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Research Article

Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage

Mu-Qing Li1,3,§, Yulin Cao3,§, Lei Qin4, Hua Cheng1( ), Weimin Yang2( ), Zhouguang Lu3( )
School of Materials Science and Environmental Engineering, Shenzhen Polytechnic University, Shenzhen 518055, China
Industrial Training Center, Shenzhen Polytechnic University, Shenzhen 518055, China
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China
Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

§ Mu-Qing Li and Yulin Cao contributed equally to this work.

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Graphical Abstract

A novel two-dimensional (2D) coordination network with Bi–O and Bi–S–Ar chains has been developed and utilized as energy storage.

Abstract

Single crystals of a bismuth-based coordination polymer (CP) with carboxyl-thiol ligands, [Bi(C8H2O4S2)(C2H8N)]n (Bi-DSBDC-DMA, DMBDC = 2,5-disulfur-1,4-dicarboxylate, DMA = dimethylamine), have been successfully synthesized. X-ray diffraction analysis reveals that Bi-DSBDC-DMA possesses a layered structure, with two-dimensional (2D) Bi-DSBDC networks alternating with layers composed of dimethylamine ions. This material demonstrates semiconducting properties, featuring an optical bandgap of 2.2 eV and an electrical conductivity of 2 × 10−8 S/cm. Furthermore, electrodes based on this material exhibit a capacity of 250 mAh/g after 200 cycles for lithium-ion storage.

Keywords

bismuthlayer coordination polymer (CP)semiconductorlithium ion storage

Electronic Supplementary Material

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Nano Research
Volume 17 Issue 3,
March 2024
Pages 2181-2185
DOI: 10.1007/s12274-023-6367-6
Cite this article:
Li M-Q, Cao Y, Qin L, et al. Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage. Nano Research, 2024, 17(3): 2181-2185. https://doi.org/10.1007/s12274-023-6367-6
Topics:
Coordination reactionsIon batteries

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Received: 29 October 2023
Revised: 24 November 2023
Accepted: 26 November 2023
Published: 28 December 2023
© Tsinghua University Press 2023
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