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Review Article

Recent progress on the synthesis of defective UiO-66 for thermal catalysis

Qing Feng1,2,§, Caoyu Yang1,2,§, Lin Chang1,2, Guodong Li1,2( ), Zhiyong Tang1,2( )
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
School of Nanoscience and Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

§ Qing Feng and Caoyu Yang contributed equally to this work.

Show Author Information

Graphical Abstract

This review summarizes the recent research progress on the synthesis and characterization of defective Universitetet i Oslo as well as its applications in thermal catalysis, and moreover, the challenges and future outlooks of defective metal-organic frameworks (MOFs) are highlighted for the catalytic applications.

Abstract

Zirconium terephthalate UiO-66 has aroused great interest in catalysis since it exhibits significant flexibility and compatibility for accommodating a high number of defects as well as exceptional thermal and chemical stability. Until now, many works have focused on the modulations of the Zr6-oxo clusters in UiO-66 in terms of diverse synthesis, advanced characterizations, and their catalytic applications. To achieve high catalytic efficiency, it is still highly desired for rationally constructing and modulating the Zr6-oxo clusters with exposed catalytic sites and diverse microenvironments for advanced catalysis. In this review, we provide a comprehensive summary of recent progress on the synthesis of defective UiO-66, qualitative and quantitative characterizations, as well as a logical overview of heterogeneous catalytic applications over the past few years. Finally, the outlooks for the research paradigm of defective UiO-66 are discussed.

Keywords

defective UiO-66de novo synthesispost-synthetic treatmentcharacterizationthermal catalysis

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Nano Research
Volume 17 Issue 10,
October 2024
Pages 8653-8670
DOI: 10.1007/s12274-024-6621-6
Cite this article:
Feng Q, Yang C, Chang L, et al. Recent progress on the synthesis of defective UiO-66 for thermal catalysis. Nano Research, 2024, 17(10): 8653-8670. https://doi.org/10.1007/s12274-024-6621-6
Topics:
Catalysis Catalyst activityCatalyst selectivity CatalystsCatalytic oxidation Cost effectivenessCrystal defectsCrystal structureCrystallinityDoping (additives)FabricationMicroporosity MicrostructureMorphologyNanocatalystsNanoclustersNanocrystalline materials Nanocrystalline powdersNanocrystallization NanocrystalsNanoporesNanostructured materialsNanostructuresOxidationParticle sizePore sizePore structurePorosityPorous materialsReaction intermediatesReaction ratesReductionSelective catalytic reductionSelf assemblyStructural designStructural optimizationStructure (composition)Surface defectsSynthesis (chemical)Temperature
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Received: 28 January 2024
Revised: 05 March 2024
Accepted: 07 March 2024
Published: 02 May 2024
© Tsinghua University Press 2024
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