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Research Article

Mace-like TTF-TCNQ/HKUST-1 composite structures for rapid NO2 detection: Synergistically induced ultrahigh sensitivity and outstanding selectivity

Chaoxin Lin1,2,§, Kumchol Kim1,2,§, Zuochao Wang1,3, Zhuang Yan1,2, Zhiyong Tang1,2, Yaling Liu1,2( )
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

§ Chaoxin Lin and Kumchol Kim contributed equally to this work.

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Graphical Abstract

The mace-like tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ)/HKUST-1 composite structures with single single-crystalline TTF-TCNQ submicrorods covered by ordered HKUST-1 nanosheet arrays were constructed by an efficient TTF-TCNQ seed-mediated growth approach. Impressively, such TTF-TCNQ/HKUST-1-based sensors exhibit ultrahigh sensitivity, outstanding selectivity, good reproducibility, and rapid response for NO2 detection at room temperature owing to integration and synergy of the unique functions of TTF-TCNQ and HKUST-1.

Abstract

Integration and synergy of the unique functions of different components have been developed into one of the most convenient and effective ways to construct the composite advanced materials with collective properties and improved performances. In this work, the mace-like tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ)/HKUST-1 composite structures with single single-crystalline TTF-TCNQ submicrorods covered by ordered HKUST-1 nanosheet arrays were successfully constructed by an efficient TTF-TCNQ seed-mediated growth approach. Impressively, thanks to the synergetic and complementary effects between TTF-TCNQ and HKUST-1, the sensors based on such mace-like TTF-TCNQ/HKUST-1 composite structures not only displayed an experimental detection limit of 10 part per billion (ppb) for NO2 detection, but also exhibited outstanding selectivity even if the concentration of the interfering gases was 10 times that of NO2. Meanwhile, good reproducibility and rapid response were also achieved. This work opens the avenue for creation of novel high-performance sensing materials for application in gas sensing.

Keywords

tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ)/HKUST-1integration and synergyNO2 detectionexcellent sensing performance

Electronic Supplementary Material

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References

[1]

Guan, W. J.; Zheng, X. Y.; Chung, K. F.; Zhong, N. S. Impact of air pollution on the burden of chronic respiratory diseases in China: Time for urgent action. Lancet 2016, 388, 1939–1951.
Crossref Google Scholar
[2]

Kampa, M.; Castanas, E. Human health effects of air pollution. Environ. Pollut. 2008, 151, 362–367.
Crossref Google Scholar
[3]

Kwon, Y. J.; Kang, S. Y.; Wu, P.; Peng, Y.; Kim, S. S.; Kim, H. W. Selective improvement of NO2 gas sensing behavior in SnO2 nanowires by ion-beam irradiation. ACS Appl. Mater. Interfaces 2016, 8, 13646–13658.
Crossref Google Scholar
[4]

Zhang, D. H.; Liu, Z. Q.; Li, C.; Tang, T.; Liu, X. L.; Han, S.; Lei, B.; Zhou, C. W. Detection of NO2 down to ppb levels using individual and multiple In2O3 nanowire devices. Nano Lett. 2004, 4, 1919–1924.
Crossref Google Scholar
[5]

Miller, D. R.; Akbar, S. A.; Morris, P. A. Nanoscale metal oxide-based heterojunctions for gas sensing: A review. Sens. Actuators B:Chem. 2014, 204, 250–272.
Crossref Google Scholar
[6]

Ou, J. Z.; Ge, W. Y.; Carey, B.; Daeneke, T.; Rotbart, A.; Shan, W.; Wang, Y. C.; Fu, Z. Q.; Chrimes, A. F.; Wiodarski, W. et al. Physisorption-based charge transfer in two-dimensional SnS2 for selective and reversible NO2 gas sensing. ACS Nano 2015, 9, 10313–10323.
Crossref Google Scholar
[7]

Perkins, F. K.; Friedman, A. L.; Cobas, E.; Campbell, P. M.; Jernigan, G. G.; Jonker, B. T. Chemical vapor sensing with monolayer MoS2. Nano Lett. 2013, 13, 668–673.
Crossref Google Scholar
[8]

Cho, S. Y.; Kim, S. J.; Lee, Y.; Kim, J. S.; Jung, W. B.; Yoo, H. W.; Kim, J.; Jung, H. T. Highly enhanced gas adsorption properties in vertically aligned MoS2 layers. ACS Nano 2015, 9, 9314–9321.
Crossref Google Scholar
[9]

Yuan, W. J.; Shi, G. Q. Graphene-based gas sensors. J. Mater. Chem. A 2013, 1, 10078–10091.
Crossref Google Scholar
[10]

Fowler, J. D.; Allen, M. J.; Tung, V. C.; Yang, Y.; Kaner, R. B.; Weiller, B. H. Practical chemical sensors from chemically derived graphene. ACS Nano 2009, 3, 301–306.
Crossref Google Scholar
[11]

Singh, E.; Meyyappan, M.; Nalwa, H. S. Flexible graphene-based wearable gas and chemical sensors. ACS Appl. Mater. Interfaces 2017, 9, 34544–34586.
Crossref Google Scholar
[12]

Anichini, C.; Czepa, W.; Pakulski, D.; Aliprandi, A.; Ciesielski, A.; Samorì, P. Chemical sensing with 2D materials. Chem. Soc. Rev. 2018, 47, 4860–4908.
Crossref Google Scholar
[13]

Broza, Y. Y.; Vishinkin, R.; Barash, O.; Nakhleh, M. K.; Haick, H. Synergy between nanomaterials and volatile organic compounds for non-invasive medical evaluation. Chem. Soc. Rev. 2018, 47, 4781–4859.
Crossref Google Scholar
[14]

Mao, S.; Chang, J. B.; Pu, H. H.; Lu, G. H.; He, Q. Y.; Zhang, H.; Chen, J. H. Two-dimensional nanomaterial-based field-effect transistors for chemical and biological sensing. Chem. Soc. Rev. 2017, 46, 6872–6904.
Crossref Google Scholar
[15]

Wales, D. J.; Grand, J.; Ting, V. P.; Burke, R. D.; Edler, K. J.; Bowen, C. R.; Mintova, S.; Burrows, A. D. Gas sensing using porous materials for automotive applications. Chem. Soc. Rev. 2015, 44, 4290–4321.
Crossref Google Scholar
[16]

Yao, M. S.; Xiu, J. W.; Huang, Q. Q.; Li, W. H.; Wu, W. W.; Wu, A. Q.; Cao, L. A.; Deng, W. H.; Wang, G. E.; Xu, G. Van der Waals heterostructured MOF-on-MOF thin films: Cascading functionality to realize advanced chemiresistive sensing. Angew. Chem., Int. Ed. 2019, 58, 14915–14919.
Crossref Google Scholar
[17]

Liu, Y. L.; Tang, Z. Y. Multifunctional nanoparticle@MOF core–shell nanostructures. Adv. Mater. 2013, 25, 5819–5825.
Crossref Google Scholar
[18]

Stassen, I.; Burtch, N.; Talin, A.; Falcaro, P.; Allendorf, M.; Ameloot, R. An updated roadmap for the integration of metal-organic frameworks with electronic devices and chemical sensors. Chem. Soc. Rev. 2017, 46, 3185–3241.
Crossref Google Scholar
[19]

Hu, Z. C.; Deibert, B. J.; Li, J. Luminescent metal-organic frameworks for chemical sensing and explosive detection. Chem. Soc. Rev. 2014, 43, 5815–5840.
Crossref Google Scholar
[20]

Koo, W. T.; Jang, J. S.; Kim, I. D. Metal-organic frameworks for chemiresistive sensors. Chem 2019, 5, 1938–1963.
Crossref Google Scholar
[21]

Yuvaraja, S.; Surya, S. G.; Chernikova, V.; Vijjapu, M. T.; Shekhah, O.; Bhatt, P. M.; Chandra, S.; Eddaoudi, M.; Salama, K. N. Realization of an ultrasensitive and highly selective OFET NO2 sensor: The synergistic combination of PDVT-10 polymer and porphyrin-MOF. ACS Appl. Mater. Interfaces 2020, 12, 18748–18760.
Crossref Google Scholar
[22]

Canepa, P.; Tan, K.; Du, Y. J.; Lu, H. B.; Chabal, Y. J.; Thonhauser, T. Structural, elastic, thermal, and electronic responses of small-molecule-loaded metal-organic framework materials. J. Mater. Chem. A 2015, 3, 986–995.
Crossref Google Scholar
[23]

Jo, Y. M.; Lim, K.; Yoon, J. W.; Jo, Y. K.; Moon, Y. K.; Jang, H. W.; Lee, J. H. Visible-light-activated type II heterojunction in Cu3(hexahydroxytriphenylene)2/Fe2O3 hybrids for reversible NO2 sensing: Critical role of π–π* transition. ACS Cent. Sci. 2021, 7, 1176–1182.
Crossref Google Scholar
[24]

Tan, K.; Zuluaga, S.; Gong, Q. H.; Gao, Y. Z.; Nijem, N.; Li, J.; Thonhauser, T.; Chabal, Y. J. Competitive coadsorption of CO2 with H2O, NH3, SO2, NO, NO2, N2, O2, and CH4 in M-MOF-74 (M = Mg, Co, Ni): The role of hydrogen bonding. Chem. Mater. 2015, 27, 2203–2217.
Crossref Google Scholar
[25]

Tan, K.; Zuluaga, S.; Wang, H.; Canepa, P.; Soliman, K.; Cure, J.; Li, J.; Thonhauser, T.; Chabal, Y. J. Interaction of acid gases SO2 and NO2 with coordinatively unsaturated metal organic frameworks: M-MOF-74 (M = Zn, Mg, Ni, Co). Chem. Mater. 2017, 29, 4227–4235.
Crossref Google Scholar
[26]

Bhardwaj, S. K.; Bhardwaj, N.; Kaur, R.; Mehta, J.; Sharma, A. L.; Kim, K. H.; Deep, A. An overview of different strategies to introduce conductivity in metal-organic frameworks and miscellaneous applications thereof. J. Mater. Chem. A 2018, 6, 14992–15009.
Crossref Google Scholar
[27]

He, L. C.; Liu, Y.; Liu, J. Z.; Xiong, Y. S.; Zheng, J. Z.; Liu, Y. L.; Tang, Z. Y. Core-shell noble-metal@metal-organic-framework nanoparticles with highly selective sensing property. Angew. Chem., Int. Ed. 2013, 52, 3741–3745.
Crossref Google Scholar
[28]

Li, Y. T.; Liu, J. M.; Wang, Z. C.; Jin, J.; Liu, Y. L.; Chen, C. Y.; Tang, Z. Y. Optimizing energy transfer in nanostructures enables in vivo cancer lesion tracking via near-infrared excited hypoxia imaging. Adv. Mater. 2020, 32, 1907718.
Crossref Google Scholar
[29]

Zhao, M. T.; Yuan, K.; Wang, Y.; Li, G. D.; Guo, J.; Gu, L.; Hu, W. P.; Zhao, H. J.; Tang, Z. Y. Metal-organic frameworks as selectivity regulators for hydrogenation reactions. Nature 2016, 539, 76–80.
Crossref Google Scholar
[30]

Talin, A. A.; Centrone, A.; Ford, A. C.; Foster, M. E.; Stavila, V.; Haney, P.; Kinney, R. A.; Szalai, V.; El Gabaly, F.; Yoon, H. P. et al. Tunable electrical conductivity in metal-organic framework thin-film devices. Science 2014, 343, 66–69.
Crossref Google Scholar
[31]

Zhou, J.; Cheng, X. F.; Gao, B. J.; Yu, C.; He, J. H.; Xu, Q. F.; Li, H.; Li, N. J.; Chen, D. Y.; Lu, J. M. Detection of NO2 down to one ppb using ion-in-conjugation-inspired polymer. Small 2019, 15, 1803896.
Crossref Google Scholar
[32]

Wang, Z.; Huang, L. Z.; Zhu, X. F.; Zhou, X.; Chi, L. F. An ultrasensitive organic semiconductor NO2 sensor based on crystalline TIPS-pentacene films. Adv. Mater. 2017, 29, 1703192.
Crossref Google Scholar
[33]

Yao, M. S.; Li, W. H.; Xu, G. Metal-organic frameworks and their derivatives for electrically-transduced gas sensors. Coord. Chem. Rev. 2021, 426, 213479.
Crossref Google Scholar
[34]

Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Van Duyne, R. P.; Hupp, J. T. Metal-organic framework materials as chemical sensors. Chem. Rev. 2012, 112, 1105–1125.
Crossref Google Scholar
[35]

Campbell, M. G.; Liu, S. F.; Swager, T. M.; Dincă, M. Chemiresistive sensor arrays from conductive 2D metal-organic frameworks. J. Am. Chem. Soc. 2015, 137, 13780–13783.
Crossref Google Scholar
[36]

Bronstein, H.; Nielsen, C. B.; Schroeder, B. C.; McCulloch, I. The role of chemical design in the performance of organic semiconductors. Nat. Rev. Chem. 2020, 4, 66–77.
Crossref Google Scholar
[37]

Yu, S. H.; Girma, H. G.; Sim, K. M.; Yoon, S.; Park, J. M.; Kong, H.; Chung, D. S. Polymer-based flexible NOx sensors with ppb-level detection at room temperature using breath-figure molding. Nanoscale 2019, 11, 17709–17717.
Crossref Google Scholar
[38]

Park, H.; Kim, D. H.; Ma, B. S.; Shin, E.; Kim, Y.; Kim, T. S.; Kim, F. S.; Kim, I. D.; Kim, B. J. High-performance, flexible NO2 chemiresistors achieved by design of imine-incorporated n-type conjugated polymers. Adv. Sci. 2022, 9, 2200270.
Crossref Google Scholar
[39]

Qin, Y. X.; Wang, L. P.; Wang, X. F. A high performance sensor based on PANI/ZnTi-LDHs nanocomposite for trace NH3 detection. Org. Electron. 2019, 66, 102–109.
Crossref Google Scholar
[40]

Yang, Z. J.; Wei, J. J.; Sobolev, Y. I.; Grzybowski, B. A. Systems of mechanized and reactive droplets powered by multi-responsive surfactants. Nature 2018, 553, 313–318.
Crossref Google Scholar
[41]

Qi, X. Q.; Lu, Z. H.; You, E. M.; He, Y.; Zhang, Q. E.; Yi, H. J.; Li, D. Y.; Ding, S. Y.; Jiang, Y.; Xiong, X. P. et al. Nanocombing effect leads to nanowire-based, in-plane, uniaxial thin films. ACS Nano 2018, 12, 12701–12712.
Crossref Google Scholar
[42]

Xie, L.; Liu, J. R.; Bao, X. B.; Chen, J. D.; Zheng, X. Z.; He, Y. J.; Zhang, W.; Zeng, J.; Wang, Y.; Kong, B. Interfacial assembly of nanowire arrays toward carbonaceous mesoporous nanorods and superstructures. Small 2022, 18, 2104477.
Crossref Google Scholar
[43]

Park, S.; Lim, J. H.; Chung, S. W.; Mirkin, C. A. Self-assembly of mesoscopic metal-polymer amphiphiles. Science 2004, 303, 348–351.
Crossref Google Scholar
[44]

Zheng, J. Z.; Pang, K. L.; Liu, X.; Li, S. X.; Song, R.; Liu, Y. L.; Tang, Z. Y. Integration and synergy of organic single crystals and metal-organic frameworks in core–shell heterostructures enables outstanding gas selectivity for detection. Adv. Funct. Mater. 2020, 30, 2005727.
Crossref Google Scholar
[45]

Liao, J. Y.; Ho, K. C. A study of partially irreversible characteristics in a TTF-TCNQ gas sensing system. Sens. Actuators B:Chem. 2008, 130, 343–350.
Crossref Google Scholar
[46]

Jouve, C.; Jullien, D.; Remaki, B. Conductive polyethylene as sensitive layer for gas detection. Sens. Actuators B:Chem. 1995, 28, 75–80.
Crossref Google Scholar
[47]
Ho, K. C.; Liao, J. Y. NO2 gas sensing based on vacuum-deposited TTF-TCNQ thin films. Sens. Actuators B: Chem. 2003, 93, 370–378.
Crossref
[48]

Wang, C.; Wu, N.; Jacobs, D. L.; Xu, M.; Yang, X. M.; Zang, L. Discrimination of alkyl and aromatic amine vapors using TTF-TCNQ based chemiresistive sensors. Chem. Commun. 2017, 53, 1132–1135.
Crossref Google Scholar
[49]

Petit, C.; Levasseur, B.; Mendoza, B.; Bandosz, T. J. Reactive adsorption of acidic gases on MOF/graphite oxide composites. Micropor. Mesopor. Mater. 2012, 154, 107–112.
Crossref Google Scholar
[50]

Liu, H. B.; Li, J. B.; Lao, C. S.; Huang, C. S.; Li, Y. L.; Wang, Z. L.; Zhu, D. B. Morphological tuning and conductivity of organic conductor nanowires. Nanotechnology 2007, 18, 495704.
Crossref Google Scholar
[51]

Kistenmacher, T. J.; Phillips, T. E.; Cowan, D. O. The crystal structure of the 1: 1 radical cation-radical anion salt of 2, 2'-bis-l, 3-dithiole (TTF) and 7, 7, 8, 8-tetracyanoquinodimethane (TCNQ). Acta Crystallogr. Sec. B 1974, 30, 763–768.
Crossref Google Scholar
[52]

Moitra, N.; Fukumoto, S.; Reboul, J.; Sumida, K.; Zhu, Y.; Nakanishi, K.; Furukawa, S.; Kitagawa, S.; Kanamori, K. Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(II) hydroxide-based monoliths. Chem. Commun. 2015, 51, 3511–3514.
Crossref Google Scholar
[53]

Wang, Q. E.; Lian, M. L.; Zhu, X. W.; Chen, X. Excellent humidity sensor based on ultrathin HKUST-1 nanosheets. RSC Adv. 2021, 11, 192–197.
Crossref Google Scholar
[54]

Dey, K. K.; Kumar, A.; Shanker, R.; Dhawan, A.; Wan, M.; Yadav, R. R.; Srivastava, A. K. Growth morphologies, phase formation, optical & biological responses of nanostructures of CuO and their application as cooling fluid in high energy density devices. RSC Adv. 2012, 2, 1387–1403.
Crossref Google Scholar
[55]

Ba, N. N.; Zhu, L. J.; Li, H. B.; Zhang, G. Z.; Li, J. F.; Sun, J. F. 3D rod-like copper oxide with nanowire hierarchical structure: Ultrasound assisted synthesis from Cu2(OH)3NO3 precursor, optical properties and formation mechanism. Solid State Sci. 2016, 53, 23–29.
Crossref Google Scholar
[56]
Li, Y. Synthesis of copper (II) oxide particle and detection of photoelectrochemically generated hydrogen. In Proceedings of 2008 NNIN REU Research Accomplishments, 2008, pp 46–47.
[57]

Feng, Y. F.; Jiang, H.; Li, S. N.; Wang, J.; Jing, X. Y.; Wang, Y. R.; Chen, M. Metal-organic frameworks HKUST-1 for liquid-phase adsorption of uranium. Colloids Surf. A:Physicochem. Eng. Asp. 2013, 431, 87–92.
Crossref Google Scholar
[58]

Kumar, R. S.; Kumar, S. S.; Kulandainathan, M. A. Efficient electrosynthesis of highly active Cu3(BTC)2-MOF and its catalytic application to chemical reduction. Micropor. Mesopor. Mater. 2013, 168, 57–64.
Crossref Google Scholar
[59]

Xu, X. M.; Liu, Y. X.; Wang, T.; Ji, H. D.; Chen, L.; Li, S.; Liu, W. Co-adsorption of ciprofloxacin and Cu(II) onto titanate nanotubes: Speciation variation and metal-organic complexation. J. Mol. Liq. 2019, 292, 111375.
Crossref Google Scholar
[60]

Arul, C.; Moulaee, K.; Donato, N.; Iannazzo, D.; Lavanya, N.; Neri, G.; Sekar, C. Temperature modulated Cu-MOF based gas sensor with dual selectivity to acetone and NO2 at low operating temperatures. Sens. Actuators B:Chem. 2021, 329, 129053.
Crossref Google Scholar
[61]

Small, L. J.; Henkelis, S. E.; Rademacher, D. X.; Schindelholz, M. E.; Krumhansl, J. L.; Vogel, D. J.; Nenoff, T. M. Near-zero power MOF-based sensors for NO2 detection. Adv. Funct. Mater. 2020, 30, 2006598.
Crossref Google Scholar
[62]

Liu, Y. S.; Wang, R.; Zhang, T.; Liu, S.; Fei, T. Zeolitic imidazolate framework-8 (ZIF-8)-coated In2O3 nanofibers as an efficient sensing material for ppb-level NO2 detection. J. Colloid Interface Sci. 2019, 541, 249–257.
Crossref Google Scholar
[63]

Ko, W. C.; Kim, M. S.; Kwon, Y. J.; Jeong, J.; Kim, W. R.;Choi, H.; Park, J. K.; Jeong, Y. K. Two-dimensional semiconducting covalent organic nanosheets for highly sensitive and stable NO2 sensing under humid conditions. J. Mater. Chem. A 2020, 8, 19246–19253.
Crossref Google Scholar
[64]

Zhan, M. M.; Ge, C. X.; Hussain, S.; Alkorbi, A. S.; Alsaiari, R.; Alhemiary, N. A.; Qiao, G. J.; Liu, G. W. Enhanced NO2 gas-sensing performance by core–shell SnO2/ZIF-8 nanospheres. Chemosphere 2022, 291, 132842.
Crossref Google Scholar
[65]

Zhan, M. M.; Hussain, S.; AlGarni, T. S.; Shah, S.; Liu, J. L.; Zhang, X. Z.; Ahmad, A.; Javed, M. S.; Qiao, G. J.; Liu, G. W. Facet controlled polyhedral ZIF-8 MOF nanostructures for excellent NO2 gas-sensing applications. Mater. Res. Bull. 2021, 136, 111133.
Crossref Google Scholar
[66]

Li, Z.; Zhang, Y.; Zhang, H.; Jiang, Y.; Yi, J. X. Superior NO2 sensing of MOF-derived Indium-doped ZnO porous hollow cages. ACS Appl. Mater. Interfaces 2020, 12, 37489–37498.
Crossref Google Scholar
[67]

Fan, J. L.; Hu, X. F.; Qin, W. W.; Liu, Z. Y.; Liu, Y. S.; Gao, S. J.; Tan, L. P.; Yang, J. L.; Luo, L. B.; Zhang, W. UV-light-assisted gas sensor based on PdSe2/InSe heterojunction for ppb-level NO2 sensing at room temperature. Nanoscale 2022, 14, 13204–13213.
Crossref Google Scholar
[68]

Ji, W. T.; Yang, F.; Sun, J. H.; Xu, R. P.; Li, P.; Jing, L. Q. Improved performance of g-C3N4 for optoelectronic detection of NO2 gas by coupling metal-organic framework nanosheets with coordinatively unsaturated Ni(II) Sites. ACS Appl. Mater. Interfaces 2023, 15, 11961–11969.
Crossref Google Scholar
[69]

Li, Y. Y.; Liu, Y. Z.; Lu, Y.; Liu, Z. Q.; Sui, C. M.; Wang, Y. L.; Yang, L.; Liu, F. M.; Sun, P.; Liu, F. M. et al. Preparation of BiOI-functionalized ZnO nanorods for ppb-Level NO2 detection at room temperature. ACS Sens. 2022, 7, 3915–3922.
Crossref Google Scholar
[70]

Pham, T.; Li, G. H.; Bekyarova, E.; Itkis, M. E.; Mulchandani, A. MoS2-based optoelectronic gas sensor with sub-parts-per-billion limit of NO2 gas detection. ACS Nano 2019, 13, 3196–3205.
Crossref Google Scholar
[71]

Kwon, E. H.; Kim, M.; Lee, C. Y.; Kim, M.; Park, Y. D. Metal-organic-framework-decorated carbon nanofibers with enhanced gas sensitivity when incorporated into an organic semiconductor-based gas sensor. ACS Appl. Mater. Interfaces 2022, 14, 10637–10647.
Crossref Google Scholar
[72]

Lee, J. I.; Kim, M.; Park, K. C.; Lee, C. Y.; Park, Y. D. Polythiophene hybrid film with zirconium-porphyrin metal-organic framework for improved charge carrier transport and NO2 gas sensing. Mater. Chem. Phys. 2022, 278, 125661.
Crossref Google Scholar
[73]

Koo, W. T.; Kim, S. J.; Jang, J. S.; Kim, D. H.; Kim, I. D. Catalytic metal nanoparticles embedded in conductive metal-organic frameworks for chemiresistors: Highly active and conductive porous materials. Adv. Sci. 2019, 6, 1900250.
Crossref Google Scholar
[74]

Park, C.; Koo, W. T.; Chong, S.; Shin, H.; Kim, Y. H.; Cho, H. J.; Jang, J. S.; Kim, D. H.; Lee, J.; Park, S. et al. Confinement of ultrasmall bimetallic nanoparticles in conductive metal-organic frameworks via site-specific nucleation. Adv. Mater. 2021, 33, 2101216.
Crossref Google Scholar
[75]

Kim, J. O.; Koo, W. T.; Kim, H.; Park, C.; Lee, T.; Hutomo, C. A.; Choi, S. Q.; Kim, D. S.; Kim, I. D.; Park, S. Large-area synthesis of nanoscopic catalyst-decorated conductive MOF film using microfluidic-based solution shearing. Nat. Commun. 2021, 12, 4294.
Crossref Google Scholar
[76]

Kang, Y.; Kwak, D. H.; Kwon, J. E.; Kim, B. G.; Lee, W. H. NO2-affinitive conjugated polymer for selective sub-parts-per-billion NO2 detection in a field-effect transistor sensor. ACS Appl. Mater. Interfaces 2021, 13, 31910–31918.
Crossref Google Scholar
[77]

Khan, M. W.; Sadiq, M. M.; Gopalsamy, K.; Xu, K.; Jannat, A.; Zhang, B. Y.; Mohiuddin, M.; Haris, M.; Ou, R.; Afrin, S. et al. Hetero-metallic metal-organic frameworks for room-temperature NO2 sensing. J. Colloid Interface Sci. 2022, 610, 304–312.
Crossref Google Scholar
[78]

Fan, J. L.; Hu, X. F.; Qin, W. W.; Zhou, M.; Liu, Y. S.; Cheng, S.; Gao, S. J.; Tan, L. P.; Wang, G. Q.; Zhang, W. Room-temperature sensing performance of binary Co-Zn doped MoS2/graphite composites toward ppb-level NO2. J. Mater. Chem. C 2023, 11, 2364–2374.
Crossref Google Scholar
[79]

Gardner, D. W.; Gao, X.; Fahad, H. M.; Yang, A. T.; He, S.; Javey, A.; Carraro, C.; Maboudian, R. Transistor-based work-function measurement of metal-organic frameworks for ultra-low-power, rationally designed chemical sensors. Chem. -Eur. J. 2019, 25, 13176–13183.
Crossref Google Scholar
[80]

Zhang, L. Z.; Fang, Q. L.; Huang, Y. H.; Xu, K. W.; Chu, P. K.; Ma, F. Oxygen vacancy enhanced gas-sensing performance of CeO2/graphene heterostructure at room temperature. Anal. Chem. 2018, 90, 9821–9829.
Crossref Google Scholar
Nano Research
Volume 16 Issue 12,
December 2023
Pages 13366-13374
DOI: 10.1007/s12274-023-6046-7
Cite this article:
Lin C, Kim K, Wang Z, et al. Mace-like TTF-TCNQ/HKUST-1 composite structures for rapid NO2 detection: Synergistically induced ultrahigh sensitivity and outstanding selectivity. Nano Research, 2023, 16(12): 13366-13374. https://doi.org/10.1007/s12274-023-6046-7
Topics:
Chemical sensors
Part of a topical collection:
Special issue for the 20th Anniversary of NCNST

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Received: 29 April 2023
Revised: 26 July 2023
Accepted: 26 July 2023
Published: 08 September 2023
© Tsinghua University Press 2023
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