; Paul, S.; Moldovan, S.; Ersen, O.; Marinova, M.; Ordomsky, V. V.; Khodakov, A. Y. Nanoreactors: An efficient tool to control the chain-length distribution in Fischer–Tropsch synthesis. ACS Catal. 2016, 6, 1785–1792.
Crossref Google Scholar
[60]

Sun, X. H.; Suarez, A. I. O.; Meijerink, M.; Van Deelen, T.; Ould-Chikh, S.; Zečević, J.; De Jong, K. P.; Kapteijn, F.; Gascon, J. Manufacture of highly loaded silica-supported cobalt Fischer–Tropsch catalysts from a metal organic framework. Nat. Commun. 2017, 8, 1680.
Crossref Google Scholar
[61]

Yan, N.; Chen, Q. W.; Wang, F.; Wang, Y.; Zhong, H.; Hu, L. High catalytic activity for CO oxidation of Co3O4 nanoparticles in SiO2 nanocapsules. J. Mater. Chem. A 2013, 1, 637–643.
Crossref Google Scholar
[62]

Li, B. F.; Wei, F.; Su, B.; Guo, Z.; Ding, Z. X.; Yang, M. Q.; Wang, S. B. Mesoporous cobalt tungstate nanoparticles for efficient and stable visible-light-driven photocatalytic CO2 reduction. Mater. Today Energy 2022, 24, 100943.
Crossref Google Scholar
[63]

Li, Q.; Odoom-Wubah, T.; Zhou, Y. P.; Mulka, R.; Zheng, Y. M.; Huang, J. L.; Sun, D. H.; Li, Q. B. Coral-like CoMnOx as a highly active catalyst for benzene catalytic oxidation. Ind. Eng. Chem. Res. 2019, 58, 2882–2890.
Crossref Google Scholar
[64]

Mo, S. P.; Zhang, Q.; Li, J. Q.; Sun, Y. H.; Ren, Q. M.; Zou, S. B.; Zhang, Q.; Lu, J. H.; Fu, M. L.; Mo, D. Q. et al. Highly efficient mesoporous MnO2 catalysts for the total toluene oxidation: Oxygen-vacancy defect engineering and involved intermediates using in situ DRIFTS. Appl. Catal. B: Environ. 2020, 264, 118464.
Crossref Google Scholar
[65]

Hu, Z.; Qiu, S.; You, Y.; Guo, Y.; Guo, Y. L.; Wang, L.; Zhan, W. C.; Lu, G. Z. Hydrothermal synthesis of NiCeOx nanosheets and its application to the total oxidation of propane. Appl. Catal. B: Environ. 2018, 225, 110–120.
Crossref Google Scholar
[66]

Ma, Y.; Wang, L.; Ma, J. Z.; Wang, H. H.; Zhang, C. B.; Deng, H.; He, H. Investigation into the enhanced catalytic oxidation of o-xylene over MOF-derived Co3O4 with different shapes: The role of surface twofold-coordinate lattice oxygen (O2f). ACS Catal. 2021, 11, 6614–6625.
Crossref Google Scholar
[67]

Soghrati, E.; Ong, T. K. C.; Poh, C. K.; Kawi, S.; Borgna, A. Zeolite-supported nickel phyllosilicate catalyst for C-O hydrogenolysis of cyclic ethers and polyols. Appl. Catal. B: Environ. 2018, 235, 130–142.
Crossref Google Scholar
[68]

Fang, J. X.; Huang, Z. W.; Wang, L. P.; Guo, S. F.; Li, M. X.; Liu, Y. C.; Chen, J. M.; Wu, X. M.; Shen, H. Z.; Zhao, H. W. et al. Activation of oxygen on the surface of the Co3O4 catalyst by single-atom Ag toward efficient catalytic benzene combustion. J. Phys. Chem. C 2022, 126, 5873–5884.
Crossref Google Scholar
[69]

Zhao, X. T.; Xu, D. J.; Wang, Y. N.; Zheng, Z. W.; Li, K.; Zhang, Y. R.; Zhan, R.; Lin, H. Electric field assisted benzene oxidation over Pt-Ce-Zr nano-catalysts at low temperature. J. Hazard. Mater. 2021, 407, 124349.
Crossref Google Scholar
[70]

Yang, K.; Liu, Y. X.; Deng, J. G.; Zhao, X. T.; Yang, J.; Han, Z.; Hou, Z. Q.; Dai, H. X. Three-dimensionally ordered mesoporous iron oxide-supported single-atom platinum: Highly active catalysts for benzene combustion. Appl. Catal. B: Environ. 2019, 244, 650–659.
Crossref Google Scholar
[71]

Hou, J. C.; Hu, J. L.; Chang, L. P.; Wang, J. C.; Zeng, Z. Q.; Wu, D. X.; Cui, X. M.; Bao, W. R.; Yao, J. X. Synergistic effects between highly dispersed CuOx and the surface Cu-[Ox]-Ce structure on the catalysis of benzene combustion. J. Catal. 2022, 408, 9–23.
Crossref Google Scholar
[72]

Lichtenberger, J.; Amiridis, M. D. Catalytic oxidation of chlorinated benzenes over V2O5/TiO2 catalysts. J. Catal. 2004, 223, 296–308.
Crossref Google Scholar
[73]

Li, L.; Yang, Q. L.; Wang, D.; Peng, Y.; Yan, J. L.; Li, J. H.; Crittenden, J. Facile synthesis λ-MnO2 spinel for highly effective catalytic oxidation of benzene. Chem. Eng. J. 2021, 421, 127828.
Crossref Google Scholar
[74]

Li, J. J.; Yu, E. Q.; Cai, S. C.; Chen, X.; Chen, J.; Jia, H. P.; Xu, Y. J. Noble metal free, CeO2/LaMnO3 hybrid achieving efficient photo-thermal catalytic decomposition of volatile organic compounds under IR light. Appl. Catal. B: Environ. 2019, 240, 141–152.
Crossref Google Scholar
[75]

Xue, L.; Zhang, C. B.; He, H.; Teraoka, Y. Catalytic decomposition of N2O over CeO2 promoted Co3O4 spinel catalyst. Appl. Catal. B: Environ. 2007, 75, 167–174.
Crossref Google Scholar
[76]

Liu, X. L.; Zeng, J. L.; Shi, W. B.; Wang, J.; Zhu, T. Y.; Chen, Y. F. Catalytic oxidation of benzene over ruthenium-cobalt bimetallic catalysts and study of its mechanism. Catal. Sci. Technol. 2017, 7, 213–221.
Crossref Google Scholar
[77]

Kang, S. Y.; Wang, M.; Zhu, N.; Wang, C. Y.; Deng, H.; He, H. Significant enhancement in water resistance of Pd/Al2O3 catalyst for benzene oxidation by Na addition. Chin. Chem. Lett. 2019, 30, 1450–1454.
Crossref Google Scholar
[78]

Odoom-Wubah, T.; Li, Q.; Adilov, I.; Huang, J. L.; Li, Q. B. Towards efficient Pd/Mn3O4 catalyst with enhanced acidic sites and low temperature reducibility for benzene abatement. Mol. Catal. 2019, 477, 110558.
Crossref Google Scholar
[79]

Zhong, J. P.; Zeng, Y. K.; Zhang, M. Y.; Feng, W. H.; Xiao, D. R.; Wu, J. L.; Chen, P. R.; Fu, M. L.; Ye, D. Q. Toluene oxidation process and proper mechanism over Co3O4 nanotubes: Investigation through in-situ DRIFTS combined with PTR-TOF-MS and quasi in-situ XPS. Chem. Eng. J. 2020, 397, 125375.
Crossref Google Scholar
Nano Research
Volume 16 Issue 10,
October 2023
Pages 12173-12185
DOI: 10.1007/s12274-023-5631-0
Cite this article:
Xi Y, Dong F, Xu X, et al. A novel 3D printed technology to construct a monolithic ultrathin nanosheets Co3O4/SiO2 catalyst for benzene catalytic combustion. Nano Research, 2023, 16(10): 12173-12185. https://doi.org/10.1007/s12274-023-5631-0
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Received: 17 January 2023
Revised: 23 February 2023
Accepted: 28 February 2023
Published: 18 May 2023
© Tsinghua University Press 2023
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