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Research Article

Constructing a fluorinated interface layer enriched with Ge nanoparticles and Li-Ge alloy for stable lithium metal anodes

Fulu Chu1,†, Jinwei Zhou1, Jiamin Liu1, Fengcheng Tang1, Liubin Song2( ), Feixiang Wu1( )
School of Metallurgy and Environment, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-added Metallurgy, Central South University, Changsha 410083, China
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha 410004, China
Present address: School of Materials Science & Engineering, University of Jinan, Jinan 250022, China
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Graphical Abstract

An artificial solid electrolyte interphase (SEI) is constructed via a simple brush coating method, exhibiting superior interfacial stability and cycling performance. The composition and working mechanism of the hybrid SEI are determined to show mutual reinforcement between fluorinated species and Li-Ge alloys.

Abstract

Lithium metal batteries (LMBs) based on metallic Li exhibit high energy density to be competent for advanced energy storage applications. However, the unstable solid electrolyte interphase (SEI) layer due to continuous decomposition of electrolytes, and the attendant problem of Li dendrite growth frustrate their commercialization process. Herein, a hybrid SEI comprising abundant LiF, lithiophilic Li-Ge alloy, and Ge nanoparticles is constructed via a simple brush coating method. This fluorinated interface layer with embedded Ge-containing components isolates the Li anode from the corrosive electrolyte and facilitates homogenous Li nucleation as well as uniform growth. Consequently, the modified Li anode exhibits remarkable stability without notorious Li dendrites, delivering stable cycling lives of more than 1000 h for symmetric Li||Li cells and over 600 cycles for Li||Cu cells at 1 mA·cm−2. Moreover, the reinforced Li anodes endow multiple full-cell architectures with dramatically improved cyclability under different test conditions. This work provides rational guidance to design an artificial hybrid SEI layer and would stimulate more ideas to solve the dendrite issue and promote the further development of advanced LMBs.

Keywords

lithium metal anodeartificial solid electrolyte interphase (SEI)dendrite suppressionlithium fluorideLi-Ge alloy

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Nano Research
Volume 17 Issue 6,
June 2024
Pages 5148-5158
DOI: 10.1007/s12274-024-6437-4
Cite this article:
Chu F, Zhou J, Liu J, et al. Constructing a fluorinated interface layer enriched with Ge nanoparticles and Li-Ge alloy for stable lithium metal anodes. Nano Research, 2024, 17(6): 5148-5158. https://doi.org/10.1007/s12274-024-6437-4
Topics:
Lithium batteriesSecondary batteries

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Received: 21 November 2023
Revised: 20 December 2023
Accepted: 21 December 2023
Published: 25 January 2024
© Tsinghua University Press 2024
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