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Review Article

Electrodes for Li-ion batteries: From high-voltage LiCoO2 to Co-reduced /Co-free layered oxides with potential anodes

Luting Song1, Weiguo Chu1,2()
Nanofabrication Laboratory, National Center for Nanoscience and Technology, Beijing 100190, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
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In this review, we review and comment on layered cathodic oxides for Li-ion batteries from the perspective of gradually vanishing cobalt involved, including particular strategies of improving the performance of cathode materials and their underlying mechanisms. Also, carbon and silicon-based anode materials that can pair appropriately with them are briefly discussed.

Abstract

Li-ion batteries (LIBs) are one type of more and more widely used devices for energy storage and power supply in which cathode materials are playing a relatively more decisive role at current stage. In this review, we start with pioneeringly commercialized LiCoO2 (LCO) with a layered rhombohedral structure (space group R3¯m) to discuss novel sequentially emerging LCO-derived layered oxides from the perspectives of both cobalt content reduction and performance improvement. Emphasis is placed on the improvement of high-voltage performance of LCO and Co-reduced/free layered oxides, including Co-reduced high-nickel layered oxides, Co-free Li-rich layered oxides, and Ni-based layered oxides cathodes, and their underlying mechanisms via different strategies. Also, possibly matched carbon and silicon-based anode materials are briefly discussed. The common issues and prospects of the layered oxides cathodes and their potential anodes are summarized and commented on. This review can help understand the emergence logics of novel layered oxides with gradually vanishing cobalt involved, provide insights about the underlying mechanisms of performance enhancement pertaining to particular strategies, and even inspire the discovery of novel cathode materials with high performance and low cost.

Keywords

Li-ion batteriescathodic materialsanode materialshigh-voltage LiCoO2Co-reduced/free layered oxides

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Nano Research
Volume 16 Issue 12,
December 2023
Pages 12983-13007
DOI: 10.1007/s12274-023-6239-4
Cite this article:
Song L, Chu W. Electrodes for Li-ion batteries: From high-voltage LiCoO2 to Co-reduced /Co-free layered oxides with potential anodes. Nano Research, 2023, 16(12): 12983-13007. https://doi.org/10.1007/s12274-023-6239-4
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Lithium batteries
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