AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Lithium-aluminum layered double hydroxides (LiAl-LDH) have been be successfully applied in commercial-scale for lithium extraction from salt lake brine, however, further advancement of their applications is hampered by suboptimal Li+ adsorption performance and ambiguous extraction process. Herein, a doping engineering strategy was developed to fabricate novel Zn2+-doped LiAl-LDH (LiZnAl-LDH) with remarkable higher Li+ adsorption capacity (13.4 mg/g) and selectivity (separation factors of 213, 834, 171 for Li+/K+, Li+/Na+, Li+/Mg2+, respectively), as well as lossless reusability in Luobupo brine compared to the pristine LiAl-LDH. Further, combining experiments and simulation calculations, it was revealed that the specific surface area, hydrophilic, and surface attraction for Li+ of LiZnAl-LDH were significantly improved, reducing the adsorption energy (Ead) and Gibbs free energy (ΔG), thus facilitating the transfer of Li+ from brine into interface followed by insertion into voids. Importantly, the intrinsic oxygen vacancies derived from Zn-doping depressed the diffusion energy barrier of Li+, which accelerated the diffusion process of Li+ in the internal bulk of LiZnAl-LDH. This work provides a general strategy to overcome the existing limitations of Li+ recovery and deepens the understanding of Li+ extraction on LiAl-LDH.
Xu, S. S.; Song, J. F.; Bi, Q. Y.; Chen, Q.; Zhang, W. M.; Qian, Z. X.; Zhang, L.; Xu, S. A.; Tang, N.; He, T. Extraction of lithium from Chinese salt-lake brines by membranes: Design and practice. J. Membr. Sci. 2021, 635, 119441.
Yang, S. X.; Zhang, F.; Ding, H. P.; He, P.; Zhou, H. S. Lithium metal extraction from seawater. Joule 2018, 2, 1648–1651.
Hou, L.; Xing, B. L.; Zeng, H. H.; Kang, W. W.; Guo, H.; Cheng, S.; Huang, G. X.; Cao, Y. J.; Chen, Z. F.; Zhang, C. X. Aluminothermic reduction synthesis of Si/C composite nanosheets from waste vermiculite as high-performance anode materials for lithium-ion batteries. J. Alloys Compd. 2022, 922, 166134.
Wu, L.; Zhang, C. Y.; Kim, S.; Hatton, T. A.; Mo, H. L.; Waite, T. D. Lithium recovery using electrochemical technologies: Advances and challenges. Water Res. 2022, 221, 118822.
Sun, X.; Ouyang, M. G.; Hao, H. Surging lithium price will not impede the electric vehicle boom. Joule 2022, 6, 1738–1742.
Chen, J.; Lin, S.; Yu, J. G. High-selective cyclic adsorption and magnetic recovery performance of magnetic lithium-aluminum layered double hydroxides (MLDHs) in extracting Li+ from ultrahigh Mg/Li ratio brines. Sep. Purif. Technol. 2021, 255, 117710.
Zhang, T. T.; Bai, H. Y.; Zhao, Y. L.; Ren, B.; Wen, T.; Chen, L. C.; Song, S. X.; Komarneni, S. Precise cation recognition in two-dimensional nanofluidic channels of clay membranes imparted from intrinsic selectivity of clays. ACS Nano 2022, 16, 4930–4939.
Zhao, X. Y.; Yang, S.; Hou, Y. D.; Gao, H. Q.; Wang, Y. F.; Gribble, D. A.; Pol, V. G. Recent progress on key materials and technical approaches for electrochemical lithium extraction processes. Desalination 2023, 546, 116189.
Baudino, L.; Santos, C.; Pirri, C. F.; La Mantia, F.; Lamberti, A. Recent advances in the lithium recovery from water resources: From passive to electrochemical methods. Adv. Sci. 2022, 9, 2201380.
Sun, Y.; Wang, Q.; Wang, Y. H.; Yun, R. P.; Xiang, X. Recent advances in magnesium/lithium separation and lithium extraction technologies from salt lake brine. Sep. Purif. Technol. 2021, 256, 117807.
Miao, J.; Zhao, K. Y.; Guo, F.; Xu, L. N.; Xie, Y. C.; Deng, T. L. Novel LIS-doped mixed matrix membrane absorbent with high structural stability for sustainable lithium recovery from geothermal water. Desalination 2022, 527, 115570.
Safari, S.; Lottermoser, B. G.; Alessi, D. S. Metal oxide sorbents for the sustainable recovery of lithium from unconventional resources. Appl. Mater. Today 2020, 19, 100638.
Xu, X.; Chen, Y. M.; Wan, P. Y.; Gasem, K.; Wang, K. Y.; He, T.; Adidharma, H.; Fan, M. H. Extraction of lithium with functionalized lithium ion-sieves. Prog. Mater. Sci. 2016, 84, 276–313.
Chen, J.; Lin, S.; Yu, J. G. Quantitative effects of Fe3O4 nanoparticle content on Li+ adsorption and magnetic recovery performances of magnetic lithium-aluminum layered double hydroxides in ultrahigh Mg/Li ratio brines. J. Hazard. Mater. 2020, 388, 122101.
Yu, H. W.; Naidu, G.; Zhang, C. Y.; Wang, C.; Razmjou, A.; Han, D. S.; He, T.; Shon, H. Metal-based adsorbents for lithium recovery from aqueous resources. Desalination 2022, 539, 115951.
Zhang, Y. B.; Liu, J. C.; Yang, Y.; Lin, S.; Li, P. Preparation of granular titanium-type lithium-ion sieves and recyclability assessment for lithium recovery from brines with different pH value. Sep. Purif. Technol. 2021, 267, 118613.
Zhao, K. Y.; Tong, B. J.; Yu, X. P.; Guo, Y. F.; Xie, Y. C.; Deng, T. L. Synthesis of porous fiber-supported lithium ion-sieve adsorbent for lithium recovery from geothermal water. Chem. Eng. J. 2022, 430, 131423.
Bao, L. R.; Zhang, J. Z.; Tang, W. P.; Sun, S. Y. Synthesis and adsorption properties of metal oxide-coated lithium ion-sieve from salt lake brine. Desalination 2023, 546, 116196.
Dong, M. Z.; Luo, Q. L.; Li, J.; Wu, Z. J.; Liu, Z. Lithium adsorption properties of porous LiAl-layered double hydroxides synthesized using surfactants. J. Saudi Chem. Soc. 2022, 26, 101535.
Lin, S.; Pan, Y. N.; Du, J. L.; Yang, Y.; Su, H. P.; Yu, J. G. Double-edged role of interlayer water on Li+ extraction from ultrahigh Mg2+/Li+ ratio brines using Li/Al-LDHs. J. Colloid Interface Sci. 2022, 627, 872–879.
Wu, L. L.; Evans, S. F.; Cheng, Y. Q.; Navrotsky, A.; Moyer, B. A.; Harrison, S.; Paranthaman, M. P. Neutron spectroscopic and thermochemical characterization of lithium-aluminum-layered double hydroxide chloride: Implications for lithium recovery. J. Phys. Chem. C 2019, 123, 20723–20729.
Luo, Q. L.; Dong, M. Z.; Li, Q.; Wu, Z. J.; Liu, Z.; Li, J. Improve the durability of lithium adsorbent Li/Al-LDHs by Fe3+ substitution and nanocomposite of FeOOH. Miner. Eng. 2022, 185, 107717.
Paranthaman, M. P.; Li, L.; Luo, J. Q.; Hoke, T.; Ucar, H.; Moyer, B. A.; Harrison, S. Recovery of lithium from geothermal brine with lithium-aluminum layered double hydroxide chloride sorbents. Environ. Sci. Technol. 2017, 51, 13481–13486.
Xiao, W.; Jiang, X. P.; Liu, X.; Zhou, W. M.; Garba, Z. N.; Lawan, I.; Wang, L. W.; Yuan, Z. H. Adsorption of organic dyes from wastewater by metal-doped porous carbon materials. J. Cleaner Prod. 2021, 284, 124773.
Ma, Z.; Shi, W.; Yan, K.; Pan, L. J.; Yu, G. H. Doping engineering of conductive polymer hydrogels and their application in advanced sensor technologies. Chem. Sci. 2019, 10, 6232–6244.
Zhang, L. J.; Ke, Z. S.; Wang, W. Z.; Liu, H. L.; Mao, Y. T.; Xiang, M. X.; Zhang, P. Enhanced removal of multiple metal ions on S-doped graphene-like carbon-supported layered double oxide: Mechanism and DFT study. Sep. Purif. Technol. 2022, 288, 120636.
Zhang, L. J.; Zheng, S. Y.; Li, P.; Zhu, Z. B.; Zou, Y. Q.; Zhang, P. Resource utilization of organic spent adsorbent to prepare three-dimensional sulfate-functionalized layered double oxide for superior removal of azo dye. Environ. Sci. Pollut. Res. 2021, 28, 53021–53033.
Wu, J.; Yang, B. Q.; Song, S. X.; Quintana, M.; Jia, F. F.; Tian, X. The efficient recovery of molybdenite fines using a novel collector: Flotation performances, adsorption mechanism and DFT calculation. Miner. Eng. 2022, 188, 107848.
Jiang, M. X.; Hu, Y. J.; Mao, B. G.; Wang, Y. X.; Yang, Z.; Meng, T.; Wang, X.; Cao, M. H. Strain-regulated Gibbs free energy enables reversible redox chemistry of chalcogenides for sodium ion batteries. Nat. Commun. 2022, 13, 5588.
Sun, D.; Ye, D. L.; Liu, P.; Tang, Y. G.; Guo, J.; Wang, L. Z.; Wang, H. Y. MoS2/graphene nanosheets from commercial bulky MoS2 and graphite as anode materials for high rate sodium-ion batteries. Adv. Energy Mater. 2018, 8, 1702383.
Qian, F. R.; Guo, M.; Qian, Z. Q.; Zhao, B.; Li, J.; Wu, Z. J.; Liu, Z. Enabling highly structure stability and adsorption performances of Li1.6Mn1.6O4 by Al-gradient surface doping. Sep. Purif. Technol. 2021, 264, 118433.
Li, Y. Y.; Tang, N.; Zhang, L.; Li, J. Fabrication of Fe-doped lithium-aluminum-layered hydroxide chloride with enhanced reusable stability inspired by computational theory and its application in lithium extraction. Colloids Surf. A Physicochem. Eng. Aspects 2023, 658, 130641.
Graham, T. R.; Hu, J. Z.; Zhang, X.; Dembowski, M.; Jaegers, N. R.; Wan, C.; Bowden, M.; Lipton, A. S.; Felmy, A. R.; Clark, S. B. et al. Unraveling gibbsite transformation pathways into LiAl-LDH in concentrated lithium hydroxide. Inorg. Chem. 2019, 58, 12385–12394.
Khan, A. I.; O’Hare, D. Intercalation chemistry of layered double hydroxides: Recent developments and applications. J. Mater. Chem. 2002, 12, 3191–3198.
Zhang, X.; Yi, H.; Jin, M. T.; Lian, Q.; Huang, Y.; Ai, Z.; Huang, R. Q.; Zuo, Z. T.; Tang, C. M.; Amini, A. et al. In situ reconstructed Zn doped FexNi(1−x)OOH catalyst for efficient and ultrastable oxygen evolution reaction at high current densities. Small 2022, 18, 2203710.
Pu, X. H.; Du, X. H.; Jing, P.; Wei, Y. H.; Wang, G. C.; Xian, C. X.; Wu, K. P.; Wu, H.; Wang, Q.; Ji, X. B. et al. Interface and defect engineering enable fast and high-efficiency Li extraction of metatitanic acid adsorbent. Chem. Eng. J. 2021, 425, 130550.
Keyikoglu, R.; Khataee, A.; Lin, H. J.; Orooji, Y. Vanadium (V)-doped ZnFe layered double hydroxide for enhanced sonocatalytic degradation of pymetrozine. Chem. Eng. J. 2022, 434, 134730.
Zhou, S. Y.; Guo, X. J.; Yan, X.; Chen, Y.; Lang, W. Z. Zr-doped titanium lithium ion sieve and EP-granulated composite: Superb adsorption and recycling performance. Particuology 2022, 69, 100–110.
Cao, G. F.; Yang, X. Y.; Yin, Z. L.; Lei, Y. T.; Wang, H.; Li, J. S. Synthesis, adsorption properties and stability of Cr-doped lithium ion sieve in salt lake brine. Bull. Chem. Soc. Jpn. 2019, 92, 1205–1210.
Hou, L.; Xing, B. L.; Kang, W. W.; Zeng, H. H.; Guo, H.; Cheng, S.; Huang, G. X.; Cao, Y. J.; Chen, Z. F.; Zhang, C. X. Aluminothermic reduction synthesis of porous silicon nanosheets from vermiculite as high-performance anode materials for lithium-ion batteries. Appl. Clay Sci. 2022, 218, 106418.
Zhitova, E. S.; Pekov, I. V.; Chaikovskiy, I. I.; Chirkova, E. P.; Yapaskurt, V. O.; Bychkova, Y. V.; Belakovskiy, D. I.; Chukanov, N. V.; Zubkova, N. V.; Krivovichev, S. V. et al. Dritsite, Li2Al4(OH)12Cl2·3H2O, a new gibbsite-based hydrotalcite supergroup mineral. Minerals 2019, 9, 492.
Luo, D. Z.; Yang, B. P.; Mei, Z. W.; Kang, Q.; Chen, G.; Liu, X. H.; Zhang, N. Tuning the d-band states of Ni-based serpentine materials via Fe3+ doping for efficient oxygen evolution reaction. ACS Appl. Mater. Interfaces 2022, 14, 52857–52867.
Li, Q. N.; Liang, W. Y.; Liu, F.; Wang, G. H.; Wan, J.; Zhang, W.; Peng, C.; Yang, J. Simultaneous immobilization of arsenic, lead and cadmium by magnesium-aluminum modified biochar in mining soil. J. Environ. Manage. 2022, 310, 114792.
Lan, T.; Li, P. F.; Rehman, F. U.; Li, X. L.; Yang, W.; Guo, S. W. Efficient adsorption of Cd2+ from aqueous solution using metakaolin geopolymers. Environ. Sci. Pollut. Res. 2019, 26, 33555–33567.
Ding, Y. M.; Wang, Z.; Zhang, Z. Y.; Zhao, Y. C.; Yang, S. Y.; Zhang, Y. L.; Yao, S. C.; Wang, S. B.; Huang, T.; Zhang, Y. et al. Oxygen vacancy-engineered BaTiO3 nanoparticles for synergistic cancer photothermal, photodynamic, and catalytic therapy. Nano Res. 2022, 15, 7304–7312.
Li, X. W.; Chao, Y. H.; Chen, L. L.; Chen, W.; Luo, J.; Wang, C.; Wu, P. W.; Li, H. M.; Zhu, W. S. Taming wettability of lithium ion sieve via different TiO2 precursors for effective Li recovery from aqueous lithium resources. Chem. Eng. J. 2020, 392, 123731.
Zhang, P.; Zhang, L. J.; Ke, Z. S.; Xiang, M. X.; Cai, Y.; Wang, W. J.; Chen, Y. N.; Zhu, Z. B. Sulfate-loaded layered double oxide: A bifunctional adsorbent for simultaneous purification of metal ion and anionic dye. Appl. Clay Sci. 2022, 216, 106366.
Lu, Z.; Wu, Y.; Ding, L.; Wei, Y. Y.; Wang, H. H. A lamellar MXene (Ti3C2Tx)/PSS composite membrane for fast and selective lithium-ion separation. Angew. Chem. 2021, 133, 22439–22443.
Ding, K. Y.; Zhu, G. R.; Song, C. H.; Wang, Q.; Wang, L.; Wang, Z. Q.; Meng, C. X.; Gao, C. J. Fabrication of polyacrylonitrile-Li1.6Mn1.6O4 composite nanofiber flat-sheet membranes via electrospinning method as effective adsorbents for Li+ recovery from salt-lake brine. Sep. Purif. Technol. 2022, 284, 120242.
Persson, I. Hydrated metal ions in aqueous solution: How regular are their structures. Pure Appl. Chem. 2010, 82, 1901–1917.
Lin, J.; Zeng, C. H.; Lin, X. M.; Xu, C.; Xu, X.; Luo, Y. F. Metal-organic framework-derived hierarchical MnO/Co with oxygen vacancies toward elevated-temperature Li-Ion battery. ACS Nano 2021, 15, 4594–4607.
