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Research Article

Surface reconstruction and structural transformation of two-dimensional Ni-Fe MOFs for oxygen evolution in seawater media

Liyuan Xiao1,§, Xue Bai1,§, Jingyi Han1, Tianmi Tang1, Siyu Chen1, Hui Qi2, Changmin Hou3, Fuquan Bai4( ), Zhenlu Wang1( ), Jingqi Guan1( )
Institute of Physical Chemistry, College of Chemistry, Jilin University, Changchun 130021, China
The Second Hospital of Jilin University, Changchun 130021, China
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, College of Chemistry, Changchun 130023, China

§ Liyuan Xiao and Xue Bai contributed equally to this work.

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Graphical Abstract

Ni-Fe metal-organic framework nanosheets on nickel foam (Ni3Fe-TPA/NF, TPA = terephthalic acid) shows low η10 of 189, 192, and 265 mV for the oxygen evolution reaction (OER) in 1 M KOH, in 0.5 M NaCl + 1 M KOH, and in seawater + 1 M KOH, respectively. During the OER, surface reconstruction and structural transformation occurred, and active Ni3FeOOH species with more oxygen vacancies were in-situ generated on the Ni3Fe-TPA/NF.

Abstract

As a four-electron transfer reaction, oxygen evolution reaction (OER) is limited by large overpotential and slow kinetics. Here, we in-situ synthesized two-dimensional (2D) Ni-Fe metal-organic framework nanosheets on nickel foam (NixFe-TPA/NF, TPA = terephthalic acid) for oxygen evolution in alkaline and alkaline seawater electrolytes. In 1 M KOH, Ni3Fe-TPA/NF shows a low overpotential (η10) of 189 mV at 10 mA·cm−2 and an ultra-low overpotential of only 260 mV at 500 mA·cm−2. In alkaline seawater, Ni3Fe-TPA/NF still provides impressive OER performance, with an η10 of 265 mV. In-situ Raman characterization results show that the phase transition occurs during the OER, and Ni3FeOOH with more oxygen vacancies is in-situ formed, reducing the OER energy barrier. Density functional theory (DFT) reveals that the synergy between Ni and Fe reduces the energy barrier and accelerates the rate-determining step. In addition, the ultra-thin 2D sheet structure and the close combination of Ni3FeOOH and highly conductive NF support ensure the high catalytic OER activity. Therefore, the surface reconstruction and structural modification strategy can be used to design and prepare high-performance OER electrocatalysts for energy-related applications.

Keywords

density functional theory (DFT) calculationNi3FeOOHoxygen evolution reactionseawater electrolysissurface reconstruction

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References

[1]

Han, J. Y.; Guan, J. Q. Multicomponent transition metal oxides and (oxy)hydroxides for oxygen evolution. Nano Res. 2023, 16, 1913–1966.
Crossref Google Scholar
[2]

Huang, Z. D.; Feng, C.; Sun, J. P.; Xu, B.; Huang, T. X.; Wang, X. K.; Dai, F. N.; Sun, D. F. Ultrathin metal-organic framework nanosheets-derived yolk–shell Ni0.85Se@NC with rich Se-vacancies for enhanced water electrolysis. CCS Chem. 2021, 3, 2696–2711.
Crossref Google Scholar
[3]

Han, J. Y.; Niu, X. D.; Guan, J. Q. Unveiling the role of defects in iron oxyhydroxide for oxygen evolution. J. Colloid Interface Sci. 2023, 635, 167–175.
Crossref Google Scholar
[4]

Xiao, K.; Wang, Y. F.; Wu, P. Y.; Hou, L. P.; Liu, Z. Q. Activating lattice oxygen in spinel ZnCo2O4 through filling oxygen vacancies with fluorine for electrocatalytic oxygen evolution. Angew. Chem., Int. Ed. 2023, 62, e202301408.
Crossref Google Scholar
[5]

Han, W. K.; Wei, J. X.; Xiao, K.; Ouyang, T.; Peng, X. W.; Zhao, S. L.; Liu, Z. Q. Activating lattice oxygen in layered lithium oxides through cation vacancies for enhanced urea electrolysis. Angew. Chem., Int. Ed. 2022, 61, e202206050.
Crossref Google Scholar
[6]

Bai, X.; Fan, Y.; Hou, C. M.; Tang, T. M.; Guan, J. Q. Partial crystallization of Co-Fe oxyhydroxides towards enhanced oxygen evolution activity. Int. J. Hydrogen Energy 2022, 47, 16711–16718.
Crossref Google Scholar
[7]

Trotochaud, L.; Young, S. L.; Ranney, J. K.; Boettcher, S. W. Nickel-iron oxyhydroxide oxygen-evolution electrocatalysts: The role of intentional and incidental iron incorporation. J. Am. Chem. Soc. 2014, 136, 6744–6753.
Crossref Google Scholar
[8]

Deng, J.; Nellist, M. R.; Stevens, M. B.; Dette, C.; Wang, Y.; Boettcher, S. W. Morphology dynamics of single-layered Ni(OH)2/NiOOH nanosheets and subsequent Fe incorporation studied by in situ electrochemical atomic force microscopy. Nano Lett. 2017, 17, 6922–6926.
Crossref Google Scholar
[9]

Hu, J.; Liang, Y. Q.; Wu, S. L.; Li, Z. Y.; Shi, C. S.; Luo, S. Y.; Sun, H. J.; Zhu, S. L.; Cui, Z. D. Hierarchical nickle-iron layered double hydroxide composite electrocatalyst for efficient oxygen evolution reaction. Mater. Today Nano 2022, 17, 100150.
Crossref Google Scholar
[10]

Wang, H. Y.; Chen, L. Y.; Tan, L.; Liu, X. E.; Wen, Y. H.; Hou, W. G.; Zhan, T. R. Electrodeposition of NiFe-layered double hydroxide layer on sulfur-modified nickel molybdate nanorods for highly efficient seawater splitting. J. Colloid Interface Sci. 2022, 613, 349–358.
Crossref Google Scholar
[11]

Park, Y. S.; Lee, J.; Jang, M. J.; Yang, J. C.; Jeong, J.; Park, J.; Kim, Y.; Seo, M. H.; Chen, Z. W.; Choi, S. M. High-performance anion exchange membrane alkaline seawater electrolysis. J. Mater. Chem. A 2021, 9, 9586–9592.
Crossref Google Scholar
[12]

Xiao, K.; Lin, R. T.; Wei, J. X.; Li, N.; Li, H.; Ma, T. Y.; Liu, Z. Q. Electrochemical disproportionation strategy to in-situ fill cation vacancies with Ru single atoms. Nano Res. 2022, 15, 4980–4985.
Crossref Google Scholar
[13]

Chang, J. F.; Wang, G. Z.; Yang, Z. Z.; Li, B. Y.; Wang, Q.; Kuliiev, R.; Orlovskaya, N.; Gu, M.; Du, Y. G.; Wang, G. F. et al. Dual-doping and synergism toward high-performance seawater electrolysis. Adv. Mater. 2021, 33, 2101425.
Crossref Google Scholar
[14]

Song, Y. Y.; Sun, M. Z.; Zhang, S. C.; Zhang, X. Y.; Yi, P.; Liu, J. Z.; Huang, B. L.; Huang, M. H.; Zhang, L. X. Alleviating the work function of vein-like CoxP by Cr doping for enhanced seawater electrolysis. Adv. Funct. Mater. 2023, 33, 2214081.
Crossref Google Scholar
[15]

Khan, M. A.; Al-Attas, T.; Roy, S.; Rahman, M. M.; Ghaffour, N.; Thangadurai, V.; Larter, S.; Hu, J. G.; Ajayan, P. M.; Kibria, M. G. Seawater electrolysis for hydrogen production: A solution looking for a problem. Energy Environ. Sci. 2021, 14, 4831–4839.
Crossref Google Scholar
[16]

Song, H. J.; Yoon, H.; Ju, B.; Lee, D. Y.; Kim, D. W. Electrocatalytic selective oxygen evolution of carbon-coated Na2Co1−xFexP2O7 nanoparticles for alkaline seawater electrolysis. ACS Catal. 2020, 10, 702–709.
Crossref Google Scholar
[17]

Feng, S. Y.; Gu, C. S.; Yu, Y. H.; Rao, P.; Deng, P. L.; Li, J.; Kang, Z. Y.; Tian, X. L.; Wu, Z. F. A two-dimensional heterogeneous structured Ni3Se2@MoO3 catalyst for seawater electrolysis. J. Mater. Chem. A 2023, 11, 11740–11747.
Crossref Google Scholar
[18]

Wang, C. Z.; Zhu, M. Z.; Cao, Z. Y.; Zhu, P.; Cao, Y. Q.; Xu, X. Y.; Xu, C. X.; Yin, Z. Y. Heterogeneous bimetallic sulfides based seawater electrolysis towards stable industrial-level large current density. Appl. Catal. B: Environ. 2021, 291, 120071.
Crossref Google Scholar
[19]

Sun, H.; Sun, J. K.; Song, Y. Y.; Zhang, Y. F.; Qiu, Y.; Sun, M. X.; Tian, X. Y.; Li, C. Y.; Lv, Z.; Zhang, L. X. Nickel-cobalt hydrogen phosphate on nickel nitride supported on nickel foam for alkaline seawater electrolysis. ACS Appl. Mater. Interfaces 2022, 14, 22061–22070.
Crossref Google Scholar
[20]

Jiang, N.; Meng, H. M.; Song, L. J.; Yu, H. Y. Study on Ni-Fe-C cathode for hydrogen evolution from seawater electrolysis. Int. J. Hydrogen Energy 2010, 35, 8056–8062.
Crossref Google Scholar
[21]

Enkhtuvshin, E.; Kim, K. M.; Kim, Y. K.; Mihn, S.; Kim, S. J.; Jung, S. Y.; Thao, N. T. T.; Ali, G.; Akbar, M.; Chung, K. Y. et al. Stabilizing oxygen intermediates on redox-flexible active sites in multimetallic Ni-Fe-Al-Co layered double hydroxide anodes for excellent alkaline and seawater electrolysis. J. Mater. Chem. A 2021, 9, 27332–27346.
Crossref Google Scholar
[22]

Yin, X.; Hua, Y. N.; Gao, Z. Two-dimensional materials for high-performance oxygen evolution reaction: Fundamentals, recent progress, and improving strategies. CCS Chem. 2023, 1, 190–226.
Crossref Google Scholar
[23]

Li, L.; Fang, Z. B.; Deng, W. Z.; Yi, J. D.; Wang, R.; Liu, T. F. Precise construction of stable bimetallic metal-organic frameworks with single-site Ti(IV) incorporation in nodes for efficient photocatalytic oxygen evolution. CCS Chem. 2022, 4, 2782–2792.
Crossref Google Scholar
[24]

Tang, T. M.; Li, S. S.; Sun, J. R.; Wang, Z. L.; Guan, J. Q. Advances and challenges in two-dimensional materials for oxygen evolution. Nano Res. 2022, 15, 8714–8750.
Crossref Google Scholar
[25]

Bai, X.; Guan, J. Q. MXenes for electrocatalysis applications: Modification and hybridization. Chin. J. Catal. 2022, 43, 2057–2090.
Crossref Google Scholar
[26]

Xiao, L. Y.; Wang, Z. L.; Guan, J. Q. 2D MOFs and their derivatives for electrocatalytic applications: Recent advances and new challenges. Coord. Chem. Rev. 2022, 472, 214777.
Crossref Google Scholar
[27]

Lin, C.; He, X.; Li, H. Q.; Zou, J. J.; Que, M. L.; Tian, J. Y.; Qian, Y. Tunable metal-organic framework nanoarrays on carbon cloth constructed by a rational self-sacrificing template for efficient and robust oxygen evolution reactions. CrystEngComm 2021, 23, 7090–7096.
Crossref Google Scholar
[28]

Meng, C. Q.; Cao, Y.; Luo, Y. L.; Zhang, F.; Kong, Q. Q.; Alshehri, A. A.; Alzahrani, K. A.; Li, T. S.; Liu, Q.; Sun, X. P. A Ni-MOF nanosheet array for efficient oxygen evolution electrocatalysis in alkaline media. Inorg. Chem. Front. 2021, 8, 3007–3011.
Crossref Google Scholar
[29]

Huo, J. M.; Wang, Y.; Yan, L. T.; Xue, Y. Y.; Li, S. N.; Hu, M. C.; Jiang, Y. C.; Zhai, Q. G. In situ semi-transformation from heterometallic MOFs to Fe-Ni LDH/MOF hierarchical architectures for boosted oxygen evolution reaction. Nanoscale 2020, 12, 14514–14523.
Crossref Google Scholar
[30]

Kim, J. H.; Youn, D. H.; Kawashima, K.; Lin, J.; Lim, H.; Mullins, C. B. An active nanoporous Ni(Fe) OER electrocatalyst via selective dissolution of Cd in alkaline media. Appl. Catal. B: Environ. 2018, 225, 1–7.
Crossref Google Scholar
[31]

Zhao, J. Z.; Wu, W. B.; Jia, X. Y.; Zhao, Z. L.; Hu, X. A coaxial three-layer (Ni,Fe)OxHy/Ni/Cu mesh electrode: Excellent oxygen evolution reaction activity for water electrolysis. Catal. Sci. Technol. 2020, 10, 1803–1808.
Crossref Google Scholar
[32]

Liu, Y. K.; Jiang, S.; Li, S. J.; Zhou, L.; Li, Z. H.; Li, J. M.; Shao, M. F. Interface engineering of (Ni,Fe)S2@MoS2 heterostructures for synergetic electrochemical water splitting. Appl. Catal. B: Environ. 2019, 247, 107–114.
Crossref Google Scholar
[33]

Tan, J. B.; He, X. B.; Yin, F. X.; Chen, B. H.; Liang, X.; Li, G. R.; Yin, H. Q. Fe doped metal organic framework (Ni)/carbon black nanosheet as highly active electrocatalyst for oxygen evolution reaction. Int. J. Hydrogen Energy 2020, 45, 21431–21441.
Crossref Google Scholar
[34]

Kahnamouei, M. H.; Shahrokhian, S. Ultrafast two-step synthesis of S-doped Fe/Ni (oxy)hydroxide/Ni nanocone arrays on carbon cloth and stainless-steel substrates for water-splitting applications. ACS Appl. Energy Mater. 2021, 4, 10627–10638.
Crossref Google Scholar
[35]

Liu, W. J.; Hu, X.; Li, H. C.; Yu, H. Q. Pseudocapacitive Ni-Co-Fe hydroxides/N-doped carbon nanoplates-based electrocatalyst for efficient oxygen evolution. Small 2018, 14, 1801878.
Crossref Google Scholar
[36]

Qi, D. D.; Chen, X.; Liu, W. P.; Liu, C. X.; Liu, W. B.; Wang, K.; Jiang, J. Z. A Ni/Fe-based heterometallic phthalocyanine conjugated polymer for the oxygen evolution reaction. Inorg. Chem. Front. 2020, 7, 642–646.
Crossref Google Scholar
[37]

Zheng, F. Q.; Zhang, Z. W.; Xiang, D.; Li, P.; Du, C.; Zhuang, Z. H.; Li, X. K.; Chen, W. Fe/Ni bimetal organic framework as efficient oxygen evolution catalyst with low overpotential. J. Colloid Interface Sci. 2019, 555, 541–547.
Crossref Google Scholar
[38]

Chai, Y. M.; Shang, X.; Liu, Z. Z.; Dong, B.; Han, G. Q.; Gao, W. K.; Chi, J. Q.; Yan, K. L.; Liu, C. G. Ripple-like NiFeCo sulfides on nickel foam derived from in-situ sulfurization of precursor oxides as efficient anodes for water oxidation. Appl. Surf. Sci. 2018, 428, 370–376.
Crossref Google Scholar
[39]

Xiao, C. H.; Zhang, B.; Li, D. Partial-sacrificial-template synthesis of Fe/Ni phosphides on Ni foam: A strongly stabilized and efficient catalyst for electrochemical water splitting. Electrochim. Acta 2017, 242, 260–267.
Crossref Google Scholar
[40]

Wan, Z. X.; Yu, H. B.; He, Q. T.; Hu, Y.; Yan, P. X.; Shao, X.; Isimjan, T. T.; Zhang, B.; Yang, X. L. In-situ growth and electronic structure modulation of urchin-like Ni-Fe oxyhydroxide on nickel foam as robust bifunctional catalysts for overall water splitting. Int. J. Hydrogen Energy 2020, 45, 22427–22436.
Crossref Google Scholar
[41]

Zhao, T.; Cheng, C.; Wang, D.; Zhong, D. Z.; Hao, G. Y.; Liu, G.; Li, J. P.; Zhao, Q. Preparation of a bimetallic NiFe-MOF on nickel foam as a highly efficient electrocatalyst for oxygen evolution reaction. ChemistrySelect 2021, 6, 1320–1327.
Crossref Google Scholar
[42]

Yuan, J. X.; Cheng, X. D.; Lei, C. J.; Yang, B.; Li, Z. J.; Luo, K.; Lam, K. H. K.; Lei, L. C.; Hou, Y.; Ostrikov, K. K. Bimetallic oxyhydroxide as a high-performance water oxidation electrocatalyst under industry-relevant conditions. Engineering 2021, 7, 1306–1312.
Crossref Google Scholar
[43]
Niu, S.; Tang, T.; Qu, Y. J.; Chen, Y. Y.; Luo, H.; Pan, H.; Jiang, W. J.; Zhang, J. N.; Hu, J. S. Mitigating the reconstruction of metal sulfides for ultrastable oxygen evolution at high current density. CCS Chem., in press, https://doi.org/10.31635/ccschem.023.202202663.
[44]

Han, J. Y.; Zhang, M. Z.; Bai, X.; Duan, Z. Y.; Tang, T. M.; Guan, J. Q. Mesoporous Mn-Fe oxyhydroxides for oxygen evolution. Inorg. Chem. Front. 2022, 9, 3559–3565.
Crossref Google Scholar
[45]

Zheng, Y. P.; Yu, D. H.; Xu, W.; Zhang, K.; Ma, K. L.; Guo, X. Y.; Lou, Y. B.; Hu, M. L. Robust FeCoP nanoparticles grown on a rGO-coated Ni foam as an efficient oxygen evolution catalyst for excellent alkaline and seawater electrolysis. Dalton Trans. 2023, 52, 3493–3500.
Crossref Google Scholar
[46]

Yang, L. J.; Feng, C.; Guan, C. D.; Zhu, L. J.; Xia, D. H. Construction of seaurchin-like structured Ag2Se-Ag2S-CoCH/NF electrocatalyst with high catalytic activity and corrosion resistance for seawater electrolysis. Appl. Surf. Sci. 2023, 607, 154885.
Crossref Google Scholar
[47]

Yan, L.; Chen, X. W.; Liu, X. J.; Chen, L. P.; Zhang, B. In situ formed VOOH nanosheet arrays anchored on a Ti3C2Tx MXene as a highly efficient and robust synergistic electrocatalyst for boosting water oxidation and reduction. J. Mater. Chem. A 2020, 8, 23637–23644.
Crossref Google Scholar
[48]

Chen, J. X.; Long, Q. W.; Xiao, K.; Ouyang, T.; Li, N.; Ye, S. Y.; Liu, Z. Q. Vertically-interlaced NiFeP/MXene electrocatalyst with tunable electronic structure for high-efficiency oxygen evolution reaction. Sci. Bull. 2021, 66, 1063–1072.
Crossref Google Scholar
[49]

Xing, X. S.; Ren, X. F.; Zeng, X. Y.; Li, A.; Wang, Y. Q.; Zhou, Z. Y.; Guo, Y.; Wu, S. L.; Du, J. M. Accelerating oxygen evolution reaction kinetics by reconstructing layered and defective Ni3FeOOH/FeOOH in a hematite photoanode. Sol. RRL 2023, 7, 2201041.
Crossref Google Scholar
[50]

Deng, Q.; Huangyang, X. Y.; Zhang, X.; Xiao, Z. H.; Zhou, W. B.; Wang, H. R.; Liu, H. Y.; Zhang, F.; Li, C. Z.; Wu, X. W. et al. Edge-rich multidimensional frame carbon as high-performance electrode material for vanadium redox flow batteries. Adv. Energy Mater. 2022, 12, 2103186.
Crossref Google Scholar
[51]

Zhong, H. Y.; Wang, X. P.; Sun, G. X.; Tang, Y. X.; Tan, S. D.; He, Q.; Zhang, J.; Xiong, T.; Diao, C. Z.; Yu, Z. G. et al. Optimization of oxygen evolution activity by tuning eg* band broadening in nickel oxyhydroxide. Energy Environ. Sci. 2023, 16, 641–652.
Crossref Google Scholar
[52]

Cheng, F. P.; Li, Z. J.; Wang, L.; Yang, B.; Lu, J. G.; Lei, L. C.; Ma, T. Y.; Hou, Y. In situ identification of the electrocatalytic water oxidation behavior of a nickel-based metal-organic framework nanoarray. Mater. Horiz. 2021, 8, 556–564.
Crossref Google Scholar
[53]

Chen, J. D.; Zheng, F.; Zhang, S. J.; Fisher, A.; Zhou, Y.; Wang, Z. Y.; Li, Y. Y.; Xu, B. B.; Li, J. T.; Sun, S. G. Interfacial interaction between FeOOH and Ni-Fe LDH to modulate the local electronic structure for enhanced OER electrocatalysis. ACS Catal. 2018, 8, 11342–11351.
Crossref Google Scholar
[54]

Yan, P.; Liu, Q.; Zhang, H.; Qiu, L. C.; Wu, H. B.; Yu, X. Y. Deeply reconstructed hierarchical and defective NiOOH/FeOOH nanoboxes with accelerated kinetics for the oxygen evolution reaction. J. Mater. Chem. A 2021, 9, 15586–15594.
Crossref Google Scholar
Nano Research
Volume 17 Issue 4,
April 2024
Pages 2429-2437
DOI: 10.1007/s12274-023-6088-x
Cite this article:
Xiao L, Bai X, Han J, et al. Surface reconstruction and structural transformation of two-dimensional Ni-Fe MOFs for oxygen evolution in seawater media. Nano Research, 2024, 17(4): 2429-2437. https://doi.org/10.1007/s12274-023-6088-x
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Received: 03 July 2023
Revised: 29 July 2023
Accepted: 13 August 2023
Published: 07 September 2023
© Tsinghua University Press 2023
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