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Research Article

Stabilizing high-efficiency iridium single atoms via lattice confinement for acidic oxygen evolution

Yibo Wang1,2,4,§, Jiadong Jiang5,§, Zhaoping Shi1,2,4, Hongxiang Wu1,2,4, Jiahao Yang1,2,4, Pengbo Wang1,2,4, Shuai Hou1, Meiling Xiao1,2,3,4, Junjie Ge1,2( ), Changpeng Liu1,2,4( ), Wei Xing1,2,3,4( )
Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, . China
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Key Laboratory of Physics and Technology for Advanced Batteries, Ministry of Education, College of Physics, Jilin University, Changchun 130012, China

§ Yibo Wang and Jiadong Jiang contributed equally to this work.

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Graphical Abstract

A lattice-confined strategy was reported to stabilize Ir single atom. The synthesized IrSAs-PdO exhibited superior activity and stability in a practical water electrolyzer even though the loading of Ir was as low as 60 µg·cm−2.

Abstract

Stable and efficient single atom catalysts (SACs) are highly desirable yet challenging in catalyzing acidic oxygen evolution reaction (OER). Herein, we report a novel iridium single atom catalyst structure, with atomic Ir doped in tetragonal PdO matrix (IrSAs-PdO) via a lattice-confined strategy. The optimized IrSAs-PdO-0.10 exhibited remarkable OER activity with an overpotential of 277 mV at 10 mA·cm−2 and long-term stability of 1000 h in 0.5 M H2SO4. Furthermore, the turnover frequency attains 1.6 s−1 at an overpotential of 300 mV with a 24-fold increase in the intrinsic activity. The high activity originates from isolated iridium sites with low valence states and decreased Ir–O bonding covalency, and the excellent stability is a result of the effective confinement of iridium sites by Ir–O–Pd motifs. Moreover, we demonstrated for the first time that SACs have great potential in realizing ultralow loading of iridium (as low as microgram per square center meter level) in a practical water electrolyzer.

Keywords

lattice confinementiridium single atomsultralow iridium loadingacidic oxygen evolutionproton exchange membrane water electrolysis

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References

[1]

Hu, L. Y.; Xiao, R. S.; Du, D.; Zhu, C. Z.; Lin, Y. H. Metal–organic framework-based electrocatalysts for acidic oxygen evolution reaction. Trends Chem. 2023, 5, 324–335.
Crossref Google Scholar
[2]

Hu, S. Q.; Ge, S. Y.; Liu, H. M.; Kang, X.; Yu, Q. M.; Liu, B. L. Low-dimensional electrocatalysts for acidic oxygen evolution: Intrinsic activity, high current density operation, and long-term stability. Adv Funct. Mater. 2022, 32, 2201726.
Crossref Google Scholar
[3]

Yu, H. R.; Danilovic, N.; Wang, Y.; Willis, W.; Poozhikunnath, A.; Bonville, L.; Capuano, C.; Ayers, K.; Maric, R. Nano-size IrO x catalyst of high activity and stability in PEM water electrolyzer with ultra-low iridium loading. Appl. Catal. B: Environ. 2018, 239, 133–146.
Crossref Google Scholar
[4]

Ma, R. P.; Wang, X.; Yang, X. L.; Li, Y.; Liu, C. P.; Ge, J. J.; Xing, W. Identification of active sites and synergistic effect in multicomponent carbon-based Ru catalysts during electrocatalytic hydrogen evolution. Nano Res. 2023, 16, 166–173.
Crossref Google Scholar
[5]

Dong, S.; Zhang, C. Y.; Yue, Z. Y.; Zhang, F. R.; Zhao, H.; Cheng, Q. Q.; Wang, G. L.; Xu, J. F.; Chen, C.; Zou, Z. Q. et al. Overall design of anode with gradient ordered structure with low iridium loading for proton exchange membrane water electrolysis. Nano Lett 2022, 22, 9434–9440.
Crossref Google Scholar
[6]

Zhao, G. Q.; Luo, Z. X.; Zhang, B. H.; Chen, Y. P.; Cui, X. Z.; Chen, J.; Liu, Y. F.; Gao, M. X.; Pan, H. G.; Sun, W. P. Epitaxial interface stabilizing iridium dioxide toward the oxygen evolution reaction under high working potentials. Nano Res. 2023, 16, 4767–4774.
Crossref Google Scholar
[7]

Minke, C.; Suermann, M.; Bensmann, B.; Hanke-Rauschenbach, R. Is iridium demand a potential bottleneck in the realization of large-scale PEM water electrolysis. Int. J. Hyd. Energy 2021, 46, 23581–23590.
Crossref Google Scholar
[8]

Ni, J.; Shi, Z. P.; Wang, X.; Wang, Y. B.; Wu, H. X.; Liu, C. P.; Ge, J. J.; Xing, W. Recent development of low iridium electrocatalysts toward efficient water oxidation. J. Electrochem. 2022, 28, 2214010.
Crossref Google Scholar
[9]

Ji, M. W.; Yang, X.; Chang, S. D.; Chen, W. X.; Wang, J.; He, D. S.; Hu, Y.; Deng, Q.; Sun, Y.; Li, B. et al. RuO2 clusters derived from bulk SrRuO3: Robust catalyst for oxygen evolution reaction in acid. Nano Res. 2022, 15, 1959–1965.
Crossref Google Scholar
[10]

Li, G. Q.; Li, S. T.; Xiao, M. L.; Ge, J. J.; Liu, C. P.; Xing, W. Nanoporous IrO2 catalyst with enhanced activity and durability for water oxidation owing to its micro/mesoporous structure. Nanoscale 2017, 9, 9291–9298.
Crossref Google Scholar
[11]

Li, N.; Cai, L.; Wang, C.; Lin, Y.; Huang, J. Z.; Sheng, H. Y.; Pan, H. B.; Zhang, W.; Ji, Q. Q.; Duan, H. L. et al. Identification of the active-layer structures for acidic oxygen evolution from 9R-BaIrO3 electrocatalyst with enhanced iridium mass activity. J. Am. Chem. Soc. 2021, 143, 18001–18009.
Crossref Google Scholar
[12]

Wang, H. P.; Xu, Z. X.; Lin, W.; Yang, X.; Gu, X. R.; Zhu, W.; Zhuang, Z. B. Improving the water electrolysis performance by manipulating the generated nano/micro-bubbles using surfactants. Nano Res. 2023, 16, 420–426.
Crossref Google Scholar
[13]

Li, L. G.; Wang, P. T.; Shao, Q.; Huang, X. Q. Recent progress in advanced electrocatalyst design for acidic oxygen evolution reaction. Adv. Mater. 2021, 33, 2004243.
Crossref Google Scholar
[14]

Shan, J. Q.; Ye, C.; Chen, S. M.; Sun, T. L.; Jiao, Y.; Liu, L. M.; Zhu, C. Z.; Song, L.; Han, Y.; Jaroniec, M. et al. Short-range ordered iridium single atoms integrated into cobalt oxide spinel structure for highly efficient electrocatalytic water oxidation. J. Am. Chem. Soc. 2021, 143, 5201–5211.
Crossref Google Scholar
[15]

Jia, C. X.; Qin, H.; Zhen, C.; Zhu, H. Z.; Yang, Y. Q.; Han, A.; Wang, L. Z.; Liu, G.; Cheng, H. M. Ir single atoms modified Ni(OH)2 nanosheets on hierarchical porous nickel foam for efficient oxygen evolution. Nano Res. 2022, 15, 10014–10020.
Crossref Google Scholar
[16]

Iqbal, S.; Safdar, B.; Hussain, I.; Zhang, K. L.; Chatzichristodoulou, C. Trends and prospects of bulk and single-atom catalysts for the oxygen evolution reaction. Adv. Energy Mater. 2023, 13, 2203913.
Crossref Google Scholar
[17]

Lebedev, D.; Ezhov, R.; Heras-Domingo, J.; Comas-Vives, A.; Kaeffer, N.; Willinger, M.; Solans-Monfort, X.; Huang, X.; Pushkar, Y.; Copéret, C. Atomically dispersed iridium on indium tin oxide efficiently catalyzes water oxidation. ACS Cent. Sci. 2020, 6, 1189–1198.
Crossref Google Scholar
[18]

Shi, Z. P.; Wang, Y.; Li, J.; Wang, X.; Wang, Y. B.; Li, Y.; Xu, W. L.; Jiang, Z.; Liu, C. P.; Xing, W. et al. Confined Ir single sites with triggered lattice oxygen redox: Toward boosted and sustained water oxidation catalysis. Joule 2021, 5, 2164–2176.
Crossref Google Scholar
[19]

Kaiser, S. K.; Chen, Z. P.; Faust Akl, D.; Mitchell, S.; Pérez-Ramírez, J. Single-atom catalysts across the periodic table. Chem. Rev. 2020, 120, 11703–11809.
Crossref Google Scholar
[20]

Chen, Y. B.; Li, H. Y.; Wang, J. X.; Du, Y. H.; Xi, S. B.; Sun, Y. M.; Sherburne, M.; Ager III, J. W.; Fisher, A. C.; Xu, Z. J. Exceptionally active iridium evolved from a pseudo-cubic perovskite for oxygen evolution in acid. Nat. Commun. 2019, 10, 572.
Crossref Google Scholar
[21]

Zhang, N.; Feng, X. B.; Rao, D. W.; Deng, X.; Cai, L. J.; Qiu, B. C.; Long, R.; Xiong, Y. J.; Lu, Y.; Chai, Y. Lattice oxygen activation enabled by high-valence metal sites for enhanced water oxidation. Nat. Commun. 2020, 11, 4066.
Crossref Google Scholar
[22]

Zhang, F. F.; Cheng, C. Q.; Wang, J. Q.; Shang, L.; Feng, Y.; Zhang, Y.; Mao, J.; Guo, Q. J.; Xie, Y. M.; Dong, C. K. et al. Iridium oxide modified with silver single atom for boosting oxygen evolution reaction in acidic media. ACS Energy Lett. 2021, 6, 1588–1595.
Crossref Google Scholar
[23]

Zlatar, M.; Nater, D.; Escalera-López, D.; Joy, R. M.; Pobedinskas, P.; Haenen, K.; Copéret, C.; Cherevko, S. Evaluating the stability of Ir single atom and Ru atomic cluster oxygen evolution reaction electrocatalysts. Electrochim. Acta 2023, 444, 141982.
Crossref Google Scholar
[24]

Geiger, S.; Kasian, O.; Ledendecker, M.; Pizzutilo, E.; Mingers, A. M.; Fu, W. T.; Diaz-Morales, O.; Li, Z. Z.; Oellers, T.; Fruchter, L. et al. The stability number as a metric for electrocatalyst stability benchmarking. Nat. Catal. 2018, 1, 508–515.
Crossref Google Scholar
[25]

Wang, Y. B.; Ma, R. P.; Shi, Z. P.; Wu, H. X.; Hou, S.; Wang, Y.; Liu, C. P.; Ge, J. J.; Xing, W. Inverse doping IrO x /Ti with weakened Ir–O interaction toward stable and efficient acidic oxygen evolution. Chem 2023, 9, 2931–2942.
Crossref Google Scholar
[26]
Ni, J.; Shi, Z. P.; Wang, Y. B.; Yang, J. H.; Wu, H. X.; Wang, P. B.; Li, K.; Xiao, M. L.; Liu, C. P.; Xing, W. Suppressing the lattice oxygen diffusion via high-entropy oxide construction towards stabilized acidic water oxidation. Nano Res., in press, DOI: 10.1007/s12274-023-5913-6.
[27]

Lončar, A.; Escalera-López, D.; Cherevko, S.; Hodnik, N. Inter-relationships between oxygen evolution and iridium dissolution mechanisms. Angew. Chem., Int. Ed. 2022, 61, e202114437.
Crossref Google Scholar
[28]

Kasian, O.; Grote, J. P.; Geiger, S.; Cherevko, S.; Mayrhofer, K. J. J. The common intermediates of oxygen evolution and dissolution reactions during water electrolysis on iridium. Angew. Chem., Int. Ed. 2018, 57, 2488–2491.
Crossref Google Scholar
[29]

Cai, C.; Wang, M. Y.; Han, S. B.; Wang, Q.; Zhang, Q.; Zhu, Y. M.; Yang, X. M.; Wu, D. J.; Zu, X. T.; Sterbinsky, G. E. et al. Ultrahigh oxygen evolution reaction activity achieved using Ir single atoms on amorphous CoO x nanosheets. ACS Catal. 2021, 11, 123–130.
Crossref Google Scholar
[30]

Wang, Q.; Huang, X.; Zhao, Z. L.; Wang, M. Y.; Xiang, B.; Li, J.; Feng, Z. X.; Xu, H.; Gu, M. Ultrahigh-loading of Ir single atoms on NiO matrix to dramatically enhance oxygen evolution reaction. J. Am. Chem. Soc. 2020, 142, 7425–7433.
Crossref Google Scholar
[31]

Sun, Y. M.; Liao, H. B.; Wang, J. R.; Chen, B.; Sun, S. N.; Ong, S. J. H.; Xi, S. B.; Diao, C. Z.; Du, Y. H.; Wang, J. O. et al. Covalency competition dominates the water oxidation structure-activity relationship on spinel oxides. Nat. Catal. 2020, 3, 554–563.
Crossref Google Scholar
[32]

Wang, L.; Ji, B. F.; Zheng, Y. P.; Tang, Y. B. Asymmetric coordination of iridium single-atom IrN3O boosting formic acid oxidation catalysis. Angew. Chem., Int. Ed. 2023, 62, e202301711.
Crossref Google Scholar
[33]

Chen, F. Y.; Wu, Z. Y.; Adler, Z.; Wang, H. T. Stability challenges of electrocatalytic oxygen evolution reaction: From mechanistic understanding to reactor design. Joule 2021, 5, 1704–1731.
Crossref Google Scholar
[34]

Zhao, Z. Y.; Elwood, J.; Carpenter, M. A. Phonon anharmonicity of PdO studied by Raman spectrometry. J. Phys. Chem. C 2015, 119, 23094–23102.
Crossref Google Scholar
[35]

Shi, Z. P.; Li, J.; Jiang, J. D.; Wang, Y. B.; Wang, X.; Li, Y.; Yang, L. T.; Chu, Y. Y.; Bai, J. S.; Yang, J. H. et al. Enhanced acidic water oxidation by dynamic migration of oxygen species at the Ir/Nb2O5− x catalyst/support interfaces. Angew. Chem., Int. Ed. 2022, 61, e202212341.
Crossref Google Scholar
Nano Research
Volume 17 Issue 4,
April 2024
Pages 2492-2498
DOI: 10.1007/s12274-023-6177-x
Cite this article:
Wang Y, Jiang J, Shi Z, et al. Stabilizing high-efficiency iridium single atoms via lattice confinement for acidic oxygen evolution. Nano Research, 2024, 17(4): 2492-2498. https://doi.org/10.1007/s12274-023-6177-x
Topics:
Electrocatalysis Oxygen evolution reaction

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Received: 11 July 2023
Revised: 29 August 2023
Accepted: 10 September 2023
Published: 02 December 2023
© Tsinghua University Press 2023
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