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Research Article

Accelerated reconstruction of ZIF-67 with significantly enhanced glucose detection sensitivity

Huihui Jin1,2, Weihao Zeng3, Wei Qian3, Lun Li3, Pengxia Ji3, Zhengying Li1,3( ), Daping He2( )
School of Information Engineering, Wuhan University of Technology, Wuhan 430070, China
Hubei Engineering Research Center of RF-Microwave Technology and Application, Wuhan University of Technology, Wuhan 430070, China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
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Graphical Abstract

Electrochemical activation promotes the reconstruction of zeolitic imidazolate framework-67 (ZIF-67) to generate CoOOH, achieving efficient and stable glucose detection.

Abstract

Research on metal-organic framework (MOF)-based non-enzymatic glucose sensors usually ignores the impact of the surface reconstruction degree of MOF on the activity of catalyzing glucose oxidation. In this work, we choose zeolitic imidazolate framework-67 (ZIF-67), which is commonly used in glucose sensing, as a representative to investigate the influence of reconstruction degree on its structure and glucose catalytic performance. By employing the electrochemical activation strategy, the activity of ZIF-67 in catalyzing glucose gradually increased with the prolongation of the activation time, reaching the optimum after 2 h activation. The detection sensitivity of the activated ZIF-67 was 19 times higher than that of the initial ZIF-67, and the limit of detection (LOD) was lowered from 7 to 0.4 μM. Our findings demonstrate that the oxidation degree of ZIF-67 deepened rapidly with continuously activation and was basically reconstructed to CoOOH after 2 h activation, accompanied by a morphological change from cuboctahedral to flower-like. Simultaneously, theoretical investigation revealed that ZIF-67 is not suitable as a stable glucose sensor electrode since the adsorbed glucose molecules hasten the dissociation of ligands and the breaking of Co–N bond in ZIF-67. Therefore, our work has important implications for the rational design of next-generation MOF-based glucose sensors.

Keywords

zeolitic imidazolate framework-67 (ZIF-67)glucose oxidationelectrochemical activationreconstructionCoOOH

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Nano Research
Volume 17 Issue 6,
June 2024
Pages 4737-4743
DOI: 10.1007/s12274-023-6409-0
Cite this article:
Jin H, Zeng W, Qian W, et al. Accelerated reconstruction of ZIF-67 with significantly enhanced glucose detection sensitivity. Nano Research, 2024, 17(6): 4737-4743. https://doi.org/10.1007/s12274-023-6409-0
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Catalytic oxidation

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Received: 30 November 2023
Revised: 10 December 2023
Accepted: 11 December 2023
Published: 25 January 2024
© Tsinghua University Press 2024
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