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Electrocatalytic n-valeraldehyde oxidation reaction was an inexpensive and eco-friendly method to control n-valeraldehyde contamination and produce high value-added octane. However, low-cost and readily available electrocatalysts with high current efficiency were urgently needed. Herein, two-dimensional porous carbon derived from pollen with enlarged interlayer distance was built by alkali activation method, applying in electrocatalytic n-valeraldehyde oxidation reaction. The enlarged interlayer distance was verified by X-ray diffraction (XRD) and high-angle annular dark-field scanning transmission electron microscope (HAADF-STEM). Electrocatalytic experiments consequences showed activated biomass derived carbon possessed a higher electrocatalytic activity and octane selectivity than unactivated catalyst. Systematic tests and in situ infrared experiments demonstrated that enlarged interlayer distance was positively correlated with specific surface area of catalysts, large specific surface area provided abundant absorption sites, facilitated the adsorption for n-valeraldehyde, and further promoted the transformation of n-valeraldehyde to octane. This work also provides a new avenue for creating high-performance electrocatalysts in terms of lattice engineering.
An, H. L.; Wang, D.; Miao, S.; Yang, Q. S.; Zhao, X. Q.; Wang, Y. J. Preparation of Ni-IL/SiO2 and its catalytic performance for one-pot sequential synthesis of 2-propylheptanol from n-valeraldehyde. RSC Adv. 2020, 10, 28100–28105.
Zhao, L. L.; An, H. L.; Zhao, X. Q.; Wang, Y. J. Effect of second metal component on the reduction property and catalytic performance of NiO-MO x /Nb2O5-TiO2 for direct synthesis of 2-propylheptanol from n-valeraldehyde. Catal. Commun. 2021, 149, 106209.
Zhao, L. L.; An, H. L.; Zhao, X. Q.; Wang, Y. J. Effect of Ni/Co mass ratio and NiO-Co3O4 loading on catalytic performance of NiO-Co3O4/Nb2O5-TiO2 for direct synthesis of 2-propylheptanol from n-valeraldehyde. RSC Adv. 2021, 11, 1736–1742.
Scirè, S.; Liotta, L. F. Supported gold catalysts for the total oxidation of volatile organic compounds. Appl. Catal. B: Environ. 2012, 125, 222–246.
Nikawa, T.; Naya, S. I.; Kimura, T.; Tada, H. Rapid removal and subsequent low-temperature mineralization of gaseous acetaldehyde by the dual thermocatalysis of gold nanoparticle-loaded titanium(IV) oxide. J. Catal. 2015, 326, 9–14.
Azzouz, A.; Vikrant, K.; Kim, K. H.; Ballesteros, E.; Rhadfi, T.; Malik, A. K. Advances in colorimetric and optical sensing for gaseous volatile organic compounds. TrAC Trends Analyt. Chem. 2019, 118, 502–516.
Suzuki, N.; Nakaoka, H.; Nakayama, Y.; Takaya, K.; Tsumura, K.; Hanazato, M.; Tanaka, S.; Matsushita, K.; Iwayama, R.; Mori, C. Changes in the concentration of volatile organic compounds and aldehydes in newly constructed houses over time. Int. J. Environ. Sci. Technol. 2019, 17, 333–342.
Gomes, B. F.; Holzhäuser, F. J.; Lobo, C. M. S.; Da Silva, P. F.; Danieli, E.; Carmo, M.; Colnago, L. A.; Palkovits, S.; Palkovits, R.; Blümich, B. Sustainable electrocoupling of the biogenic valeric acid under in situ low-field nuclear magnetic resonance conditions. ACS Sustain. Chem. Eng. 2019, 7, 18288–18296.
Bisselink, R. J. M.; Crockatt, M.; Zijlstra, M.; Bakker, I. J.; Goetheer, E.; Slaghek, T. M.; Van Es, D. S. Identification of more benign cathode materials for the electrochemical reduction of levulinic acid to valeric acid. ChemElectroChem 2019, 6, 3285–3290.
Klüh, D.; Waldmüller, W.; Gaderer, M. Kolbe electrolysis for the conversion of carboxylic acids to valuable products—A process design study. Clean Technol. 2021, 3, 1–18.
Nilges, P.; Schröder, U. Electrochemistry for biofuel generation: Production of furans by electrocatalytic hydrogenation of furfurals. Energy Environ. Sci. 2013, 6, 2925–2931.
Qin, M. C.; Fan, S. Y.; Li, X. Y.; Niu, Z. D.; Bai, C. P.; Chen, G. H. Highly efficient electrocatalytic upgrade of n-valeraldehyde to octane over Au SACs-NiMn2O4 spinel synergetic composites. Small 2022, 18, 2201359.
Zhang, T. Y.; Ran, F. Design strategies of 3D carbon‐based electrodes for charge/ion transport in lithium ion battery and sodium ion battery. Adv. Funct. Mater. 2021, 31, 2010041.
Yuan, X. M.; Zhu, B.; Feng, J. K.; Wang, C. G.; Cai, X.; Qin, R. M. Recent advance of biomass-derived carbon as anode for sustainable potassium ion battery. Chem. Eng. J. 2021, 405, 126897.
Wang, R.; Li, Y. S. Carbon electrodes improving electrochemical activity and enhancing mass and charge transports in aqueous flow battery: Status and perspective. Energy Storage Mater. 2020, 31, 230–251.
Rojaee, R.; Shahbazian-Yassar, R. Two-dimensional materials to address the lithium battery challenges. ACS Nano 2020, 14, 2628–2658.
Hawley, W. B.; Parejiya, A.; Bai, Y. C.; Meyer, H. M.; Wood, D. L.; Li, J. L. Lithium and transition metal dissolution due to aqueous processing in lithium-ion battery cathode active materials. J. Power Sources 2020, 466, 228315.
Turcheniuk, K.; Bondarev, D.; Amatucci, G. G.; Yushin, G. Battery materials for low-cost electric transportation. Mater. Today 2021, 42, 57–72.
Yuan, H. D.; Liu, T. F.; Liu, Y. J.; Nai, J. W.; Wang, Y.; Zhang, W. K.; Tao, X. Y. A review of biomass materials for advanced lithium-sulfur batteries. Chem. Sci. 2019, 10, 7484–7495.
Jin, C. B.; Nai, J. W.; Sheng, O. W.; Yuan, H. D.; Zhang, W. K.; Tao, X. Y.; Lou, X. W. Biomass-based materials for green lithium secondary batteries. Energy Environ. Sci. 2021, 14, 1326–1379.
Gao, T.; Xu, C. Y.; Li, R. Q.; Zhang, R.; Wang, B. L.; Jiang, X. F.; Hu, M.; Bando, Y.; Kong, D. S.; Dai, P. C. et al. Biomass-derived carbon paper to sandwich magnetite anode for long-life Li-ion battery. ACS Nano 2019, 13, 11901–11911.
Zhang, C.; Xie, Z. H.; Yang, W. F.; Liang, Y.; Meng, D. D.; He, X.; Liang, P.; Zhang, Z. H. NiCo2O4/biomass-derived carbon composites as anode for high-performance lithium ion batteries. J. Power Sources 2020, 451, 227761.
Xiao, K. X.; Liu, H.; Li, Y.; Yang, G. Y.; Wang, Y. J.; Yao, H. Excellent performance of porous carbon from urea-assisted hydrochar of orange peel for toluene and iodine adsorption. Chem. Eng. J. 2020, 382, 122997.
Anarghya, D.; Anantha, M. S.; Venkatesh, K.; Santosh, M. S.; Priya, M. G.; Muralidhara, H. B. Bermuda grass derived nitrogen-doped carbon as electrocatalyst in graphite felt electrode to increase the efficiency of all-iron redox flow batteries. J. Electroanal. Chem. 2020, 878, 114577.
Lu, J. M.; Mishra, P.K.; Hunter, T. N.; Yang, F.; Lu, Z. G.; Harbottle, D.; Xu, Z. H. Functionalization of mesoporous carbons derived from pomelo peel as capacitive electrodes for preferential removal/recovery of copper and lead from contaminated water. Chem. Eng. J. 2022, 433, 134508.
Mestre, A. S.; Viegas, R. M. C.; Mesquita, E.; Rosa, M. J. A.; Carvalho, A. P. Engineered pine nut shell derived activated carbons for improved removal of recalcitrant pharmaceuticals in urban wastewater treatment. J. Hazard. Mater. 2022, 437, 129319.
Chen, Z. H.; Du, X. L.; He, J. B.; Li, F.; Wang, Y.; Li, Y. L.; Li, B.; Xin, S. Porous coconut shell carbon offering high retention and deep lithiation of sulfur for lithium-sulfur batteries. ACS Appl. Mater. Interfaces 2017, 9, 33855–33862.
Mou, P. P.; Zhao, J. C.; Wang, G. Z.; Shi, S. H.; Wan, G. P.; Zhou, M. F.; Deng, Z.; Teng, S. J.; Wang, G. L. BCN nanosheets derived from coconut shells with outstanding microwave absorption and thermal conductive properties. Chem. Eng. J. 2022, 437, 135285.
Guan, L.; Pan, L.; Peng, T. Y.; Gao, C.; Zhao, W. N.; Yang, Z. X.; Hu, H.; Wu, M. B. Synthesis of biomass-derived nitrogen-doped porous carbon nanosheests for high-performance supercapacitors. ACS Sustain. Chem. Eng. 2019, 7, 8405–8412.
Zhu, Z. Y.; Xu, Z. The rational design of biomass-derived carbon materials towards next-generation energy storage: A review. Renew. Sustain. Energy Rev. 2020, 134, 110308.
Sun, Y.; Shi, X. L.; Yang, Y. L.; Suo, G. Q.; Zhang, L.; Lu, S. Y.; Chen, Z. G. Biomass‐derived carbon for high-performance batteries: From structure to properties. Adv. Funct. Mater. 2022, 32, 2201584.
Wang, J. C.; Kaskel, S. KOH activation of carbon-based materials for energy storage. J. Mater. Chem. 2012, 22, 23710.
Xu, C.; Yang, W.; Ma, G.; Che, S.; Li, Y.; Jia, Y.; Chen, N.; Huang, C. Y.; Li, Y. F. Edge-nitrogen enriched porous carbon nanosheets anodes with enlarged interlayer distance for fast charging sodium-ion batteries. Small 2022, 18, 2204375.
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