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Review Article

Regulation of aqueous electrolyte interface via electrolyte strategies for uniform zinc deposition

Wei Zhong1,2,3,§, Chaoqiang Tan2,3,§, Laixi Li1,2, Shichao Zhang2, Xinyang Wang2,4, Hao Cheng1,2,3( ), Yingying Lu1,2,3( )
Institute of Wenzhou, Zhejiang University, Wenzhou 325006, China
State Key Laboratory of Chemical Engineering, Institute of Pharmaceutical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, China
Zhejiang Huayou Cobalt Company Limited, Tongxiang 314500, China

§ Wei Zhong and Chaoqiang Tan contributed equally to this work.

Show Author Information

Graphical Abstract

This review focuses on the primary challenge faced by Zn anodes, provides an in-depth look at electrochemical models that control Zn deposition in aqueous zinc ion batteries (AZIBs) and discusses how these models guide the design of the electrolyte system.

Abstract

Aqueous zinc ion batteries (AZIBs), renowned for their high theoretical energy density, safety, cost-effectiveness and eco-friendliness, offer immense potential in the realm of energy storage and conversion, finding applications in renewable energy and portable devices. However, the development of AZIBs still faces several challenges related to the electrochemical behavior of zinc anodes in aqueous electrolytes, primarily zinc dendrite formation, which emphasize the critical need for a fundamental understanding of the interfacial phenomena between the electrode and electrolyte. This review focuses on the three models: the electric double layer (EDL) model, the solvation structure model, and the Zn/electrolyte interface model. They guide the design of the electrolyte system in AZIBs. These models provide a comprehensive understanding of the interactions between the electrode, electrolyte, and the solvated ions in the system. By optimizing the salt types, salt concentrations, solvents and additives based on these models, it is possible to enhance the performance of AZIBs, including their energy density, cycle life, and safety. The review also highlights recent research progress in electrolyte modification of AZIBs for understanding battery behavior, along with perspectives for the direction of further investigations.

Keywords

aqueous zinc ion batterieselectric double layersolvation structureelectrolyte optimization

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Nano Research
Volume 17 Issue 10,
October 2024
Pages 8678-8693
DOI: 10.1007/s12274-024-6591-8
Cite this article:
Zhong W, Tan C, Li L, et al. Regulation of aqueous electrolyte interface via electrolyte strategies for uniform zinc deposition. Nano Research, 2024, 17(10): 8678-8693. https://doi.org/10.1007/s12274-024-6591-8
Topics:
Secondary batteries
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Tenth Nano Research Award

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Received: 14 January 2024
Revised: 23 February 2024
Accepted: 26 February 2024
Published: 16 April 2024
© Tsinghua University Press 2024
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