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Review Article

Self-healing Ga-based liquid metal/alloy anodes for rechargeable batteries

School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212000, China
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jingshi Road 17923, Jinan 250061, China
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Graphical Abstract

This review focuses on the properties, applications, and key issues of liquid Ga-based metal/alloys as main anode and composite anode materials for batteries.

Abstract

With the rapid development of electronics, electric vehicles, and grid energy storage stations, higher requirements have been put forward for advanced secondary batteries. Liquid metal/alloy electrodes have been considered as a promising development direction to achieve excellent electrochemical performance in metal-ion batteries, due to their specific advantages including the excellent electrode kinetics and self-healing ability against microstructural electrode damage. For conventional liquid batteries, high temperatures are needed to keep electrode liquid and ensure the high conductivity of molten salt electrolytes, which also brings the corrosion and safety issues. Ga-based metal/alloys, which can be operated at or near room temperature, are potential candidates to circumvent the above problems. In this review, the properties and advantages of Ga-based metal/alloys are summarized. Then, Ga-based liquid metal/alloys as anodes in various metal-ion batteries are reviewed in terms of their self-healing ability, battery configurations, working mechanisms, and so on. Furthermore, some views on the future development of Ga-based electrodes in batteries are provided.

Keywords

metal-ion batteriesGa-based liquid metal/alloy anodesself-healing capabilityroom temperature

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12274_2023_5955_MOESM1_ESM.pdf (1.8 MB)

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Nano Research
Volume 17 Issue 3,
March 2024
Pages 1366-1383
DOI: 10.1007/s12274-023-5955-9
Cite this article:
Song M, Zhang Z. Self-healing Ga-based liquid metal/alloy anodes for rechargeable batteries. Nano Research, 2024, 17(3): 1366-1383. https://doi.org/10.1007/s12274-023-5955-9
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Received: 23 April 2023
Revised: 06 June 2023
Accepted: 23 June 2023
Published: 31 July 2023
© Tsinghua University Press 2023
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