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Review Article

Diverse atomic structure configurations of metal-doped transition metal dichalcogenides for enhancing hydrogen evolution

Longlu Wang1( ), Yuxin Zhang1, Chen Gu1, Haoxuan Yu1, Yanling Zhuang1, Zechao Zhuang2( )
College of Electronic and Optical Engineering and College of Flexible Electronics (Future Technology), Jiangsu Province Engineering Research Center for Fabrication and Application of Special Optical Fiber Materials and Devices, Nanjing University of Posts and Telecommunications, Nanjing 210023, China
Department of Chemical Engineering, Columbia University, New York, NY 10027, USA
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Graphical Abstract

Diverse atomic structure configurations of adsorptive doping, substitutional doping, and transition metal dichalcogenides (TMDs) alloys are summarized.

Abstract

Doping foreign metal atoms into the substrate of transition metal dichalcogenides (TMDs) enables the formation of diverse atomic structure configurations, including isolated atoms, chains, and clusters. Therefore, it is very important to reasonably control the atomic structure and determine the structure–activity relationship between the atomic configurations and the hydrogen evolution reaction (HER) performance. Although numerous studies have indicated that doping can yield diverse atomic structure configurations, there remains an incomplete understanding of the relationship between atomic configurations within the lattice of TMDs and their performance. Here, diverse atomic structure configurations of adsorptive doping, substitutional doping, and TMDs alloys are summarized. The structure–activity relationship between different atomic configurations and HER performance can be determined by micro-nanostructure devices and density functional theory (DFT) calculations. These diverse atomic structure configurations are of great significance for activating the inert basal plane of TMDs and improving the catalytic activity of HER. Finally, we have summarized the current challenges and future opportunities, offering new perspectives for the design of highly active and stable metal-doped TMDs catalysts.

Keywords

transition metal dichalcogenides (TMDs)dopant effectdiverse atomic structure configurationshydrogen evolution reaction (HER)

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Nano Research
Volume 17 Issue 5,
May 2024
Pages 3586-3602
DOI: 10.1007/s12274-023-6374-7
Cite this article:
Wang L, Zhang Y, Gu C, et al. Diverse atomic structure configurations of metal-doped transition metal dichalcogenides for enhancing hydrogen evolution. Nano Research, 2024, 17(5): 3586-3602. https://doi.org/10.1007/s12274-023-6374-7
Topics:
Hydrogen evolution reaction

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Received: 15 October 2023
Revised: 01 November 2023
Accepted: 23 November 2023
Published: 29 December 2023
© Tsinghua University Press 2023
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