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Review Article

Recent advances in bimetallic metal-organic frameworks and their derivatives for thermal catalysis

Fengbin Zheng1,2, Tian Lin2,3, Kun Wang1,2, Yinglong Wang1( ), Guodong Li2,4( )
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
School of Chemical Science, University of Chinese Academy of Sciences, Beijing 100049, China
School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China
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Graphical Abstract

This review summarizes the synthesis strategies and characterization of bimetallic metal-organic frameworks (MOFs) and their derivatives, discusses their applications in thermal catalysis, and proposes the potential challenges and prospects of bimetallic MOF based nanocatalysts.

Abstract

Compared with monometallic metal-organic frameworks (MOFs) that are synthesized by reacting inorganic metal ions or clusters with bidentate or multidentate ligands via hydrothermal or solvothermal methods, the construction of heterogeneous frameworks like at least two kinds of metal sites in the individual nodes is proved to be an effective way to modulate their properties for advanced catalysis, especially for selective catalysis and multifunctional catalysis. However, it is still very challenging to precisely characterize their microstructures and reveal the relationship among the composition, structure, and their performances. Therefore, it is necessary to summarize the recent progress on bimetallic MOFs for thermal catalysis. First, we summarize the synthesis strategies and characterization methods of bimetallic MOFs and their derivatives. Second, the application of bimetallic MOFs and their derivatives as catalysts in thermal catalysis is discussed, and the relationship among the active components, structures, and their properties is elucidated. Third, the potential challenges and prospects of bimetallic MOF based nanocatalysts are proposed. This review will bring some insights into the design and preparation of bimetallic MOFs based nanocatalysts in the future.

Keywords

metal-organic frameworksbimetallic metal nodessynthesis methodsfunction synergyheterogeneous catalysis

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Nano Research
Volume 16 Issue 12,
December 2023
Pages 12919-12935
DOI: 10.1007/s12274-023-5935-0
Cite this article:
Zheng F, Lin T, Wang K, et al. Recent advances in bimetallic metal-organic frameworks and their derivatives for thermal catalysis. Nano Research, 2023, 16(12): 12919-12935. https://doi.org/10.1007/s12274-023-5935-0
Topics:
Nanocatalysts
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Special issue for the 20th Anniversary of NCNST

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Received: 04 May 2023
Revised: 13 June 2023
Accepted: 14 June 2023
Published: 08 August 2023
© Tsinghua University Press 2023
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