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Review Article

Designing metal sulfide-based cathodes and separators for suppressing polysulfide shuttling in lithium-sulfur batteries

Guoyin Zhu1,§ ( ), Qingzhu Wu2,§, Xianghua Zhang3, Yuwen Bao1, Xuan Zhang1, Zhuoyao Shi1, Yizhou Zhang1 ( ), Lianbo Ma2 ( )
Institute of Advanced Materials and Flexible Electronics (IAMFE), School of Chemistry and Materials Science, Nanjing University of Information Science & Technology, Nanjing 210044, China
School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China
School of Mechanical Engineering, Jiangsu University of Technology, Changzhou 213001, China

§ Guoyin Zhu and Qingzhu Wu contributed equally to this work.

Show Author Information

Graphical Abstract

Metal sulfides with high chemical affinity to intermediate polysulfides and remarkable electrocatalytic activity toward polysulfide conversions have been extensively utilized in lithium-sulfur (Li-S) batteries. This review summarizes the recent progress on metal sulfide in sulfur hosts and separator coating layers for Li-S batteries, presents the remaining issues/challenges, and gives the future perspectives for practical applications. This work will provide new guidance for exploring high-performance metal sulfide-based Li-S batteries.

Abstract

Lithium-sulfur (Li-S) batteries, known for their high energy density, are attracting extensive research interest as a promising next-generation energy storage technology. However, their widespread use has been hampered by certain issues, including the dissolution and migration of polysulfides, along with sluggish redox kinetics. Metal sulfides present a promising solution to these obstacles regarding their high electrical conductivity, strong chemical adsorption with polysulfides, and remarkable electrocatalytic capabilities for polysulfide conversion. In this review, the recent progress on the utilization of metal sulfide for suppressing polysulfide shuttling in Li-S batteries is systematically summarized, with a special focus on sulfur hosts and functional separators. The critical roles of metal sulfides in realizing high-performing Li-S batteries have been comprehensively discussed by correlating the materials’ structure and electrochemical performances. Moreover, the remaining issues/challenges and future perspectives are highlighted. By offering a detailed understanding of the crucial roles of metal sulfides, this review dedicates to contributing valuable knowledge for the pursuit of high-efficiency Li-S batteries based on metal sulfides.

Keywords

lithium-sulfur batteriesmetal sulfidespolysulfide shuttlingsulfur hostsseparator coating layers

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Nano Research
Volume 17 Issue 4,
April 2024
Pages 2574-2591
DOI: 10.1007/s12274-023-6227-4
Cite this article:
Zhu G, Wu Q, Zhang X, et al. Designing metal sulfide-based cathodes and separators for suppressing polysulfide shuttling in lithium-sulfur batteries. Nano Research, 2024, 17(4): 2574-2591. https://doi.org/10.1007/s12274-023-6227-4
Topics:
Secondary batteries

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Received: 31 August 2023
Revised: 18 September 2023
Accepted: 20 September 2023
Published: 03 November 2023
© Tsinghua University Press 2023
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