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Research Article

Perovskite films with gradient bandgap for self-powered multiband photodetectors and spectrometers

Chuantian Zuo1,11, Lixiu Zhang1, Xiyan Pan1, He Tian3, Keyou Yan4, Yuanhang Cheng5, Zhiwen Jin6, Chenyi Yi7, Xiaoliang Zhang8, Wu-Qiang Wu9, Qinye Bao2( ), Liyuan Han10, Liming Ding1( )
Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China
School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China
School of Integrated Circuits, Tsinghua University, Beijing 100084, China
School of Environment and Energy, South China University of Technology, Guangzhou 510000, China
School of New Energy, Nanjing University of Science and Technology, Jiangyin 214443, China
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China
State Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University, Beijing 100084, China
School of Materials Science and Engineering, Beihang University, Beijing 100191, China
School of Chemistry, Sun Yat-sen University, Guangzhou 510006, China
State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
Key Laboratory of Semiconductor Materials Science, Beijing Key Laboratory of Low Dimensional Semiconductor Materials and Devices, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
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Graphical Abstract

Perovskite films with gradient bandgap were made by using a facile solution interdiffusion method. Self-powered multiband photodetectors and spectrometers were fabricated by using the bandgap-graded perovskite films.

Abstract

Bandgap-graded materials present varying spectral responses at different positions, making them possible to be used as an alternative to photoactive materials array in multi-spectral responsive devices, thus miniaturizing the apparatus. However, the preparation of bandgap-graded materials usually requires complicated deposition process. Here we report a facile low-temperature solution process to make films with lateral bandgap gradients, which form spontaneously via self-spreading and interdiffusion of solutions. We show lead halide perovskite films with MAPbCl3-MAPbBr3 and MAPbBr3-MAPbI3 gradients, which exhibit light absorption onsets ranging from 410 to 781 nm. The bandgap-graded films were used to make self-powered multiband photodetectors, which show different spectral responses at different positions without applying bias voltage. Furthermore, self-powered spectrometers were made by using the multiband photodetectors.

Keywords

interdiffusionself-spreadingbandgap-graded perovskiteself-powered spectrometersmultiband photodetectors

Electronic Supplementary Material

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References

[1]

Fang, Y. J.; Dong, Q. F.; Shao, Y. C.; Yuan, Y. B.; Huang, J. S. Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination. Nat. Photonics 2015, 9, 679–686.
Crossref Google Scholar
[2]

Lin, Q. Q.; Armin, A.; Burn, P. L.; Meredith, P. Filterless narrowband visible photodetectors. Nat. Photonics 2015, 9, 687–694.
Crossref Google Scholar
[3]

Xu, X. B.; Dong, Y. H.; Zhang, Y. Z.; Han, Z. Y.; Liu, J. X.; Yu, D. J.; Wei, Y.; Zou, Y. S.; Huang, B.; Chen, J. et al. High-definition colorful perovskite narrowband photodetector array enabled by laser-direct-writing. Nano Res. 2022, 15, 5476–5482.
Crossref Google Scholar
[4]

Xie, B. M.; Xie, R. H.; Zhang, K.; Yin, Q. W.; Hu, Z. C.; Yu, G.; Huang, F.; Cao, Y. Self-filtering narrowband high performance organic photodetectors enabled by manipulating localized Frenkel exciton dissociation. Nat. Commun. 2020, 11, 2871.
Crossref Google Scholar
[5]

Li, K. H.; Lu, Y.; Yang, X. K.; Fu, L. C.; He, J. G.; Lin, X. T.; Zheng, J. J.; Lu, S. C.; Chen, C.; Tang, J. Filter-free self-power CdSe/Sb2(S1−x, Sex)3 nearinfrared narrowband detection and imaging. InfoMat 2021, 3, 1145–1153.
Crossref Google Scholar
[6]

Bao, J.; Bawendi, M. G. A colloidal quantum dot spectrometer. Nature 2015, 523, 67–70.
Crossref Google Scholar
[7]

Yuan, S. F.; Naveh, D.; Watanabe, K.; Taniguchi, T.; Xia, F. N. A wavelength-scale black phosphorus spectrometer. Nat. Photonics 2021, 15, 601–607.
Crossref Google Scholar
[8]

Zhu, X. X.; Bian, L. H.; Fu, H.; Wang, L. X.; Zou, B. S.; Dai, Q. H.; Zhang, J.; Zhong, H. Z. Broadband perovskite quantum dot spectrometer beyond human visual resolution. Light Sci. Appl. 2020, 9, 73.
Crossref Google Scholar
[9]

Sobhani, A.; Knight, M. W.; Wang, Y. M.; Zheng, B.; King, N. S.; Brown, L. V.; Fang, Z. Y.; Nordlander, P.; Halas, N. J. Narrowband photodetection in the near-infrared with a plasmon-induced hot electron device. Nat. Commun. 2013, 4, 1643.
Crossref Google Scholar
[10]

Xue, J.; Zhu, Z. F.; Xu, X. B.; Gu, Y.; Wang, S. L.; Xu, L. M.; Zou, Y. S.; Song, J. Z.; Zeng, H. B.; Chen, Q. Narrowband perovskite photodetector-based image array for potential application in artificial vision. Nano Lett. 2018, 18, 7628–7634.
Crossref Google Scholar
[11]

Wang, J.; Xiao, S.; Qian, W.; Zhang, K.; Yu, J.; Xu, X. W.; Wang, G. P.; Zheng, S. Z.; Yang, S. H. Self-driven perovskite narrowband photodetectors with tunable spectral responses. Adv. Mater. 2021, 33, 2005557.
Crossref Google Scholar
[12]

Yang, Z. Y.; Albrow-Owen, T.; Cai, W. W.; Hasan, T. Miniaturization of optical spectrometers. Science 2021, 371, eabe0722.
Crossref Google Scholar
[13]

Hagen, N. A.; Kudenov, M. W. Review of snapshot spectral imaging technologies. Opt. Eng. 2013, 52, 090901.
Crossref Google Scholar
[14]

Ning, C. Z.; Dou, L. T.; Yang, P. D. Bandgap engineering in semiconductor alloy nanomaterials with widely tunable compositions. Nat. Rev. Mater. 2017, 2, 17070.
Crossref Google Scholar
[15]

Xu, H.; Zhu, J. T.; Zou, G. F.; Liu, W.; Li, X.; Li, C. H.; Ryu, G. H.; Xu, W. S.; Han, X. Y.; Guo, Z. X. et al. Spatially bandgap-graded MoS2(1−x)Se2x homojunctions for self-powered visible-near-infrared phototransistors. Nano-Micro Lett. 2020, 12, 26.
Crossref Google Scholar
[16]

Huang, L.; Gao, Q. G.; Sun, L. D.; Dong, H.; Shi, S.; Cai, T.; Liao, Q.; Yan, C. H. Composition-graded cesium lead halide perovskite nanowires with tunable dual-color lasing performance. Adv. Mater. 2018, 30, 1800596.
Crossref Google Scholar
[17]

Lei, Y. S.; Chen, Y. M.; Zhang, R. Q.; Li, Y. H.; Yan, Q. Z.; Lee, S.; Yu, Y. G.; Tsai, H.; Choi, W.; Wang, K. P. et al. A fabrication process for flexible single-crystal perovskite devices. Nature 2020, 583, 790–795.
Crossref Google Scholar
[18]

Gu, F. X.; Yang, Z. Y.; Yu, H. K.; Xu, J. Y.; Wang, P.; Tong, L. M.; Pan, A. L. Spatial bandgap engineering along single alloy nanowires. J. Am. Chem. Soc. 2011, 133, 2037–2039.
Crossref Google Scholar
[19]

Zhuang, X. J.; Ning, C. Z.; Pan, A. L. Composition and bandgap-graded semiconductor alloy nanowires. Adv. Mater. 2012, 24, 13–33.
Crossref Google Scholar
[20]

Yang, Z. Y.; Albrow-Owen, T.; Cui, H. X.; Alexander-Webber, J.; Gu, F. X.; Wang, X. M.; Wu, T. C.; Zhuge, M. H.; Williams, C.; Wang, P. et al. Single-nanowire spectrometers. Science 2019, 365, 1017–1020.
Crossref Google Scholar
[21]

Dunlap-Shohl, W. A.; Zhou, Y. Y.; Padture, N. P.; Mitzi, D. B. Synthetic approaches for halide perovskite thin films. Chem. Rev. 2019, 119, 3193–3295.
Crossref Google Scholar
[22]

Jiang, Q.; Zhao, Y.; Zhang, X. W.; Yang, X. L.; Chen, Y.; Chu, Z. M.; Ye, Q. F.; Li, X. X.; Yin, Z. G.; You, J. B. Surface passivation of perovskite film for efficient solar cells. Nat. Photonics 2019, 13, 460–466.
Crossref Google Scholar
[23]

Bian, H.; Bai, D. L.; Jin, Z. W.; Wang, K.; Liang, L.; Wang, H. R.; Zhang, J. R.; Wang, Q.; Liu, S. Z. Graded bandgap CsPbI2+xBr1−x perovskite solar cells with a stabilized efficiency of 14.4%. Joule 2018, 2, 1500–1510.
Crossref Google Scholar
[24]

Zuo, C. T.; Scully, A. D.; Vak, D.; Tan, W. L.; Jiao, X. C.; McNeill, C. R.; Angmo, D.; Ding, L. M.; Gao, M. Self-assembled 2D perovskite layers for efficient printable solar cells. Adv. Energy Mater. 2019, 9, 1803258.
Crossref Google Scholar
[25]

Zuo, C. T.; Ding, L. M. Drop-casting to make efficient perovskite solar cells under high humidity. Angew. Chem., Int. Ed. 2021, 60, 11242–11246.
Crossref Google Scholar
[26]

Liu, L.; Zuo, C. T.; Ding, L. M. Self-spreading produces highly efficient perovskite solar cells. Nano Energy 2021, 90, 106509.
Crossref Google Scholar
[27]

Xiao, H. R.; Zuo, C. T.; Zhang, L. X.; Zhang, W. H.; Hao, F.; Yi, C. Y.; Liu, F. Y.; Jin, H. L.; Ding, L. M. Efficient inorganic perovskite solar cells made by drop-coating in ambient air. Nano Energy 2023, 106, 108061.
Crossref Google Scholar
[28]

Liu, L.; Xiao, H. R.; Jin, K.; Xiao, Z.; Du, X. Y.; Yan, K. Y.; Hao, F.; Bao, Q. Y.; Yi, C. Y.; Liu, F. Y. et al. 4-Terminal inorganic perovskite/organic tandem solar cells offer 22% efficiency. Nano-Micro Lett. 2023, 5, 23.
Crossref Google Scholar
[29]

Zuo, C. T.; Scully, A. D.; Gao, M. Drop-casting method to screen ruddlesden-popper perovskite formulations for use in solar cells. ACS Appl. Mater. Interfaces 2021, 13, 56217–56225.
Crossref Google Scholar
[30]

Zhang, L. X.; Zuo, C. T.; Ding, L. M. Efficient MAPbI3 solar cells made via drop-coating at room temperature. J. Semicond. 2021, 42, 072201.
Crossref Google Scholar
[31]

Liu, D. Y.; Yang, C. C.; Lunt, R. R. Halide perovskites for selective ultraviolet-harvesting transparent photovoltaics. Joule 2018, 2, 1827–1837.
Crossref Google Scholar
[32]

Noh, J. H.; Im, S. H.; Heo, J. H.; Mandal, T. N.; Seok, S. I. Chemical management for colorful, efficient, and stable inorganic–organic hybrid nanostructured solar cells. Nano Lett. 2013, 13, 1764–1769.
Crossref Google Scholar
[33]

Liu, T. H.; Chen, K.; Hu, Q.; Zhu, R.; Gong, Q. H. Inverted perovskite solar cells: Progresses and perspectives. Adv. Energy Mater. 2016, 6, 1600457.
Crossref Google Scholar
[34]

Wang, S. R.; Guo, H. X.; Wu, Y. Z. Advantages and challenges of self-assembled monolayer as a hole-selective contact for perovskite solar cells. Mater. Futures 2023, 2, 012105.
Crossref Google Scholar
[35]

Mahajan, P.; Padha, B.; Verma, S.; Gupta, V.; Datt, R.; Tsoi, W. C.; Satapathi, S.; Arya, S. Review of current progress in hole-transporting materials for perovskite solar cells. J. Energy Chem. 2022, 68, 330–386.
Crossref Google Scholar
Nano Research
Volume 16 Issue 7,
July 2023
Pages 10256-10262
DOI: 10.1007/s12274-023-5714-y
Cite this article:
Zuo C, Zhang L, Pan X, et al. Perovskite films with gradient bandgap for self-powered multiband photodetectors and spectrometers. Nano Research, 2023, 16(7): 10256-10262. https://doi.org/10.1007/s12274-023-5714-y
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Received: 06 February 2023
Revised: 28 March 2023
Accepted: 05 April 2023
Published: 29 April 2023
© Tsinghua University Press 2023
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